Thermal Contact

The concepts of temperature and entropy as applied in equilibrium thermodynamics do not easily generalize to nonequilibrium systems and there are transient systems where thermodynamics cannot apply. However, it is possible that nonequilibrium steady states may have a thermodynamics description. We e...

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Bibliographic Details
Main Authors: Tony Chung, Christopher Angstmann, Gary P. Morriss
Format: Article
Language:English
Published: MDPI AG 2008-12-01
Series:Entropy
Subjects:
Online Access:http://www.mdpi.com/1099-4300/10/4/786/
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author Tony Chung
Christopher Angstmann
Gary P. Morriss
author_facet Tony Chung
Christopher Angstmann
Gary P. Morriss
author_sort Tony Chung
collection DOAJ
description The concepts of temperature and entropy as applied in equilibrium thermodynamics do not easily generalize to nonequilibrium systems and there are transient systems where thermodynamics cannot apply. However, it is possible that nonequilibrium steady states may have a thermodynamics description. We explore the consequences of a particular microscopic thermostat-reservoir contact needed to both stabilize and measure the temperature of a system. One particular mechanical connection mechanism is considered in detail and a contact resistance is observed in the numerical simulations. We propose a microscopic mechanism to explain this effect for both equilibrium and nonequilibrium systems. These results emphasize the difficulty in identifying a microscopic expression for the thermodynamic temperature. It is evident that the kinetic temperature is not necessarily equal to the thermodynamic temperature, especially when used to define the local temperature.
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spelling doaj.art-cc7c7d03be084e0f8c7e0ce7596c04e42022-12-22T04:23:35ZengMDPI AGEntropy1099-43002008-12-0110478679810.3390/e10040786Thermal ContactTony ChungChristopher AngstmannGary P. MorrissThe concepts of temperature and entropy as applied in equilibrium thermodynamics do not easily generalize to nonequilibrium systems and there are transient systems where thermodynamics cannot apply. However, it is possible that nonequilibrium steady states may have a thermodynamics description. We explore the consequences of a particular microscopic thermostat-reservoir contact needed to both stabilize and measure the temperature of a system. One particular mechanical connection mechanism is considered in detail and a contact resistance is observed in the numerical simulations. We propose a microscopic mechanism to explain this effect for both equilibrium and nonequilibrium systems. These results emphasize the difficulty in identifying a microscopic expression for the thermodynamic temperature. It is evident that the kinetic temperature is not necessarily equal to the thermodynamic temperature, especially when used to define the local temperature.http://www.mdpi.com/1099-4300/10/4/786/Heat transportTemperature
spellingShingle Tony Chung
Christopher Angstmann
Gary P. Morriss
Thermal Contact
Entropy
Heat transport
Temperature
title Thermal Contact
title_full Thermal Contact
title_fullStr Thermal Contact
title_full_unstemmed Thermal Contact
title_short Thermal Contact
title_sort thermal contact
topic Heat transport
Temperature
url http://www.mdpi.com/1099-4300/10/4/786/
work_keys_str_mv AT tonychung thermalcontact
AT christopherangstmann thermalcontact
AT garypmorriss thermalcontact