A chemoselective and green reduction of nitro arenes to aromatic amines with FeSO4, NaBH4, H3PW12O40 in water at room temperature
A new efficient and practical method for the room-temperature reduction of aromatic nitro compounds employing FeSO4. 7H2O, NaBH4, H3PW12O40 system in H2O under mild conditions is reported. The method is simple, inexpensive, easily scaled-up and applicable for the large scale preparation of different...
Main Authors: | , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
Nanoscience and Nanotechnology Research Center, University of Kashan
2011-01-01
|
Series: | Journal of Nanostructures |
Subjects: | |
Online Access: | http://jns.kashanu.ac.ir/article_5241_6bc2c1253c296a6392dbc6350ea6204b.pdf |
_version_ | 1818293602496806912 |
---|---|
author | R. Fazaeli H. Aliyan H. Javaherian Naghash A. R. Massah F. Saliminejad |
author_facet | R. Fazaeli H. Aliyan H. Javaherian Naghash A. R. Massah F. Saliminejad |
author_sort | R. Fazaeli |
collection | DOAJ |
description | A new efficient and practical method for the room-temperature reduction of aromatic nitro compounds employing FeSO4. 7H2O, NaBH4, H3PW12O40 system in H2O under mild conditions is reported. The method is simple, inexpensive, easily scaled-up and applicable for the large scale preparation of different substituted anilines. |
first_indexed | 2024-12-13T03:18:28Z |
format | Article |
id | doaj.art-cc4fd66646424d37842da96688c96ef6 |
institution | Directory Open Access Journal |
issn | 2251-7871 2251-788X |
language | English |
last_indexed | 2024-12-13T03:18:28Z |
publishDate | 2011-01-01 |
publisher | Nanoscience and Nanotechnology Research Center, University of Kashan |
record_format | Article |
series | Journal of Nanostructures |
spelling | doaj.art-cc4fd66646424d37842da96688c96ef62022-12-22T00:01:25ZengNanoscience and Nanotechnology Research Center, University of KashanJournal of Nanostructures2251-78712251-788X2011-01-0111212610.7508/jns.2011.01.0045241A chemoselective and green reduction of nitro arenes to aromatic amines with FeSO4, NaBH4, H3PW12O40 in water at room temperatureR. Fazaeli0H. Aliyan1H. Javaherian Naghash2A. R. Massah3F. Saliminejad4Department of Chemistry, Islamic Azad University, Shahreza Branch,86145-311, Shahreza ,Isfahan , Iran.Department of Chemistry, Islamic Azad University, Shahreza Branch,86145-311, Shahreza ,Isfahan , Iran.Department of Chemistry, Islamic Azad University, Shahreza Branch,86145-311, Shahreza ,Isfahan , Iran.Department of Chemistry, Islamic Azad University, Shahreza Branch,86145-311, Shahreza ,Isfahan , Iran.Department of Chemistry, Islamic Azad University, Shahreza Branch,86145-311, Shahreza ,Isfahan , Iran.A new efficient and practical method for the room-temperature reduction of aromatic nitro compounds employing FeSO4. 7H2O, NaBH4, H3PW12O40 system in H2O under mild conditions is reported. The method is simple, inexpensive, easily scaled-up and applicable for the large scale preparation of different substituted anilines.http://jns.kashanu.ac.ir/article_5241_6bc2c1253c296a6392dbc6350ea6204b.pdfHeteropoly acids (HPAs)Polyoxometalates (POMs)HeterogeneousNanoscale Fe particles |
spellingShingle | R. Fazaeli H. Aliyan H. Javaherian Naghash A. R. Massah F. Saliminejad A chemoselective and green reduction of nitro arenes to aromatic amines with FeSO4, NaBH4, H3PW12O40 in water at room temperature Journal of Nanostructures Heteropoly acids (HPAs) Polyoxometalates (POMs) Heterogeneous Nanoscale Fe particles |
title | A chemoselective and green reduction of nitro arenes to aromatic amines with FeSO4, NaBH4, H3PW12O40 in water at room temperature |
title_full | A chemoselective and green reduction of nitro arenes to aromatic amines with FeSO4, NaBH4, H3PW12O40 in water at room temperature |
title_fullStr | A chemoselective and green reduction of nitro arenes to aromatic amines with FeSO4, NaBH4, H3PW12O40 in water at room temperature |
title_full_unstemmed | A chemoselective and green reduction of nitro arenes to aromatic amines with FeSO4, NaBH4, H3PW12O40 in water at room temperature |
title_short | A chemoselective and green reduction of nitro arenes to aromatic amines with FeSO4, NaBH4, H3PW12O40 in water at room temperature |
title_sort | chemoselective and green reduction of nitro arenes to aromatic amines with feso4 nabh4 h3pw12o40 in water at room temperature |
topic | Heteropoly acids (HPAs) Polyoxometalates (POMs) Heterogeneous Nanoscale Fe particles |
url | http://jns.kashanu.ac.ir/article_5241_6bc2c1253c296a6392dbc6350ea6204b.pdf |
work_keys_str_mv | AT rfazaeli achemoselectiveandgreenreductionofnitroarenestoaromaticamineswithfeso4nabh4h3pw12o40inwateratroomtemperature AT haliyan achemoselectiveandgreenreductionofnitroarenestoaromaticamineswithfeso4nabh4h3pw12o40inwateratroomtemperature AT hjavaheriannaghash achemoselectiveandgreenreductionofnitroarenestoaromaticamineswithfeso4nabh4h3pw12o40inwateratroomtemperature AT armassah achemoselectiveandgreenreductionofnitroarenestoaromaticamineswithfeso4nabh4h3pw12o40inwateratroomtemperature AT fsaliminejad achemoselectiveandgreenreductionofnitroarenestoaromaticamineswithfeso4nabh4h3pw12o40inwateratroomtemperature AT rfazaeli chemoselectiveandgreenreductionofnitroarenestoaromaticamineswithfeso4nabh4h3pw12o40inwateratroomtemperature AT haliyan chemoselectiveandgreenreductionofnitroarenestoaromaticamineswithfeso4nabh4h3pw12o40inwateratroomtemperature AT hjavaheriannaghash chemoselectiveandgreenreductionofnitroarenestoaromaticamineswithfeso4nabh4h3pw12o40inwateratroomtemperature AT armassah chemoselectiveandgreenreductionofnitroarenestoaromaticamineswithfeso4nabh4h3pw12o40inwateratroomtemperature AT fsaliminejad chemoselectiveandgreenreductionofnitroarenestoaromaticamineswithfeso4nabh4h3pw12o40inwateratroomtemperature |