Electrooxidation Is a Promising Approach to Functionalization of Pyrazole-Type Compounds
The review summarizes for the first time the poorly studied electrooxidative functionalization of pyrazole derivatives leading to the C–Cl, C–Br, C–I, C–S and N–N coupling products with applied properties. The introduction discusses some aspects of aromatic hydrogen substitution. Further, we mainly...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
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MDPI AG
2021-08-01
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| Series: | Molecules |
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| Online Access: | https://www.mdpi.com/1420-3049/26/16/4749 |
| _version_ | 1797522805207597056 |
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| author | Boris V. Lyalin Vera L. Sigacheva Anastasia S. Kudinova Sergey V. Neverov Vladimir A. Kokorekin Vladimir A. Petrosyan |
| author_facet | Boris V. Lyalin Vera L. Sigacheva Anastasia S. Kudinova Sergey V. Neverov Vladimir A. Kokorekin Vladimir A. Petrosyan |
| author_sort | Boris V. Lyalin |
| collection | DOAJ |
| description | The review summarizes for the first time the poorly studied electrooxidative functionalization of pyrazole derivatives leading to the C–Cl, C–Br, C–I, C–S and N–N coupling products with applied properties. The introduction discusses some aspects of aromatic hydrogen substitution. Further, we mainly consider our works on effective synthesis of the corresponding halogeno, thiocyanato and azo compounds using cheap, affordable and environmentally promising electric currents. |
| first_indexed | 2024-03-10T08:33:36Z |
| format | Article |
| id | doaj.art-cc3f9868f3b24e3b8cbf5b1e0827d8ff |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-03-10T08:33:36Z |
| publishDate | 2021-08-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-cc3f9868f3b24e3b8cbf5b1e0827d8ff2023-11-22T08:51:25ZengMDPI AGMolecules1420-30492021-08-012616474910.3390/molecules26164749Electrooxidation Is a Promising Approach to Functionalization of Pyrazole-Type CompoundsBoris V. Lyalin0Vera L. Sigacheva1Anastasia S. Kudinova2Sergey V. Neverov3Vladimir A. Kokorekin4Vladimir A. Petrosyan5N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky Prosp. 47, 119991 Moscow, RussiaN.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky Prosp. 47, 119991 Moscow, RussiaN.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky Prosp. 47, 119991 Moscow, RussiaN.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky Prosp. 47, 119991 Moscow, RussiaN.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky Prosp. 47, 119991 Moscow, RussiaN.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky Prosp. 47, 119991 Moscow, RussiaThe review summarizes for the first time the poorly studied electrooxidative functionalization of pyrazole derivatives leading to the C–Cl, C–Br, C–I, C–S and N–N coupling products with applied properties. The introduction discusses some aspects of aromatic hydrogen substitution. Further, we mainly consider our works on effective synthesis of the corresponding halogeno, thiocyanato and azo compounds using cheap, affordable and environmentally promising electric currents.https://www.mdpi.com/1420-3049/26/16/4749pyrazolespyrazolo[1,5-a]pyrimidinesaromatic substitutionelectrooxidationC–H halogenationC–H thiocyanation |
| spellingShingle | Boris V. Lyalin Vera L. Sigacheva Anastasia S. Kudinova Sergey V. Neverov Vladimir A. Kokorekin Vladimir A. Petrosyan Electrooxidation Is a Promising Approach to Functionalization of Pyrazole-Type Compounds Molecules pyrazoles pyrazolo[1,5-a]pyrimidines aromatic substitution electrooxidation C–H halogenation C–H thiocyanation |
| title | Electrooxidation Is a Promising Approach to Functionalization of Pyrazole-Type Compounds |
| title_full | Electrooxidation Is a Promising Approach to Functionalization of Pyrazole-Type Compounds |
| title_fullStr | Electrooxidation Is a Promising Approach to Functionalization of Pyrazole-Type Compounds |
| title_full_unstemmed | Electrooxidation Is a Promising Approach to Functionalization of Pyrazole-Type Compounds |
| title_short | Electrooxidation Is a Promising Approach to Functionalization of Pyrazole-Type Compounds |
| title_sort | electrooxidation is a promising approach to functionalization of pyrazole type compounds |
| topic | pyrazoles pyrazolo[1,5-a]pyrimidines aromatic substitution electrooxidation C–H halogenation C–H thiocyanation |
| url | https://www.mdpi.com/1420-3049/26/16/4749 |
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