Fused Deposition Modeling of ABS-Barium Titanate Composites: A Simple Route towards Tailored Dielectric Devices

A process for the development, characterization and correlation of composite materials for 3D printing is presented, alongside the processing of a polymer-ceramic functional composite using fused deposition modeling (FDM). The composite was developed using acrylonitrile butadiene styrene (ABS) as th...

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Main Authors: Bilal Khatri, Karl Lappe, Mathis Habedank, Tobias Mueller, Christof Megnin, Thomas Hanemann
Format: Article
Language:English
Published: MDPI AG 2018-06-01
Series:Polymers
Subjects:
Online Access:http://www.mdpi.com/2073-4360/10/6/666
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author Bilal Khatri
Karl Lappe
Mathis Habedank
Tobias Mueller
Christof Megnin
Thomas Hanemann
author_facet Bilal Khatri
Karl Lappe
Mathis Habedank
Tobias Mueller
Christof Megnin
Thomas Hanemann
author_sort Bilal Khatri
collection DOAJ
description A process for the development, characterization and correlation of composite materials for 3D printing is presented, alongside the processing of a polymer-ceramic functional composite using fused deposition modeling (FDM). The composite was developed using acrylonitrile butadiene styrene (ABS) as the matrix material filled with barium titanate (BT) micro-powder up to 35 vol % (74.2 wt %). The ABS-BT composites exhibited a shear thinning behavior with increasing ceramic content. The composite was 3D printed into structural and functional test samples using FDM by adapting and optimizing the print parameters. Structural characterization revealed increasingly brittle behavior at higher filler ratios, with the ultimate tensile strength falling from 25.5 MPa for pure ABS to 13.7 MPa for the ABS-35 vol % BT composite. Four-point flexural tests showed a similar decrease in flexural strength with increasing ceramic content. Functional characterization revealed an increase in the relative permittivity at 200 kHz from 3.08 for pure ABS to 11.5 for the composite with 35 vol % BT. These results were correlated with the Maxwell-Garnett and Jayasundere-Smith effective medium models. The process described in this work can be used for other 3D printing processes and provides a framework for the rapid prototyping of functional composites into functional parts with reliable properties. The ABS-BT composite shows promise as a functional dielectric material, with potential applications as capacitors and light-weight passive antennas.
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spelling doaj.art-cbe36ab99fc44a62935fa8a7532d48762022-12-22T03:20:01ZengMDPI AGPolymers2073-43602018-06-0110666610.3390/polym10060666polym10060666Fused Deposition Modeling of ABS-Barium Titanate Composites: A Simple Route towards Tailored Dielectric DevicesBilal Khatri0Karl Lappe1Mathis Habedank2Tobias Mueller3Christof Megnin4Thomas Hanemann5Laboratory for Materials Processing, University of Freiburg, 79110 Freiburg, GermanyLaboratory for Materials Processing, University of Freiburg, 79110 Freiburg, GermanyLaboratory for Materials Processing, University of Freiburg, 79110 Freiburg, GermanyInstitute of Automation and Applied Informatics, Karlsruhe Institute of Technology, 76344 Eggenstein-Leopoldshafen, GermanyInstitute of Applied Materials, Karlsruhe Institute of Technology, 76344 Eggenstein-Leopoldshafen, GermanyLaboratory for Materials Processing, University of Freiburg, 79110 Freiburg, GermanyA process for the development, characterization and correlation of composite materials for 3D printing is presented, alongside the processing of a polymer-ceramic functional composite using fused deposition modeling (FDM). The composite was developed using acrylonitrile butadiene styrene (ABS) as the matrix material filled with barium titanate (BT) micro-powder up to 35 vol % (74.2 wt %). The ABS-BT composites exhibited a shear thinning behavior with increasing ceramic content. The composite was 3D printed into structural and functional test samples using FDM by adapting and optimizing the print parameters. Structural characterization revealed increasingly brittle behavior at higher filler ratios, with the ultimate tensile strength falling from 25.5 MPa for pure ABS to 13.7 MPa for the ABS-35 vol % BT composite. Four-point flexural tests showed a similar decrease in flexural strength with increasing ceramic content. Functional characterization revealed an increase in the relative permittivity at 200 kHz from 3.08 for pure ABS to 11.5 for the composite with 35 vol % BT. These results were correlated with the Maxwell-Garnett and Jayasundere-Smith effective medium models. The process described in this work can be used for other 3D printing processes and provides a framework for the rapid prototyping of functional composites into functional parts with reliable properties. The ABS-BT composite shows promise as a functional dielectric material, with potential applications as capacitors and light-weight passive antennas.http://www.mdpi.com/2073-4360/10/6/666rapid prototypingpolymer-ceramic compositesfused deposition modelingmaterial characterizationmechanical characterizationdielectric characterization
spellingShingle Bilal Khatri
Karl Lappe
Mathis Habedank
Tobias Mueller
Christof Megnin
Thomas Hanemann
Fused Deposition Modeling of ABS-Barium Titanate Composites: A Simple Route towards Tailored Dielectric Devices
Polymers
rapid prototyping
polymer-ceramic composites
fused deposition modeling
material characterization
mechanical characterization
dielectric characterization
title Fused Deposition Modeling of ABS-Barium Titanate Composites: A Simple Route towards Tailored Dielectric Devices
title_full Fused Deposition Modeling of ABS-Barium Titanate Composites: A Simple Route towards Tailored Dielectric Devices
title_fullStr Fused Deposition Modeling of ABS-Barium Titanate Composites: A Simple Route towards Tailored Dielectric Devices
title_full_unstemmed Fused Deposition Modeling of ABS-Barium Titanate Composites: A Simple Route towards Tailored Dielectric Devices
title_short Fused Deposition Modeling of ABS-Barium Titanate Composites: A Simple Route towards Tailored Dielectric Devices
title_sort fused deposition modeling of abs barium titanate composites a simple route towards tailored dielectric devices
topic rapid prototyping
polymer-ceramic composites
fused deposition modeling
material characterization
mechanical characterization
dielectric characterization
url http://www.mdpi.com/2073-4360/10/6/666
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