Modification of Polycaprolactone with Plant Extracts to Improve the Aging Resistance
Natural extracts of plant origin are used as anti-aging compounds of biodegradable polymers. Coffee, cocoa, or cinnamon extracts in amounts from 0.5 to 10 wt.% were added to the polycaprolactone matrix. The manufactured materials were aged at elevated temperatures with increased relative humidity an...
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MDPI AG
2023-07-01
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Online Access: | https://www.mdpi.com/1996-1944/16/14/5154 |
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author | Krzysztof Moraczewski Magdalena Stepczyńska Rafał Malinowski Tomasz Karasiewicz Bartłomiej Jagodziński Piotr Rytlewski |
author_facet | Krzysztof Moraczewski Magdalena Stepczyńska Rafał Malinowski Tomasz Karasiewicz Bartłomiej Jagodziński Piotr Rytlewski |
author_sort | Krzysztof Moraczewski |
collection | DOAJ |
description | Natural extracts of plant origin are used as anti-aging compounds of biodegradable polymers. Coffee, cocoa, or cinnamon extracts in amounts from 0.5 to 10 wt.% were added to the polycaprolactone matrix. The manufactured materials were aged at elevated temperatures with increased relative humidity and continuous exposure to UV radiation for 720, 1440, or 2160 h. The performance of the proposed extracts was compared with the retail anti-aging compound, butylated hydroxytoluene. Visual assessment, FTIR analysis, melt flow rate, tensile strength, impact tensile strength, thermogravimetry, and differential scanning calorimetry tests were conducted. Results showed that the use of lower contents of the tested extracts is particularly advantageous. When the content of the extract did not exceed 1 wt.%, no unfavorable influence on the properties of the materials was observed. The stabilizing performance during accelerated aging was mostly similar to or greater than that of the reference compound used. |
first_indexed | 2024-03-11T00:53:13Z |
format | Article |
id | doaj.art-ccaf7c75b54b43798d74d1bdca023350 |
institution | Directory Open Access Journal |
issn | 1996-1944 |
language | English |
last_indexed | 2024-03-11T00:53:13Z |
publishDate | 2023-07-01 |
publisher | MDPI AG |
record_format | Article |
series | Materials |
spelling | doaj.art-ccaf7c75b54b43798d74d1bdca0233502023-11-18T20:18:47ZengMDPI AGMaterials1996-19442023-07-011614515410.3390/ma16145154Modification of Polycaprolactone with Plant Extracts to Improve the Aging ResistanceKrzysztof Moraczewski0Magdalena Stepczyńska1Rafał Malinowski2Tomasz Karasiewicz3Bartłomiej Jagodziński4Piotr Rytlewski5Faculty of Materials Engineering, Kazimierz Wielki University, Chodkiewicza 30, 85-064 Bydgoszcz, PolandFaculty of Materials Engineering, Kazimierz Wielki University, Chodkiewicza 30, 85-064 Bydgoszcz, PolandŁukasiewicz Research Network—Institute for Engineering of Polymer Materials and Dyes, Marii Skłodowskiej-Curie 55, 87-100 Toruń, PolandFaculty of Materials Engineering, Kazimierz Wielki University, Chodkiewicza 30, 85-064 Bydgoszcz, PolandFaculty of Materials Engineering, Kazimierz Wielki University, Chodkiewicza 30, 85-064 Bydgoszcz, PolandFaculty of Materials Engineering, Kazimierz Wielki University, Chodkiewicza 30, 85-064 Bydgoszcz, PolandNatural extracts of plant origin are used as anti-aging compounds of biodegradable polymers. Coffee, cocoa, or cinnamon extracts in amounts from 0.5 to 10 wt.% were added to the polycaprolactone matrix. The manufactured materials were aged at elevated temperatures with increased relative humidity and continuous exposure to UV radiation for 720, 1440, or 2160 h. The performance of the proposed extracts was compared with the retail anti-aging compound, butylated hydroxytoluene. Visual assessment, FTIR analysis, melt flow rate, tensile strength, impact tensile strength, thermogravimetry, and differential scanning calorimetry tests were conducted. Results showed that the use of lower contents of the tested extracts is particularly advantageous. When the content of the extract did not exceed 1 wt.%, no unfavorable influence on the properties of the materials was observed. The stabilizing performance during accelerated aging was mostly similar to or greater than that of the reference compound used.https://www.mdpi.com/1996-1944/16/14/5154polycaprolactonepolyphenolsplant extractsaccelerated aging |
spellingShingle | Krzysztof Moraczewski Magdalena Stepczyńska Rafał Malinowski Tomasz Karasiewicz Bartłomiej Jagodziński Piotr Rytlewski Modification of Polycaprolactone with Plant Extracts to Improve the Aging Resistance Materials polycaprolactone polyphenols plant extracts accelerated aging |
title | Modification of Polycaprolactone with Plant Extracts to Improve the Aging Resistance |
title_full | Modification of Polycaprolactone with Plant Extracts to Improve the Aging Resistance |
title_fullStr | Modification of Polycaprolactone with Plant Extracts to Improve the Aging Resistance |
title_full_unstemmed | Modification of Polycaprolactone with Plant Extracts to Improve the Aging Resistance |
title_short | Modification of Polycaprolactone with Plant Extracts to Improve the Aging Resistance |
title_sort | modification of polycaprolactone with plant extracts to improve the aging resistance |
topic | polycaprolactone polyphenols plant extracts accelerated aging |
url | https://www.mdpi.com/1996-1944/16/14/5154 |
work_keys_str_mv | AT krzysztofmoraczewski modificationofpolycaprolactonewithplantextractstoimprovetheagingresistance AT magdalenastepczynska modificationofpolycaprolactonewithplantextractstoimprovetheagingresistance AT rafałmalinowski modificationofpolycaprolactonewithplantextractstoimprovetheagingresistance AT tomaszkarasiewicz modificationofpolycaprolactonewithplantextractstoimprovetheagingresistance AT bartłomiejjagodzinski modificationofpolycaprolactonewithplantextractstoimprovetheagingresistance AT piotrrytlewski modificationofpolycaprolactonewithplantextractstoimprovetheagingresistance |