Excess Enthalpies for Binary Mixtures of the Reactive System Acetic Acid + n-Butanol + n-Butyl Acetate + Water: Brief Data Review and Results at 313.15 K and Atmospheric Pressure
The data on molar excess enthalpies, <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msubsup><mi>H</mi><mi>m</mi><mi>E</mi></msubsup></mrow></seman...
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| Format: | Article |
| Language: | English |
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MDPI AG
2023-03-01
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| Series: | International Journal of Molecular Sciences |
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| Online Access: | https://www.mdpi.com/1422-0067/24/6/5137 |
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| author | Alexandra Golikova Anna Shasherina Yuri Anufrikov Georgii Misikov Maria Toikka Irina Zvereva Alexander Toikka |
| author_facet | Alexandra Golikova Anna Shasherina Yuri Anufrikov Georgii Misikov Maria Toikka Irina Zvereva Alexander Toikka |
| author_sort | Alexandra Golikova |
| collection | DOAJ |
| description | The data on molar excess enthalpies, <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msubsup><mi>H</mi><mi>m</mi><mi>E</mi></msubsup></mrow></semantics></math></inline-formula>, for the binary mixtures acetic acid + n-butanol, acetic acid + n-butyl acetate and n-butanol + n-butyl acetate at 313.15 K and atmospheric pressure were obtained with use of the C80 isothermal mixing calorimeter (Setaram). The correlation of the data was carried out using the NRTL model and Redlich–Kister equation. A comparative analysis with the literature data on all available binary subsystems of the quaternary system was carried out. Other thermodynamic properties (<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msubsup><mi>C</mi><mrow><mi>p</mi><mo>,</mo><mi>m</mi></mrow><mi>E</mi></msubsup></mrow></semantics></math></inline-formula>, <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msubsup><mi>S</mi><mi>m</mi><mi>E</mi></msubsup></mrow></semantics></math></inline-formula>, <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msub><mo>Δ</mo><mrow><mi>m</mi><mi>i</mi><mi>x</mi></mrow></msub><msub><mi>S</mi><mi>m</mi></msub></mrow></semantics></math></inline-formula>, <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msubsup><mi>G</mi><mi>m</mi><mi>E</mi></msubsup></mrow></semantics></math></inline-formula> and <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msub><mo>Δ</mo><mrow><mi>m</mi><mi>i</mi><mi>x</mi></mrow></msub><msub><mi>G</mi><mi>m</mi></msub></mrow></semantics></math></inline-formula>) of the binary systems were estimated using literature data and well-known formulas of classical thermodynamics. |
| first_indexed | 2024-03-11T06:27:27Z |
| format | Article |
| id | doaj.art-cb862680755c48f48931d6be6ee077f8 |
| institution | Directory Open Access Journal |
| issn | 1661-6596 1422-0067 |
| language | English |
| last_indexed | 2024-03-11T06:27:27Z |
| publishDate | 2023-03-01 |
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| series | International Journal of Molecular Sciences |
| spelling | doaj.art-cb862680755c48f48931d6be6ee077f82023-11-17T11:29:37ZengMDPI AGInternational Journal of Molecular Sciences1661-65961422-00672023-03-01246513710.3390/ijms24065137Excess Enthalpies for Binary Mixtures of the Reactive System Acetic Acid + n-Butanol + n-Butyl Acetate + Water: Brief Data Review and Results at 313.15 K and Atmospheric PressureAlexandra Golikova0Anna Shasherina1Yuri Anufrikov2Georgii Misikov3Maria Toikka4Irina Zvereva5Alexander Toikka6Institute of Chemistry, St. Petersburg State University, Universitetskiy Prospect 26, Peterhof, Saint Petersburg 198504, RussiaInstitute of Chemistry, St. Petersburg State University, Universitetskiy Prospect 26, Peterhof, Saint Petersburg 198504, RussiaInstitute of Chemistry, St. Petersburg State University, Universitetskiy Prospect 26, Peterhof, Saint Petersburg 198504, RussiaInstitute of Chemistry, St. Petersburg State