(μ-Benzoato-κ2O:O′)tris[μ-N,N′-bis(4-methoxyphenyl)formamidinato-κ2N:N′]dimolybdenum(II) dichloromethane monosolvate
The title compound, [Mo2(C15H15N2O2)3(C7H5O2)]·CH2Cl2, has a quadruply bonded Mo24+ unit equatorially coordinated by three N,N′-bis(4-μ-methoxyphenyl)formamidinate (DAniF) ligands and one benzoate anion. The Mo—Mo bond length of 2.0881&#8...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811002558 |
| _version_ | 1819105054921064448 |
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| author | L.-J. Han |
| author_facet | L.-J. Han |
| author_sort | L.-J. Han |
| collection | DOAJ |
| description | The title compound, [Mo2(C15H15N2O2)3(C7H5O2)]·CH2Cl2, has a quadruply bonded Mo24+ unit equatorially coordinated by three N,N′-bis(4-μ-methoxyphenyl)formamidinate (DAniF) ligands and one benzoate anion. The Mo—Mo bond length of 2.0881 (8) Å is typical for quadruply bonded species. The phenyl ring and the connected dimetal chelating ring (Mo2O2C) are nearly co-planar, making a dihedral angle of 3.24 (13)°. The dichloromethane solvent molecule is disordered over four sets of sites with occupancies of 0.3:0.3:0.2:0.2. |
| first_indexed | 2024-12-22T02:16:09Z |
| format | Article |
| id | doaj.art-cb4d5f2f16a84805a38328e18ca2ec9a |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-22T02:16:09Z |
| publishDate | 2011-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-cb4d5f2f16a84805a38328e18ca2ec9a2022-12-21T18:42:17ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-02-01672m256m25610.1107/S1600536811002558(μ-Benzoato-κ2O:O′)tris[μ-N,N′-bis(4-methoxyphenyl)formamidinato-κ2N:N′]dimolybdenum(II) dichloromethane monosolvateL.-J. HanThe title compound, [Mo2(C15H15N2O2)3(C7H5O2)]·CH2Cl2, has a quadruply bonded Mo24+ unit equatorially coordinated by three N,N′-bis(4-μ-methoxyphenyl)formamidinate (DAniF) ligands and one benzoate anion. The Mo—Mo bond length of 2.0881 (8) Å is typical for quadruply bonded species. The phenyl ring and the connected dimetal chelating ring (Mo2O2C) are nearly co-planar, making a dihedral angle of 3.24 (13)°. The dichloromethane solvent molecule is disordered over four sets of sites with occupancies of 0.3:0.3:0.2:0.2.http://scripts.iucr.org/cgi-bin/paper?S1600536811002558 |
| spellingShingle | L.-J. Han (μ-Benzoato-κ2O:O′)tris[μ-N,N′-bis(4-methoxyphenyl)formamidinato-κ2N:N′]dimolybdenum(II) dichloromethane monosolvate Acta Crystallographica Section E |
| title | (μ-Benzoato-κ2O:O′)tris[μ-N,N′-bis(4-methoxyphenyl)formamidinato-κ2N:N′]dimolybdenum(II) dichloromethane monosolvate |
| title_full | (μ-Benzoato-κ2O:O′)tris[μ-N,N′-bis(4-methoxyphenyl)formamidinato-κ2N:N′]dimolybdenum(II) dichloromethane monosolvate |
| title_fullStr | (μ-Benzoato-κ2O:O′)tris[μ-N,N′-bis(4-methoxyphenyl)formamidinato-κ2N:N′]dimolybdenum(II) dichloromethane monosolvate |
| title_full_unstemmed | (μ-Benzoato-κ2O:O′)tris[μ-N,N′-bis(4-methoxyphenyl)formamidinato-κ2N:N′]dimolybdenum(II) dichloromethane monosolvate |
| title_short | (μ-Benzoato-κ2O:O′)tris[μ-N,N′-bis(4-methoxyphenyl)formamidinato-κ2N:N′]dimolybdenum(II) dichloromethane monosolvate |
| title_sort | amp 956 benzoato amp 954 2o o amp 8242 tris amp 956 n n amp 8242 bis 4 methoxyphenyl formamidinato amp 954 2n n amp 8242 dimolybdenum ii dichloromethane monosolvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811002558 |
| work_keys_str_mv | AT ljhan amp956benzoatoamp9542ooamp8242trisamp956nnamp8242bis4methoxyphenylformamidinatoamp9542nnamp8242dimolybdenumiidichloromethanemonosolvate |