Carbon-oxygen bond formation via visible-light-induced O–H insertion between acylsilanes and oximes
Visible light promoted C–O bond formation reaction through O–H insertion of acylsilanes with oximes has been developed. The reaction occurred under mild reaction conditions (sole blue LED irradiation in the absence of any catalysts or additives) with a short reaction time and afforded the correspond...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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KeAi Communications Co. Ltd.
2022-05-01
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| Series: | Green Synthesis and Catalysis |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S2666554921001137 |
| _version_ | 1811226312301346816 |
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| author | Bao Gui Cai Qian Li Lei Li Jun Xuan |
| author_facet | Bao Gui Cai Qian Li Lei Li Jun Xuan |
| author_sort | Bao Gui Cai |
| collection | DOAJ |
| description | Visible light promoted C–O bond formation reaction through O–H insertion of acylsilanes with oximes has been developed. The reaction occurred under mild reaction conditions (sole blue LED irradiation in the absence of any catalysts or additives) with a short reaction time and afforded the corresponding oxime ethers in moderate to good yields. |
| first_indexed | 2024-04-12T09:23:05Z |
| format | Article |
| id | doaj.art-cb6f5f7cc2bd48ffa7d5c3fb42437b40 |
| institution | Directory Open Access Journal |
| issn | 2666-5549 |
| language | English |
| last_indexed | 2024-04-12T09:23:05Z |
| publishDate | 2022-05-01 |
| publisher | KeAi Communications Co. Ltd. |
| record_format | Article |
| series | Green Synthesis and Catalysis |
| spelling | doaj.art-cb6f5f7cc2bd48ffa7d5c3fb42437b402022-12-22T03:38:34ZengKeAi Communications Co. Ltd.Green Synthesis and Catalysis2666-55492022-05-0132194197Carbon-oxygen bond formation via visible-light-induced O–H insertion between acylsilanes and oximesBao Gui Cai0Qian Li1Lei Li2Jun Xuan3Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials and Key Laboratory of Functional Inorganic Materials of Anhui Province, College of Chemistry & Chemical Engineering, Anhui University, Hefei 230601, ChinaAnhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials and Key Laboratory of Functional Inorganic Materials of Anhui Province, College of Chemistry & Chemical Engineering, Anhui University, Hefei 230601, ChinaAnhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials and Key Laboratory of Functional Inorganic Materials of Anhui Province, College of Chemistry & Chemical Engineering, Anhui University, Hefei 230601, ChinaAnhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials and Key Laboratory of Functional Inorganic Materials of Anhui Province, College of Chemistry & Chemical Engineering, Anhui University, Hefei 230601, China; Key Laboratory of Structure and Functional Regulation of Hybrid Materials (Anhui University), Ministry of Education, Hefei 230601, China; Corresponding author. Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials and Key Laboratory of Functional Inorganic Materials of Anhui Province, College of Chemistry & Chemical Engineering, Anhui University, Hefei 230601, China.Visible light promoted C–O bond formation reaction through O–H insertion of acylsilanes with oximes has been developed. The reaction occurred under mild reaction conditions (sole blue LED irradiation in the absence of any catalysts or additives) with a short reaction time and afforded the corresponding oxime ethers in moderate to good yields.http://www.sciencedirect.com/science/article/pii/S2666554921001137Visible lightAcylsilanesSiloxy carbeneOximesC–O bond formation |
| spellingShingle | Bao Gui Cai Qian Li Lei Li Jun Xuan Carbon-oxygen bond formation via visible-light-induced O–H insertion between acylsilanes and oximes Green Synthesis and Catalysis Visible light Acylsilanes Siloxy carbene Oximes C–O bond formation |
| title | Carbon-oxygen bond formation via visible-light-induced O–H insertion between acylsilanes and oximes |
| title_full | Carbon-oxygen bond formation via visible-light-induced O–H insertion between acylsilanes and oximes |
| title_fullStr | Carbon-oxygen bond formation via visible-light-induced O–H insertion between acylsilanes and oximes |
| title_full_unstemmed | Carbon-oxygen bond formation via visible-light-induced O–H insertion between acylsilanes and oximes |
| title_short | Carbon-oxygen bond formation via visible-light-induced O–H insertion between acylsilanes and oximes |
| title_sort | carbon oxygen bond formation via visible light induced o h insertion between acylsilanes and oximes |
| topic | Visible light Acylsilanes Siloxy carbene Oximes C–O bond formation |
| url | http://www.sciencedirect.com/science/article/pii/S2666554921001137 |
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