University, Universitetskiy Prospect 26, Peterhof, Saint Petersburg 198504, RussiaInstitute of Chemistry, St. Petersburg State University, Universitetskiy Prospect 26, Peterhof, Saint Petersburg 198504, RussiaInstitute of Chemistry, St. Petersburg State University, Universitetskiy Prospect 26, Peterhof, Saint Petersburg 198504, RussiaInstitute of Chemistry, St. Petersburg State University, Universitetskiy Prospect 26, Peterhof, Saint Petersburg 198504, RussiaThe data on molar excess enthalpies, <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msubsup><mi>H</mi><mi>m</mi><mi>E</mi></msubsup></mrow></semantics></math></inline-formula>, for the binary mixtures acetic acid + n-butanol, acetic acid + n-butyl acetate and n-butanol + n-butyl acetate at 313.15 K and atmospheric pressure were obtained with use of the C80 isothermal mixing calorimeter (Setaram). The correlation of the data was carried out using the NRTL model and Redlich–Kister equation. A comparative analysis with the literature data on all available binary subsystems of the quaternary system was carried out. Other thermodynamic properties (<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msubsup><mi>C</mi><mrow><mi>p</mi><mo>,</mo><mi>m</mi></mrow><mi>E</mi></msubsup></mrow></semantics></math></inline-formula>, <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msubsup><mi>S</mi><mi>m</mi><mi>E</mi></msubsup></mrow></semantics></math></inline-formula>, <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msub><mo>Δ</mo><mrow><mi>m</mi><mi>i</mi><mi>x</mi></mrow></msub><msub><mi>S</mi><mi>m</mi></msub></mrow></semantics></math></inline-formula>, <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msubsup><mi>G</mi><mi>m</mi><mi>E</mi></msubsup></mrow></semantics></math></inline-formula> and <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msub><mo>Δ</mo><mrow><mi>m</mi><mi>i</mi><mi>x</mi></mrow></msub><msub><mi>G</mi><mi>m</mi></msub></mrow></semantics></math></inline-formula>) of the binary systems were estimated using literature data and well-known formulas of classical thermodynamics.https://www.mdpi.com/1422-0067/24/6/5137heat of mixingcalorimetryn-butyl acetatethermochemistryRedlich–Kister equationNRTL |
| spellingShingle | Alexandra Golikova Anna Shasherina Yuri Anufrikov Georgii Misikov Maria Toikka Irina Zvereva Alexander Toikka Excess Enthalpies for Binary Mixtures of the Reactive System Acetic Acid + n-Butanol + n-Butyl Acetate + Water: Brief Data Review and Results at 313.15 K and Atmospheric Pressure International Journal of Molecular Sciences heat of mixing calorimetry n-butyl acetate thermochemistry Redlich–Kister equation NRTL |
| title | Excess Enthalpies for Binary Mixtures of the Reactive System Acetic Acid + n-Butanol + n-Butyl Acetate + Water: Brief Data Review and Results at 313.15 K and Atmospheric Pressure |
| title_full | Excess Enthalpies for Binary Mixtures of the Reactive System Acetic Acid + n-Butanol + n-Butyl Acetate + Water: Brief Data Review and Results at 313.15 K and Atmospheric Pressure |
| title_fullStr | Excess Enthalpies for Binary Mixtures of the Reactive System Acetic Acid + n-Butanol + n-Butyl Acetate + Water: Brief Data Review and Results at 313.15 K and Atmospheric Pressure |
| title_full_unstemmed | Excess Enthalpies for Binary Mixtures of the Reactive System Acetic Acid + n-Butanol + n-Butyl Acetate + Water: Brief Data Review and Results at 313.15 K and Atmospheric Pressure |
| title_short | Excess Enthalpies for Binary Mixtures of the Reactive System Acetic Acid + n-Butanol + n-Butyl Acetate + Water: Brief Data Review and Results at 313.15 K and Atmospheric Pressure |
| title_sort | excess enthalpies for binary mixtures of the reactive system acetic acid n butanol n butyl acetate water brief data review and results at 313 15 k and atmospheric pressure |
| topic | heat of mixing calorimetry n-butyl acetate thermochemistry Redlich–Kister equation NRTL |
| url | https://www.mdpi.com/1422-0067/24/6/5137 |
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