Bis(2,2′-bipyridyl-κ2N,N′)(nitrato-κ2O,O′)(trifluoroacetato-κO)cadmium(II)
In the title complex, [Cd(C2F3O2)(NO3)(C10H8N2)2], the Cd(II) ion is heptacoordinated by two chelating 2,2′-bipyridyl ligands [Cd...N 2.370 (6)–2.416 (6) Å], one carboxylate O atom [Cd...O 2.290 (6)&...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-06-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809016717 |
| _version_ | 1831654599309656064 |
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| author | Wenzeng Duan Junshan Sun Yudao Ma Rentao Wu |
| author_facet | Wenzeng Duan Junshan Sun Yudao Ma Rentao Wu |
| author_sort | Wenzeng Duan |
| collection | DOAJ |
| description | In the title complex, [Cd(C2F3O2)(NO3)(C10H8N2)2], the Cd(II) ion is heptacoordinated by two chelating 2,2′-bipyridyl ligands [Cd...N 2.370 (6)–2.416 (6) Å], one carboxylate O atom [Cd...O 2.290 (6) Å] from the trifluoroacetate ligand and two O atoms [Cd...O 2.386 (6), 2.633 (6) Å] from a chelating nitrate anion. The trifluoromethyl fragment is rotationally disordered between two orientations in a 0.640 (7):0.360 (7) ratio. In the crystal, weak intermolecular C—H...O hydrogen bonds contribute to the crystal packing stability. |
| first_indexed | 2024-12-19T16:31:08Z |
| format | Article |
| id | doaj.art-cc5e0c346146465ba4d90414014a1fca |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-19T16:31:08Z |
| publishDate | 2009-06-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-cc5e0c346146465ba4d90414014a1fca2022-12-21T20:14:11ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-06-01656m635m63510.1107/S1600536809016717Bis(2,2′-bipyridyl-κ2N,N′)(nitrato-κ2O,O′)(trifluoroacetato-κO)cadmium(II)Wenzeng DuanJunshan SunYudao MaRentao WuIn the title complex, [Cd(C2F3O2)(NO3)(C10H8N2)2], the Cd(II) ion is heptacoordinated by two chelating 2,2′-bipyridyl ligands [Cd...N 2.370 (6)–2.416 (6) Å], one carboxylate O atom [Cd...O 2.290 (6) Å] from the trifluoroacetate ligand and two O atoms [Cd...O 2.386 (6), 2.633 (6) Å] from a chelating nitrate anion. The trifluoromethyl fragment is rotationally disordered between two orientations in a 0.640 (7):0.360 (7) ratio. In the crystal, weak intermolecular C—H...O hydrogen bonds contribute to the crystal packing stability.http://scripts.iucr.org/cgi-bin/paper?S1600536809016717 |
| spellingShingle | Wenzeng Duan Junshan Sun Yudao Ma Rentao Wu Bis(2,2′-bipyridyl-κ2N,N′)(nitrato-κ2O,O′)(trifluoroacetato-κO)cadmium(II) Acta Crystallographica Section E |
| title | Bis(2,2′-bipyridyl-κ2N,N′)(nitrato-κ2O,O′)(trifluoroacetato-κO)cadmium(II) |
| title_full | Bis(2,2′-bipyridyl-κ2N,N′)(nitrato-κ2O,O′)(trifluoroacetato-κO)cadmium(II) |
| title_fullStr | Bis(2,2′-bipyridyl-κ2N,N′)(nitrato-κ2O,O′)(trifluoroacetato-κO)cadmium(II) |
| title_full_unstemmed | Bis(2,2′-bipyridyl-κ2N,N′)(nitrato-κ2O,O′)(trifluoroacetato-κO)cadmium(II) |
| title_short | Bis(2,2′-bipyridyl-κ2N,N′)(nitrato-κ2O,O′)(trifluoroacetato-κO)cadmium(II) |
| title_sort | bis 2 2 amp 8242 bipyridyl amp 954 2n n amp 8242 nitrato amp 954 2o o amp 8242 trifluoroacetato amp 954 o cadmium ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809016717 |
| work_keys_str_mv | AT wenzengduan bis22amp8242bipyridylamp9542nnamp8242nitratoamp9542ooamp8242trifluoroacetatoamp954ocadmiumii AT junshansun bis22amp8242bipyridylamp9542nnamp8242nitratoamp9542ooamp8242trifluoroacetatoamp954ocadmiumii AT yudaoma bis22amp8242bipyridylamp9542nnamp8242nitratoamp9542ooamp8242trifluoroacetatoamp954ocadmiumii AT rentaowu bis22amp8242bipyridylamp9542nnamp8242nitratoamp9542ooamp8242trifluoroacetatoamp954ocadmiumii |