In situ monitoring of electroactive species by using voltammetry at microelectrodes
Mercury coated platinum microelectrodes were employed for the in situ determination, in soils and porewater of sediments, of redox key species of environmental interest. Sand samples were considered as soil model for the in situ detection of oxygen. Direct measurements of sulphide were performed in...
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Format: | Article |
Language: | English |
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Sociedade Brasileira de Química
2002-01-01
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Series: | Journal of the Brazilian Chemical Society |
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Online Access: | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532002000400004 |
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author | Daniele Salvatore Baldo M. Antonietta Bragato Carlo |
author_facet | Daniele Salvatore Baldo M. Antonietta Bragato Carlo |
author_sort | Daniele Salvatore |
collection | DOAJ |
description | Mercury coated platinum microelectrodes were employed for the in situ determination, in soils and porewater of sediments, of redox key species of environmental interest. Sand samples were considered as soil model for the in situ detection of oxygen. Direct measurements of sulphide were performed in anoxic sediments collected in the Lagoon of Venice. An investigation on the interaction among heavy metals, sulphide and solid particles in pore-water extracted from the sediments was also performed. For the quantification of the various electroactive species examined, calibrantioless procedures were employed. |
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format | Article |
id | doaj.art-cc0eff8497eb4181b554bd77833464b0 |
institution | Directory Open Access Journal |
issn | 0103-5053 |
language | English |
last_indexed | 2024-12-12T03:29:18Z |
publishDate | 2002-01-01 |
publisher | Sociedade Brasileira de Química |
record_format | Article |
series | Journal of the Brazilian Chemical Society |
spelling | doaj.art-cc0eff8497eb4181b554bd77833464b02022-12-22T00:39:58ZengSociedade Brasileira de QuímicaJournal of the Brazilian Chemical Society0103-50532002-01-01134425432In situ monitoring of electroactive species by using voltammetry at microelectrodesDaniele SalvatoreBaldo M. AntoniettaBragato CarloMercury coated platinum microelectrodes were employed for the in situ determination, in soils and porewater of sediments, of redox key species of environmental interest. Sand samples were considered as soil model for the in situ detection of oxygen. Direct measurements of sulphide were performed in anoxic sediments collected in the Lagoon of Venice. An investigation on the interaction among heavy metals, sulphide and solid particles in pore-water extracted from the sediments was also performed. For the quantification of the various electroactive species examined, calibrantioless procedures were employed.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532002000400004mercury microelectrodessoilssedimentsoxygensulphideheavy metals |
spellingShingle | Daniele Salvatore Baldo M. Antonietta Bragato Carlo In situ monitoring of electroactive species by using voltammetry at microelectrodes Journal of the Brazilian Chemical Society mercury microelectrodes soils sediments oxygen sulphide heavy metals |
title | In situ monitoring of electroactive species by using voltammetry at microelectrodes |
title_full | In situ monitoring of electroactive species by using voltammetry at microelectrodes |
title_fullStr | In situ monitoring of electroactive species by using voltammetry at microelectrodes |
title_full_unstemmed | In situ monitoring of electroactive species by using voltammetry at microelectrodes |
title_short | In situ monitoring of electroactive species by using voltammetry at microelectrodes |
title_sort | in situ monitoring of electroactive species by using voltammetry at microelectrodes |
topic | mercury microelectrodes soils sediments oxygen sulphide heavy metals |
url | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532002000400004 |
work_keys_str_mv | AT danielesalvatore insitumonitoringofelectroactivespeciesbyusingvoltammetryatmicroelectrodes AT baldomantonietta insitumonitoringofelectroactivespeciesbyusingvoltammetryatmicroelectrodes AT bragatocarlo insitumonitoringofelectroactivespeciesbyusingvoltammetryatmicroelectrodes |