Di-n-butyl{4-hydroxy-N′-[(2-oxido-1-naphthyl-κO)methylene]benzohydrazidato-κ2O,N′}tin(IV)
The deprotonated Schiff base ligand in the title compound, [Sn(C4H9)2(C18H12N2O3)], O,N,O′-chelates to the Sn atom, which is five-coordinated in a cis-C2NO2Sn trigonal-bipyramidal environment. The apical sites are occupied by the O atoms [O—Sn—O = 155.2&...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-05-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810014662 |
| _version_ | 1818323430264537088 |
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| author | Md. Abu Affan Norrihan Sam Fasihuddin Ahmad Seik Weng Ng |
| author_facet | Md. Abu Affan Norrihan Sam Fasihuddin Ahmad Seik Weng Ng |
| author_sort | Md. Abu Affan |
| collection | DOAJ |
| description | The deprotonated Schiff base ligand in the title compound, [Sn(C4H9)2(C18H12N2O3)], O,N,O′-chelates to the Sn atom, which is five-coordinated in a cis-C2NO2Sn trigonal-bipyramidal environment. The apical sites are occupied by the O atoms [O—Sn—O = 155.2 (2)°]. The hydroxy group is a hydrogen-bond donor to the two-coordinate N atom of an adjacent molecule, the hydrogen-bonding interaction giving rise to a helical chain running along the c axis. The carbon atoms of the butyl chains are equally disordered over two positions. |
| first_indexed | 2024-12-13T11:12:34Z |
| format | Article |
| id | doaj.art-cbb6cedefd48434091e324906aeb5506 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T11:12:34Z |
| publishDate | 2010-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-cbb6cedefd48434091e324906aeb55062022-12-21T23:48:42ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-05-01665m572m57210.1107/S1600536810014662Di-n-butyl{4-hydroxy-N′-[(2-oxido-1-naphthyl-κO)methylene]benzohydrazidato-κ2O,N′}tin(IV)Md. Abu AffanNorrihan SamFasihuddin AhmadSeik Weng NgThe deprotonated Schiff base ligand in the title compound, [Sn(C4H9)2(C18H12N2O3)], O,N,O′-chelates to the Sn atom, which is five-coordinated in a cis-C2NO2Sn trigonal-bipyramidal environment. The apical sites are occupied by the O atoms [O—Sn—O = 155.2 (2)°]. The hydroxy group is a hydrogen-bond donor to the two-coordinate N atom of an adjacent molecule, the hydrogen-bonding interaction giving rise to a helical chain running along the c axis. The carbon atoms of the butyl chains are equally disordered over two positions.http://scripts.iucr.org/cgi-bin/paper?S1600536810014662 |
| spellingShingle | Md. Abu Affan Norrihan Sam Fasihuddin Ahmad Seik Weng Ng Di-n-butyl{4-hydroxy-N′-[(2-oxido-1-naphthyl-κO)methylene]benzohydrazidato-κ2O,N′}tin(IV) Acta Crystallographica Section E |
| title | Di-n-butyl{4-hydroxy-N′-[(2-oxido-1-naphthyl-κO)methylene]benzohydrazidato-κ2O,N′}tin(IV) |
| title_full | Di-n-butyl{4-hydroxy-N′-[(2-oxido-1-naphthyl-κO)methylene]benzohydrazidato-κ2O,N′}tin(IV) |
| title_fullStr | Di-n-butyl{4-hydroxy-N′-[(2-oxido-1-naphthyl-κO)methylene]benzohydrazidato-κ2O,N′}tin(IV) |
| title_full_unstemmed | Di-n-butyl{4-hydroxy-N′-[(2-oxido-1-naphthyl-κO)methylene]benzohydrazidato-κ2O,N′}tin(IV) |
| title_short | Di-n-butyl{4-hydroxy-N′-[(2-oxido-1-naphthyl-κO)methylene]benzohydrazidato-κ2O,N′}tin(IV) |
| title_sort | di n butyl 4 hydroxy n amp 8242 2 oxido 1 naphthyl amp 954 o methylene benzohydrazidato amp 954 2o n amp 8242 tin iv |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810014662 |
| work_keys_str_mv | AT mdabuaffan dinbutyl4hydroxynamp82422oxido1naphthylamp954omethylenebenzohydrazidatoamp9542onamp8242tiniv AT norrihansam dinbutyl4hydroxynamp82422oxido1naphthylamp954omethylenebenzohydrazidatoamp9542onamp8242tiniv AT fasihuddinahmad dinbutyl4hydroxynamp82422oxido1naphthylamp954omethylenebenzohydrazidatoamp9542onamp8242tiniv AT seikwengng dinbutyl4hydroxynamp82422oxido1naphthylamp954omethylenebenzohydrazidatoamp9542onamp8242tiniv |