In situ monitoring of electroactive species by using voltammetry at microelectrodes

Mercury coated platinum microelectrodes were employed for the in situ determination, in soils and porewater of sediments, of redox key species of environmental interest. Sand samples were considered as soil model for the in situ detection of oxygen. Direct measurements of sulphide were performed in...

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Main Authors: Daniele Salvatore, Baldo M. Antonietta, Bragato Carlo
Format: Article
Language:English
Published: Sociedade Brasileira de Química 2002-01-01
Series:Journal of the Brazilian Chemical Society
Subjects:
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532002000400004
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author Daniele Salvatore
Baldo M. Antonietta
Bragato Carlo
author_facet Daniele Salvatore
Baldo M. Antonietta
Bragato Carlo
author_sort Daniele Salvatore
collection DOAJ
description Mercury coated platinum microelectrodes were employed for the in situ determination, in soils and porewater of sediments, of redox key species of environmental interest. Sand samples were considered as soil model for the in situ detection of oxygen. Direct measurements of sulphide were performed in anoxic sediments collected in the Lagoon of Venice. An investigation on the interaction among heavy metals, sulphide and solid particles in pore-water extracted from the sediments was also performed. For the quantification of the various electroactive species examined, calibrantioless procedures were employed.
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spelling doaj.art-cc0eff8497eb4181b554bd77833464b02022-12-22T00:39:58ZengSociedade Brasileira de QuímicaJournal of the Brazilian Chemical Society0103-50532002-01-01134425432In situ monitoring of electroactive species by using voltammetry at microelectrodesDaniele SalvatoreBaldo M. AntoniettaBragato CarloMercury coated platinum microelectrodes were employed for the in situ determination, in soils and porewater of sediments, of redox key species of environmental interest. Sand samples were considered as soil model for the in situ detection of oxygen. Direct measurements of sulphide were performed in anoxic sediments collected in the Lagoon of Venice. An investigation on the interaction among heavy metals, sulphide and solid particles in pore-water extracted from the sediments was also performed. For the quantification of the various electroactive species examined, calibrantioless procedures were employed.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532002000400004mercury microelectrodessoilssedimentsoxygensulphideheavy metals
spellingShingle Daniele Salvatore
Baldo M. Antonietta
Bragato Carlo
In situ monitoring of electroactive species by using voltammetry at microelectrodes
Journal of the Brazilian Chemical Society
mercury microelectrodes
soils
sediments
oxygen
sulphide
heavy metals
title In situ monitoring of electroactive species by using voltammetry at microelectrodes
title_full In situ monitoring of electroactive species by using voltammetry at microelectrodes
title_fullStr In situ monitoring of electroactive species by using voltammetry at microelectrodes
title_full_unstemmed In situ monitoring of electroactive species by using voltammetry at microelectrodes
title_short In situ monitoring of electroactive species by using voltammetry at microelectrodes
title_sort in situ monitoring of electroactive species by using voltammetry at microelectrodes
topic mercury microelectrodes
soils
sediments
oxygen
sulphide
heavy metals
url http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532002000400004
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AT baldomantonietta insitumonitoringofelectroactivespeciesbyusingvoltammetryatmicroelectrodes
AT bragatocarlo insitumonitoringofelectroactivespeciesbyusingvoltammetryatmicroelectrodes