Crystal structure of bis{2,4-di-tert-butyl-6-[(isopropylimino)methyl]phenolato-κ2N,O}zinc dichloromethane monosolvate
In the title compound, [Zn(C18H28NO)2]·CH2Cl2, the ZnII atom is N,O-chelated by two crystallographically independent salicylaldehyde imine ligands, leading to a distorted tetrahedral coordination sphere. The dihedral angle between the planes of the two metallacycles is 88.69 (6)°. Intramolecular non...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2014-12-01
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| Series: | Acta Crystallographica Section E |
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536814022636 |
| _version_ | 1818958287117221888 |
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| author | Yuan-Zeng Hao |
| author_facet | Yuan-Zeng Hao |
| author_sort | Yuan-Zeng Hao |
| collection | DOAJ |
| description | In the title compound, [Zn(C18H28NO)2]·CH2Cl2, the ZnII atom is N,O-chelated by two crystallographically independent salicylaldehyde imine ligands, leading to a distorted tetrahedral coordination sphere. The dihedral angle between the planes of the two metallacycles is 88.69 (6)°. Intramolecular non-classical C—H...O hydrogen-bonding interactions are observed. In the crystal, the complex molecules stack into columns along the a axis. Dichloromethane solvent molecules are situated in the voids of this arrangement. |
| first_indexed | 2024-12-20T11:23:21Z |
| format | Article |
| id | doaj.art-cbc3bd697b8346aea75fccf92b126ae4 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T11:23:21Z |
| publishDate | 2014-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-cbc3bd697b8346aea75fccf92b126ae42022-12-21T19:42:26ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-12-017012m390m39110.1107/S1600536814022636wm5038Crystal structure of bis{2,4-di-tert-butyl-6-[(isopropylimino)methyl]phenolato-κ2N,O}zinc dichloromethane monosolvateYuan-Zeng Hao0Guangzhou Super-Dragon Engineering Plastics Co. Ltd, People's Republic of ChinaIn the title compound, [Zn(C18H28NO)2]·CH2Cl2, the ZnII atom is N,O-chelated by two crystallographically independent salicylaldehyde imine ligands, leading to a distorted tetrahedral coordination sphere. The dihedral angle between the planes of the two metallacycles is 88.69 (6)°. Intramolecular non-classical C—H...O hydrogen-bonding interactions are observed. In the crystal, the complex molecules stack into columns along the a axis. Dichloromethane solvent molecules are situated in the voids of this arrangement.http://scripts.iucr.org/cgi-bin/paper?S1600536814022636crystal structureSchiff basezinctetrahedral coordination |
| spellingShingle | Yuan-Zeng Hao Crystal structure of bis{2,4-di-tert-butyl-6-[(isopropylimino)methyl]phenolato-κ2N,O}zinc dichloromethane monosolvate Acta Crystallographica Section E crystal structure Schiff base zinc tetrahedral coordination |
| title | Crystal structure of bis{2,4-di-tert-butyl-6-[(isopropylimino)methyl]phenolato-κ2N,O}zinc dichloromethane monosolvate |
| title_full | Crystal structure of bis{2,4-di-tert-butyl-6-[(isopropylimino)methyl]phenolato-κ2N,O}zinc dichloromethane monosolvate |
| title_fullStr | Crystal structure of bis{2,4-di-tert-butyl-6-[(isopropylimino)methyl]phenolato-κ2N,O}zinc dichloromethane monosolvate |
| title_full_unstemmed | Crystal structure of bis{2,4-di-tert-butyl-6-[(isopropylimino)methyl]phenolato-κ2N,O}zinc dichloromethane monosolvate |
| title_short | Crystal structure of bis{2,4-di-tert-butyl-6-[(isopropylimino)methyl]phenolato-κ2N,O}zinc dichloromethane monosolvate |
| title_sort | crystal structure of bis 2 4 di tert butyl 6 isopropylimino methyl phenolato κ2n o zinc dichloromethane monosolvate |
| topic | crystal structure Schiff base zinc tetrahedral coordination |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536814022636 |
| work_keys_str_mv | AT yuanzenghao crystalstructureofbis24ditertbutyl6isopropyliminomethylphenolatok2nozincdichloromethanemonosolvate |