Microfabrication of X-ray Optics by Metal Assisted Chemical Etching: A Review

High-aspect-ratio silicon micro- and nanostructures are technologically relevant in several applications, such as microelectronics, microelectromechanical systems, sensors, thermoelectric materials, battery anodes, solar cells, photonic devices, and X-ray optics. Microfabrication is usually achieved...

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Main Authors: Lucia Romano, Marco Stampanoni
Format: Article
Language:English
Published: MDPI AG 2020-06-01
Series:Micromachines
Subjects:
Online Access:https://www.mdpi.com/2072-666X/11/6/589
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author Lucia Romano
Marco Stampanoni
author_facet Lucia Romano
Marco Stampanoni
author_sort Lucia Romano
collection DOAJ
description High-aspect-ratio silicon micro- and nanostructures are technologically relevant in several applications, such as microelectronics, microelectromechanical systems, sensors, thermoelectric materials, battery anodes, solar cells, photonic devices, and X-ray optics. Microfabrication is usually achieved by dry-etch with reactive ions and KOH based wet-etch, metal assisted chemical etching (MacEtch) is emerging as a new etching technique that allows huge aspect ratio for feature size in the nanoscale. To date, a specialized review of MacEtch that considers both the fundamentals and X-ray optics applications is missing in the literature. This review aims to provide a comprehensive summary including: (i) fundamental mechanism; (ii) basics and roles to perform uniform etching in direction perpendicular to the <100> Si substrate; (iii) several examples of X-ray optics fabricated by MacEtch such as line gratings, circular gratings array, Fresnel zone plates, and other X-ray lenses; (iv) materials and methods for a full fabrication of absorbing gratings and the application in X-ray grating based interferometry; and (v) future perspectives of X-ray optics fabrication. The review provides researchers and engineers with an extensive and updated understanding of the principles and applications of MacEtch as a new technology for X-ray optics fabrication.
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spelling doaj.art-cb07fb7cbe714ab3876301a1778e52892023-11-20T03:39:52ZengMDPI AGMicromachines2072-666X2020-06-0111658910.3390/mi11060589Microfabrication of X-ray Optics by Metal Assisted Chemical Etching: A ReviewLucia Romano0Marco Stampanoni1Institute for Biomedical Engineering, ETH Zürich, 8092 Zürich, SwitzerlandInstitute for Biomedical Engineering, ETH Zürich, 8092 Zürich, SwitzerlandHigh-aspect-ratio silicon micro- and nanostructures are technologically relevant in several applications, such as microelectronics, microelectromechanical systems, sensors, thermoelectric materials, battery anodes, solar cells, photonic devices, and X-ray optics. Microfabrication is usually achieved by dry-etch with reactive ions and KOH based wet-etch, metal assisted chemical etching (MacEtch) is emerging as a new etching technique that allows huge aspect ratio for feature size in the nanoscale. To date, a specialized review of MacEtch that considers both the fundamentals and X-ray optics applications is missing in the literature. This review aims to provide a comprehensive summary including: (i) fundamental mechanism; (ii) basics and roles to perform uniform etching in direction perpendicular to the <100> Si substrate; (iii) several examples of X-ray optics fabricated by MacEtch such as line gratings, circular gratings array, Fresnel zone plates, and other X-ray lenses; (iv) materials and methods for a full fabrication of absorbing gratings and the application in X-ray grating based interferometry; and (v) future perspectives of X-ray optics fabrication. The review provides researchers and engineers with an extensive and updated understanding of the principles and applications of MacEtch as a new technology for X-ray optics fabrication.https://www.mdpi.com/2072-666X/11/6/589X-ray grating interferometrycatalystsilicongold electroplating
spellingShingle Lucia Romano
Marco Stampanoni
Microfabrication of X-ray Optics by Metal Assisted Chemical Etching: A Review
Micromachines
X-ray grating interferometry
catalyst
silicon
gold electroplating
title Microfabrication of X-ray Optics by Metal Assisted Chemical Etching: A Review
title_full Microfabrication of X-ray Optics by Metal Assisted Chemical Etching: A Review
title_fullStr Microfabrication of X-ray Optics by Metal Assisted Chemical Etching: A Review
title_full_unstemmed Microfabrication of X-ray Optics by Metal Assisted Chemical Etching: A Review
title_short Microfabrication of X-ray Optics by Metal Assisted Chemical Etching: A Review
title_sort microfabrication of x ray optics by metal assisted chemical etching a review
topic X-ray grating interferometry
catalyst
silicon
gold electroplating
url https://www.mdpi.com/2072-666X/11/6/589
work_keys_str_mv AT luciaromano microfabricationofxrayopticsbymetalassistedchemicaletchingareview
AT marcostampanoni microfabricationofxrayopticsbymetalassistedchemicaletchingareview