Crystal structure of bis{2,4-di-tert-butyl-6-[(isopropylimino)methyl]phenolato-κ2N,O}zinc dichloromethane monosolvate
In the title compound, [Zn(C18H28NO)2]·CH2Cl2, the ZnII atom is N,O-chelated by two crystallographically independent salicylaldehyde imine ligands, leading to a distorted tetrahedral coordination sphere. The dihedral angle between the planes of the two metallacycles is 88.69 (6)°. Intramolecular non...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2014-12-01
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| Series: | Acta Crystallographica Section E |
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536814022636 |
| Summary: | In the title compound, [Zn(C18H28NO)2]·CH2Cl2, the ZnII atom is N,O-chelated by two crystallographically independent salicylaldehyde imine ligands, leading to a distorted tetrahedral coordination sphere. The dihedral angle between the planes of the two metallacycles is 88.69 (6)°. Intramolecular non-classical C—H...O hydrogen-bonding interactions are observed. In the crystal, the complex molecules stack into columns along the a axis. Dichloromethane solvent molecules are situated in the voids of this arrangement. |
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| ISSN: | 1600-5368 |