[1-(4-Hydroxy-2-oxidobenzylidene)-4-phenylthiosemicarbazonato-κ3N,O,S](1,10-phenanthroline-κ2N,N′)zinc(II)–4,4′-bipyridine (2/1)

[1-(4-Hydroxy-2-oxidobenzylidene)-4-phenylthiosemicarbazonato-κ3N,O,S](1,10-phenanthroline-κ2N,N′)zinc(II)–4,4′-bipyridine (2/1)

The ZnII atom in the title compound, [Zn(C14H11N3O2S)(C12H8N2)]·0.5C10H8N2, is N,N′-chelated by the N-heterocycle and N,O,S-chelated by the deprotonated Schiff base in a square-pyramidal environment. The hydroxy group of the Schiff base is a hydrogen-bond donor to 4,4&...

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Bibliographic Details
Main Authors: Seik Weng Ng, Mohd Jamil Maah, Kong Wai Tan, Chew Hee Ng
Format: Article
Language:English
Published: International Union of Crystallography 2009-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809026245
Description
Summary:The ZnII atom in the title compound, [Zn(C14H11N3O2S)(C12H8N2)]·0.5C10H8N2, is N,N′-chelated by the N-heterocycle and N,O,S-chelated by the deprotonated Schiff base in a square-pyramidal environment. The hydroxy group of the Schiff base is a hydrogen-bond donor to 4,4′-bipyridine, which is located about a center of inversion, resulting in the formation of a supramolecular trimeric unit.
ISSN:1600-5368

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