Dicyanidobis(N,N′-dimethythiourea-κS)mercury(II)
In the title complex, [Hg(CN)2(C3H8N2S)2], the HgII atom is located on a twofold rotation axis. It is four-coordinate having an irregular tetrahedral geometry composed of two cyanide C atoms [Hg—C = 2.090 (6) Å] and two thione S atoms of N,N&...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-09-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810030424 |
| _version_ | 1818945864912076800 |
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| author | Muhammad Riaz Malik Saqib Ali Saeed Ahmad Muhammad Altaf Helen Stoeckli-Evans |
| author_facet | Muhammad Riaz Malik Saqib Ali Saeed Ahmad Muhammad Altaf Helen Stoeckli-Evans |
| author_sort | Muhammad Riaz Malik |
| collection | DOAJ |
| description | In the title complex, [Hg(CN)2(C3H8N2S)2], the HgII atom is located on a twofold rotation axis. It is four-coordinate having an irregular tetrahedral geometry composed of two cyanide C atoms [Hg—C = 2.090 (6) Å] and two thione S atoms of N,N′-dimethylthiourea (dmtu) [Hg—S = 2.7114 (9) Å]. The NC—Hg—CN bond angle of 148.83 (13)° has the greatest deviation from the ideal tetrahedral geometry. The molecular structure is stabilized by intramolecular N—H...S interactions involving dmtu units related by the twofold symmetry. In the crystal, intermolecular N—H...N(CN) hydrogen-bonding interactions link symmetry-related molecules into a two-dimensional network in (110). |
| first_indexed | 2024-12-20T08:05:54Z |
| format | Article |
| id | doaj.art-cbd97b7ad0634946b44225dfe73a2a85 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T08:05:54Z |
| publishDate | 2010-09-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-cbd97b7ad0634946b44225dfe73a2a852022-12-21T19:47:25ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-09-01669m1060m106110.1107/S1600536810030424Dicyanidobis(N,N′-dimethythiourea-κS)mercury(II)Muhammad Riaz MalikSaqib AliSaeed AhmadMuhammad AltafHelen Stoeckli-EvansIn the title complex, [Hg(CN)2(C3H8N2S)2], the HgII atom is located on a twofold rotation axis. It is four-coordinate having an irregular tetrahedral geometry composed of two cyanide C atoms [Hg—C = 2.090 (6) Å] and two thione S atoms of N,N′-dimethylthiourea (dmtu) [Hg—S = 2.7114 (9) Å]. The NC—Hg—CN bond angle of 148.83 (13)° has the greatest deviation from the ideal tetrahedral geometry. The molecular structure is stabilized by intramolecular N—H...S interactions involving dmtu units related by the twofold symmetry. In the crystal, intermolecular N—H...N(CN) hydrogen-bonding interactions link symmetry-related molecules into a two-dimensional network in (110).http://scripts.iucr.org/cgi-bin/paper?S1600536810030424 |
| spellingShingle | Muhammad Riaz Malik Saqib Ali Saeed Ahmad Muhammad Altaf Helen Stoeckli-Evans Dicyanidobis(N,N′-dimethythiourea-κS)mercury(II) Acta Crystallographica Section E |
| title | Dicyanidobis(N,N′-dimethythiourea-κS)mercury(II) |
| title_full | Dicyanidobis(N,N′-dimethythiourea-κS)mercury(II) |
| title_fullStr | Dicyanidobis(N,N′-dimethythiourea-κS)mercury(II) |
| title_full_unstemmed | Dicyanidobis(N,N′-dimethythiourea-κS)mercury(II) |
| title_short | Dicyanidobis(N,N′-dimethythiourea-κS)mercury(II) |
| title_sort | dicyanidobis n n amp 8242 dimethythiourea amp 954 s mercury ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810030424 |
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