The improved diesel-like fuel from upgraded tire pyrolytic oil
Tire pyrolytic oil (TPO) obtained from thermal pyrolysis of scrap tires is not a diesel equivalent fuel which can be used directly in vehicles due to its high density, viscosity, sulfur content, low flash point and low cetane index. It can only be used in a limited way by mixing with diesel fuel (DF...
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Serbian Chemical Society
2022-01-01
|
| Series: | Journal of the Serbian Chemical Society |
| Subjects: | |
| Online Access: | http://www.doiserbia.nb.rs/img/doi/0352-5139/2022/0352-51392200048V.pdf |
| _version_ | 1811178345845489664 |
|---|---|
| author | Vural Ufuk Sancar Uysal Saban Yinanc Abdullah |
| author_facet | Vural Ufuk Sancar Uysal Saban Yinanc Abdullah |
| author_sort | Vural Ufuk Sancar |
| collection | DOAJ |
| description | Tire pyrolytic oil (TPO) obtained from thermal pyrolysis of scrap tires is not a diesel equivalent fuel which can be used directly in vehicles due to its high density, viscosity, sulfur content, low flash point and low cetane index. It can only be used in a limited way by mixing with diesel fuel (DF) in amounts less than 30 %. In this study, the pyrolysis of scrap tires was carried out at a heating rates of 5 and 10ºC min-1 in the range of 450–600ºC, using a mixture of hierarchical zeolite (HZSM-5), mesoporous silica (MCM-41) and quicklime (CaO) as the catalyst. The obtained TPO and catalytic pyrolytic oil (CPO) were upgraded by pre-treatment, and distillation consisting of a mixture of Cu(I)-loaded mesoporous aluminosilicate (Cu(I)–MAS) and MCM-41, desulfurization and decolourization steps, respectively. To obtain diesel-like fuel, the upgraded catalytic pyrolytic oil (UCPO) and biodiesel (PBD) obtained from palm oil were blended in certain proportions. Density, viscosity, flash point and cetane index of the obtained diesel-like fuels were found within the limit values of diesel fuel. |
| first_indexed | 2024-04-11T06:17:50Z |
| format | Article |
| id | doaj.art-cc5b0fb9c2d645dfa4de55eb9837df4f |
| institution | Directory Open Access Journal |
| issn | 0352-5139 1820-7421 |
| language | English |
| last_indexed | 2024-04-11T06:17:50Z |
| publishDate | 2022-01-01 |
| publisher | Serbian Chemical Society |
| record_format | Article |
| series | Journal of the Serbian Chemical Society |
| spelling | doaj.art-cc5b0fb9c2d645dfa4de55eb9837df4f2022-12-22T04:41:01ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51391820-74212022-01-0187101219123510.2298/JSC211108048V0352-51392200048VThe improved diesel-like fuel from upgraded tire pyrolytic oilVural Ufuk Sancar0https://orcid.org/0000-0002-8510-9616Uysal Saban1https://orcid.org/0000-0003-1061-6143Yinanc Abdullah2https://orcid.org/0000-0002-8144-8266Pasabayır Mh. Mehmetcik, Bandirma, Balikesir, TurkeyKarabuk University, Faculty of Science, Department of Chemistry, Karabuk, TurkeyTekirdag Namık Kemal University, Corlu Vocational School of Technical Sciences, Corlu, Tekirdag, TurkeyTire pyrolytic oil (TPO) obtained from thermal pyrolysis of scrap tires is not a diesel equivalent fuel which can be used directly in vehicles due to its high density, viscosity, sulfur content, low flash point and low cetane index. It can only be used in a limited way by mixing with diesel fuel (DF) in amounts less than 30 %. In this study, the pyrolysis of scrap tires was carried out at a heating rates of 5 and 10ºC min-1 in the range of 450–600ºC, using a mixture of hierarchical zeolite (HZSM-5), mesoporous silica (MCM-41) and quicklime (CaO) as the catalyst. The obtained TPO and catalytic pyrolytic oil (CPO) were upgraded by pre-treatment, and distillation consisting of a mixture of Cu(I)-loaded mesoporous aluminosilicate (Cu(I)–MAS) and MCM-41, desulfurization and decolourization steps, respectively. To obtain diesel-like fuel, the upgraded catalytic pyrolytic oil (UCPO) and biodiesel (PBD) obtained from palm oil were blended in certain proportions. Density, viscosity, flash point and cetane index of the obtained diesel-like fuels were found within the limit values of diesel fuel.http://www.doiserbia.nb.rs/img/doi/0352-5139/2022/0352-51392200048V.pdfdesulfurizationmesoporous zeolitemicroporous zeolitecatalytic pyrolysisthermal pyrolysis |
| spellingShingle | Vural Ufuk Sancar Uysal Saban Yinanc Abdullah The improved diesel-like fuel from upgraded tire pyrolytic oil Journal of the Serbian Chemical Society desulfurization mesoporous zeolite microporous zeolite catalytic pyrolysis thermal pyrolysis |
| title | The improved diesel-like fuel from upgraded tire pyrolytic oil |
| title_full | The improved diesel-like fuel from upgraded tire pyrolytic oil |
| title_fullStr | The improved diesel-like fuel from upgraded tire pyrolytic oil |
| title_full_unstemmed | The improved diesel-like fuel from upgraded tire pyrolytic oil |
| title_short | The improved diesel-like fuel from upgraded tire pyrolytic oil |
| title_sort | improved diesel like fuel from upgraded tire pyrolytic oil |
| topic | desulfurization mesoporous zeolite microporous zeolite catalytic pyrolysis thermal pyrolysis |
| url | http://www.doiserbia.nb.rs/img/doi/0352-5139/2022/0352-51392200048V.pdf |
| work_keys_str_mv | AT vuralufuksancar theimproveddiesellikefuelfromupgradedtirepyrolyticoil AT uysalsaban theimproveddiesellikefuelfromupgradedtirepyrolyticoil AT yinancabdullah theimproveddiesellikefuelfromupgradedtirepyrolyticoil AT vuralufuksancar improveddiesellikefuelfromupgradedtirepyrolyticoil AT uysalsaban improveddiesellikefuelfromupgradedtirepyrolyticoil AT yinancabdullah improveddiesellikefuelfromupgradedtirepyrolyticoil |