Effect of Graphene on the Microstructure and Mechanical Properties of WC-Based Cemented Carbide

WC-based cemented carbides were prepared by spark plasma sintering (SPS) of WC-Co-Cr<sub>3</sub>C<sub>2</sub>-VC alloy powder by adding different contents of graphene. The phase composition, microstructure, mechanical properties, and magnetic properties of cemented carbide we...

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Main Authors: Wanzhen Qi, Zhiwei Zhao, Yanju Qian, Shijie Zhang, Hongjuan Zheng, Xiaomiao Zhao, Xinpo Lu, Shun Wang
Format: Article
Language:English
Published: MDPI AG 2023-09-01
Series:Crystals
Subjects:
Online Access:https://www.mdpi.com/2073-4352/13/10/1414
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author Wanzhen Qi
Zhiwei Zhao
Yanju Qian
Shijie Zhang
Hongjuan Zheng
Xiaomiao Zhao
Xinpo Lu
Shun Wang
author_facet Wanzhen Qi
Zhiwei Zhao
Yanju Qian
Shijie Zhang
Hongjuan Zheng
Xiaomiao Zhao
Xinpo Lu
Shun Wang
author_sort Wanzhen Qi
collection DOAJ
description WC-based cemented carbides were prepared by spark plasma sintering (SPS) of WC-Co-Cr<sub>3</sub>C<sub>2</sub>-VC alloy powder by adding different contents of graphene. The phase composition, microstructure, mechanical properties, and magnetic properties of cemented carbide were investigated by means of XRD, SEM, Vickers hardness and fracture toughness tests, and magnetic properties tests. The results showed that the mechanical properties of the specimens show a trend of first increasing and then decreasing with the increase in graphene content. After adding 0.6 wt.% graphene, graphene is uniformly distributed on the substrate in the form of flakes, WC grain size decreases, the hardness of the specimen increases to 2009 HV, the relative density increases to 94.3%, the fracture toughness is 11.72 MPa·m<sup>1/2</sup>, and the coercivity of the sample is 437.55 Oe. Therefore, cemented carbide with a graphene content of 0.6 wt.% has excellent comprehensive performance (Vickers hardness and fracture toughness).
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spelling doaj.art-cc3d886236664fe9b03efe785c97ea0b2023-11-19T16:08:53ZengMDPI AGCrystals2073-43522023-09-011310141410.3390/cryst13101414Effect of Graphene on the Microstructure and Mechanical Properties of WC-Based Cemented CarbideWanzhen Qi0Zhiwei Zhao1Yanju Qian2Shijie Zhang3Hongjuan Zheng4Xiaomiao Zhao5Xinpo Lu6Shun Wang7College of Materials Science and Engineering, Henan University of Technology, Zhengzhou 450001, ChinaCollege of Materials Science and Engineering, Henan University of Technology, Zhengzhou 450001, ChinaCollege of Materials Science and Engineering, Henan University of Technology, Zhengzhou 450001, ChinaCollege of Materials Science and Engineering, Henan University of Technology, Zhengzhou 450001, ChinaCollege of Materials Science and Engineering, Henan University of Technology, Zhengzhou 450001, ChinaCollege of Materials Science and Engineering, Henan University of Technology, Zhengzhou 450001, ChinaCollege of Materials Science and Engineering, Henan University of Technology, Zhengzhou 450001, ChinaCollege of Materials Science and Engineering, Henan University of Technology, Zhengzhou 450001, ChinaWC-based cemented carbides were prepared by spark plasma sintering (SPS) of WC-Co-Cr<sub>3</sub>C<sub>2</sub>-VC alloy powder by adding different contents of graphene. The phase composition, microstructure, mechanical properties, and magnetic properties of cemented carbide were investigated by means of XRD, SEM, Vickers hardness and fracture toughness tests, and magnetic properties tests. The results showed that the mechanical properties of the specimens show a trend of first increasing and then decreasing with the increase in graphene content. After adding 0.6 wt.% graphene, graphene is uniformly distributed on the substrate in the form of flakes, WC grain size decreases, the hardness of the specimen increases to 2009 HV, the relative density increases to 94.3%, the fracture toughness is 11.72 MPa·m<sup>1/2</sup>, and the coercivity of the sample is 437.55 Oe. Therefore, cemented carbide with a graphene content of 0.6 wt.% has excellent comprehensive performance (Vickers hardness and fracture toughness).https://www.mdpi.com/2073-4352/13/10/1414cemented carbidesspark plasma sinteringgraphenemechanical properties
spellingShingle Wanzhen Qi
Zhiwei Zhao
Yanju Qian
Shijie Zhang
Hongjuan Zheng
Xiaomiao Zhao
Xinpo Lu
Shun Wang
Effect of Graphene on the Microstructure and Mechanical Properties of WC-Based Cemented Carbide
Crystals
cemented carbides
spark plasma sintering
graphene
mechanical properties
title Effect of Graphene on the Microstructure and Mechanical Properties of WC-Based Cemented Carbide
title_full Effect of Graphene on the Microstructure and Mechanical Properties of WC-Based Cemented Carbide
title_fullStr Effect of Graphene on the Microstructure and Mechanical Properties of WC-Based Cemented Carbide
title_full_unstemmed Effect of Graphene on the Microstructure and Mechanical Properties of WC-Based Cemented Carbide
title_short Effect of Graphene on the Microstructure and Mechanical Properties of WC-Based Cemented Carbide
title_sort effect of graphene on the microstructure and mechanical properties of wc based cemented carbide
topic cemented carbides
spark plasma sintering
graphene
mechanical properties
url https://www.mdpi.com/2073-4352/13/10/1414
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AT shijiezhang effectofgrapheneonthemicrostructureandmechanicalpropertiesofwcbasedcementedcarbide
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