[1-(4-Hydroxy-2-oxidobenzylidene)-4-phenylthiosemicarbazonato-κ3N,O,S](1,10-phenanthroline-κ2N,N′)zinc(II)–4,4′-bipyridine (2/1)
The ZnII atom in the title compound, [Zn(C14H11N3O2S)(C12H8N2)]·0.5C10H8N2, is N,N′-chelated by the N-heterocycle and N,O,S-chelated by the deprotonated Schiff base in a square-pyramidal environment. The hydroxy group of the Schiff base is a hydrogen-bond donor to 4,4&...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-08-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809026245 |
| _version_ | 1818896483158589440 |
|---|---|
| author | Seik Weng Ng Mohd Jamil Maah Kong Wai Tan Chew Hee Ng |
| author_facet | Seik Weng Ng Mohd Jamil Maah Kong Wai Tan Chew Hee Ng |
| author_sort | Seik Weng Ng |
| collection | DOAJ |
| description | The ZnII atom in the title compound, [Zn(C14H11N3O2S)(C12H8N2)]·0.5C10H8N2, is N,N′-chelated by the N-heterocycle and N,O,S-chelated by the deprotonated Schiff base in a square-pyramidal environment. The hydroxy group of the Schiff base is a hydrogen-bond donor to 4,4′-bipyridine, which is located about a center of inversion, resulting in the formation of a supramolecular trimeric unit. |
| first_indexed | 2024-12-19T19:01:00Z |
| format | Article |
| id | doaj.art-cb8647594be14e0397ed5746bba93fae |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-19T19:01:00Z |
| publishDate | 2009-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-cb8647594be14e0397ed5746bba93fae2022-12-21T20:09:33ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-08-01658m920m92010.1107/S1600536809026245[1-(4-Hydroxy-2-oxidobenzylidene)-4-phenylthiosemicarbazonato-κ3N,O,S](1,10-phenanthroline-κ2N,N′)zinc(II)–4,4′-bipyridine (2/1)Seik Weng NgMohd Jamil MaahKong Wai TanChew Hee NgThe ZnII atom in the title compound, [Zn(C14H11N3O2S)(C12H8N2)]·0.5C10H8N2, is N,N′-chelated by the N-heterocycle and N,O,S-chelated by the deprotonated Schiff base in a square-pyramidal environment. The hydroxy group of the Schiff base is a hydrogen-bond donor to 4,4′-bipyridine, which is located about a center of inversion, resulting in the formation of a supramolecular trimeric unit.http://scripts.iucr.org/cgi-bin/paper?S1600536809026245 |
| spellingShingle | Seik Weng Ng Mohd Jamil Maah Kong Wai Tan Chew Hee Ng [1-(4-Hydroxy-2-oxidobenzylidene)-4-phenylthiosemicarbazonato-κ3N,O,S](1,10-phenanthroline-κ2N,N′)zinc(II)–4,4′-bipyridine (2/1) Acta Crystallographica Section E |
| title | [1-(4-Hydroxy-2-oxidobenzylidene)-4-phenylthiosemicarbazonato-κ3N,O,S](1,10-phenanthroline-κ2N,N′)zinc(II)–4,4′-bipyridine (2/1) |
| title_full | [1-(4-Hydroxy-2-oxidobenzylidene)-4-phenylthiosemicarbazonato-κ3N,O,S](1,10-phenanthroline-κ2N,N′)zinc(II)–4,4′-bipyridine (2/1) |
| title_fullStr | [1-(4-Hydroxy-2-oxidobenzylidene)-4-phenylthiosemicarbazonato-κ3N,O,S](1,10-phenanthroline-κ2N,N′)zinc(II)–4,4′-bipyridine (2/1) |
| title_full_unstemmed | [1-(4-Hydroxy-2-oxidobenzylidene)-4-phenylthiosemicarbazonato-κ3N,O,S](1,10-phenanthroline-κ2N,N′)zinc(II)–4,4′-bipyridine (2/1) |
| title_short | [1-(4-Hydroxy-2-oxidobenzylidene)-4-phenylthiosemicarbazonato-κ3N,O,S](1,10-phenanthroline-κ2N,N′)zinc(II)–4,4′-bipyridine (2/1) |
| title_sort | 1 4 hydroxy 2 oxidobenzylidene 4 phenylthiosemicarbazonato amp 954 3n o s 1 10 phenanthroline amp 954 2n n amp 8242 zinc ii amp 8211 4 4 amp 8242 bipyridine 2 1 |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809026245 |
| work_keys_str_mv | AT seikwengng 14hydroxy2oxidobenzylidene4phenylthiosemicarbazonatoamp9543nos110phenanthrolineamp9542nnamp8242zinciiamp821144amp8242bipyridine21 AT mohdjamilmaah 14hydroxy2oxidobenzylidene4phenylthiosemicarbazonatoamp9543nos110phenanthrolineamp9542nnamp8242zinciiamp821144amp8242bipyridine21 AT kongwaitan 14hydroxy2oxidobenzylidene4phenylthiosemicarbazonatoamp9543nos110phenanthrolineamp9542nnamp8242zinciiamp821144amp8242bipyridine21 AT chewheeng 14hydroxy2oxidobenzylidene4phenylthiosemicarbazonatoamp9543nos110phenanthrolineamp9542nnamp8242zinciiamp821144amp8242bipyridine21 |