Geochemical Characteristics of the Volcanic Rocks Associated with Boron-Rich Deposits from the Xiongba Basin, Qinghai–Tibet Plateau

The Qinghai–Tibet Plateau (QTP) hosts significant lacustrine sedimentary boron-rich deposits, with the Xiongba Basin being a prominent region housing two large sedimentary boron-rich deposits. These deposits are closely associated with extensive Neogene volcanic rocks. This study investigates the or...

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Main Authors: Wenxi Chen, Xifang Liu, Yuanyi Zhao, Yongjie Lin
Format: Article
Language:English
Published: MDPI AG 2023-08-01
Series:Geosciences
Subjects:
Online Access:https://www.mdpi.com/2076-3263/13/9/265
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author Wenxi Chen
Xifang Liu
Yuanyi Zhao
Yongjie Lin
author_facet Wenxi Chen
Xifang Liu
Yuanyi Zhao
Yongjie Lin
author_sort Wenxi Chen
collection DOAJ
description The Qinghai–Tibet Plateau (QTP) hosts significant lacustrine sedimentary boron-rich deposits, with the Xiongba Basin being a prominent region housing two large sedimentary boron-rich deposits. These deposits are closely associated with extensive Neogene volcanic rocks. This study investigates the origin and boron sources of Miocene volcanic rocks in the Xiangqu River area, located within the Xiongba Basin. The volcanic rocks in the basin comprise ultrapotassic andesites, ultrapotassic trachyte, potassic trachyte, and potassic trachyandeiste. The trace element content and the active/inert elements ratios of the studied volcanic rocks have indicated that they were generated in a subduction environment and were influenced by enrichment fluids derived from deep-sea sediments or altered oceanic crust during their formation. Accordingly, the studied volcanic rocks exhibit significant boron enrichment. The eruption of magma and subsequent hydrothermal activity released boron, which became the primary source for the lacustrine sedimentary boron-rich deposits within the basin. The arc-like trace element features (e.g., Nb-Ta depletion relative to La and K) and high B concentrations in these rocks were inherited from the mantle source, which had been enriched by melt/fluid of the subducted sediments. A two-stage evolutionary model is proposed to explain the enrichment of B in subduction environments, as well as the subsequent melting of the B-enriched source during a post-collisional setting. These findings highlight the potential for boron and lithium mineralization in similar volcanic rock-bearing regions across the QTP. Future exploration efforts in such areas could provide valuable insights into the formation processes of lacustrine sedimentary boron-rich deposits and contribute to the understanding of boron and lithium resource potential.
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spelling doaj.art-cc21a0ba6137471cad455ee73db181972023-11-19T10:54:45ZengMDPI AGGeosciences2076-32632023-08-0113926510.3390/geosciences13090265Geochemical Characteristics of the Volcanic Rocks Associated with Boron-Rich Deposits from the Xiongba Basin, Qinghai–Tibet PlateauWenxi Chen0Xifang Liu1Yuanyi Zhao2Yongjie Lin3MNR Key Laboratory of Saline Lake Resources and Environments, Institute of Mineral Resources, Chinese Academy of Geological Sciences, Beijing 100037, ChinaMNR Key Laboratory of Saline Lake Resources and Environments, Institute of Mineral Resources, Chinese Academy of Geological Sciences, Beijing 100037, ChinaMNR Key Laboratory of Saline Lake Resources and Environments, Institute of Mineral Resources, Chinese Academy of Geological Sciences, Beijing 100037, ChinaMNR Key Laboratory of Saline Lake Resources and Environments, Institute of Mineral Resources, Chinese Academy of Geological Sciences, Beijing 100037, ChinaThe Qinghai–Tibet Plateau (QTP) hosts significant lacustrine sedimentary boron-rich deposits, with the Xiongba Basin being a prominent region housing two large sedimentary boron-rich deposits. These deposits are closely associated with extensive Neogene volcanic rocks. This study investigates the origin and boron sources of Miocene volcanic rocks in the Xiangqu River area, located within the Xiongba Basin. The volcanic rocks in the basin comprise ultrapotassic andesites, ultrapotassic trachyte, potassic trachyte, and potassic trachyandeiste. The trace element content and the active/inert elements ratios of the studied volcanic rocks have indicated that they were generated in a subduction environment and were influenced by enrichment fluids derived from deep-sea sediments or altered oceanic crust during their formation. Accordingly, the studied volcanic rocks exhibit significant boron enrichment. The eruption of magma and subsequent hydrothermal activity released boron, which became the primary source for the lacustrine sedimentary boron-rich deposits within the basin. The arc-like trace element features (e.g., Nb-Ta depletion relative to La and K) and high B concentrations in these rocks were inherited from the mantle source, which had been enriched by melt/fluid of the subducted sediments. A two-stage evolutionary model is proposed to explain the enrichment of B in subduction environments, as well as the subsequent melting of the B-enriched source during a post-collisional setting. These findings highlight the potential for boron and lithium mineralization in similar volcanic rock-bearing regions across the QTP. Future exploration efforts in such areas could provide valuable insights into the formation processes of lacustrine sedimentary boron-rich deposits and contribute to the understanding of boron and lithium resource potential.https://www.mdpi.com/2076-3263/13/9/265Xiongba BasinNeogenevolcanic rocksgeochemical characteristicsboron source
spellingShingle Wenxi Chen
Xifang Liu
Yuanyi Zhao
Yongjie Lin
Geochemical Characteristics of the Volcanic Rocks Associated with Boron-Rich Deposits from the Xiongba Basin, Qinghai–Tibet Plateau
Geosciences
Xiongba Basin
Neogene
volcanic rocks
geochemical characteristics
boron source
title Geochemical Characteristics of the Volcanic Rocks Associated with Boron-Rich Deposits from the Xiongba Basin, Qinghai–Tibet Plateau
title_full Geochemical Characteristics of the Volcanic Rocks Associated with Boron-Rich Deposits from the Xiongba Basin, Qinghai–Tibet Plateau
title_fullStr Geochemical Characteristics of the Volcanic Rocks Associated with Boron-Rich Deposits from the Xiongba Basin, Qinghai–Tibet Plateau
title_full_unstemmed Geochemical Characteristics of the Volcanic Rocks Associated with Boron-Rich Deposits from the Xiongba Basin, Qinghai–Tibet Plateau
title_short Geochemical Characteristics of the Volcanic Rocks Associated with Boron-Rich Deposits from the Xiongba Basin, Qinghai–Tibet Plateau
title_sort geochemical characteristics of the volcanic rocks associated with boron rich deposits from the xiongba basin qinghai tibet plateau
topic Xiongba Basin
Neogene
volcanic rocks
geochemical characteristics
boron source
url https://www.mdpi.com/2076-3263/13/9/265
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AT yuanyizhao geochemicalcharacteristicsofthevolcanicrocksassociatedwithboronrichdepositsfromthexiongbabasinqinghaitibetplateau
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