Modification of Polycaprolactone with Plant Extracts to Improve the Aging Resistance

Natural extracts of plant origin are used as anti-aging compounds of biodegradable polymers. Coffee, cocoa, or cinnamon extracts in amounts from 0.5 to 10 wt.% were added to the polycaprolactone matrix. The manufactured materials were aged at elevated temperatures with increased relative humidity an...

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Main Authors: Krzysztof Moraczewski, Magdalena Stepczyńska, Rafał Malinowski, Tomasz Karasiewicz, Bartłomiej Jagodziński, Piotr Rytlewski
Format: Article
Language:English
Published: MDPI AG 2023-07-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/16/14/5154
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author Krzysztof Moraczewski
Magdalena Stepczyńska
Rafał Malinowski
Tomasz Karasiewicz
Bartłomiej Jagodziński
Piotr Rytlewski
author_facet Krzysztof Moraczewski
Magdalena Stepczyńska
Rafał Malinowski
Tomasz Karasiewicz
Bartłomiej Jagodziński
Piotr Rytlewski
author_sort Krzysztof Moraczewski
collection DOAJ
description Natural extracts of plant origin are used as anti-aging compounds of biodegradable polymers. Coffee, cocoa, or cinnamon extracts in amounts from 0.5 to 10 wt.% were added to the polycaprolactone matrix. The manufactured materials were aged at elevated temperatures with increased relative humidity and continuous exposure to UV radiation for 720, 1440, or 2160 h. The performance of the proposed extracts was compared with the retail anti-aging compound, butylated hydroxytoluene. Visual assessment, FTIR analysis, melt flow rate, tensile strength, impact tensile strength, thermogravimetry, and differential scanning calorimetry tests were conducted. Results showed that the use of lower contents of the tested extracts is particularly advantageous. When the content of the extract did not exceed 1 wt.%, no unfavorable influence on the properties of the materials was observed. The stabilizing performance during accelerated aging was mostly similar to or greater than that of the reference compound used.
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spelling doaj.art-ccaf7c75b54b43798d74d1bdca0233502023-11-18T20:18:47ZengMDPI AGMaterials1996-19442023-07-011614515410.3390/ma16145154Modification of Polycaprolactone with Plant Extracts to Improve the Aging ResistanceKrzysztof Moraczewski0Magdalena Stepczyńska1Rafał Malinowski2Tomasz Karasiewicz3Bartłomiej Jagodziński4Piotr Rytlewski5Faculty of Materials Engineering, Kazimierz Wielki University, Chodkiewicza 30, 85-064 Bydgoszcz, PolandFaculty of Materials Engineering, Kazimierz Wielki University, Chodkiewicza 30, 85-064 Bydgoszcz, PolandŁukasiewicz Research Network—Institute for Engineering of Polymer Materials and Dyes, Marii Skłodowskiej-Curie 55, 87-100 Toruń, PolandFaculty of Materials Engineering, Kazimierz Wielki University, Chodkiewicza 30, 85-064 Bydgoszcz, PolandFaculty of Materials Engineering, Kazimierz Wielki University, Chodkiewicza 30, 85-064 Bydgoszcz, PolandFaculty of Materials Engineering, Kazimierz Wielki University, Chodkiewicza 30, 85-064 Bydgoszcz, PolandNatural extracts of plant origin are used as anti-aging compounds of biodegradable polymers. Coffee, cocoa, or cinnamon extracts in amounts from 0.5 to 10 wt.% were added to the polycaprolactone matrix. The manufactured materials were aged at elevated temperatures with increased relative humidity and continuous exposure to UV radiation for 720, 1440, or 2160 h. The performance of the proposed extracts was compared with the retail anti-aging compound, butylated hydroxytoluene. Visual assessment, FTIR analysis, melt flow rate, tensile strength, impact tensile strength, thermogravimetry, and differential scanning calorimetry tests were conducted. Results showed that the use of lower contents of the tested extracts is particularly advantageous. When the content of the extract did not exceed 1 wt.%, no unfavorable influence on the properties of the materials was observed. The stabilizing performance during accelerated aging was mostly similar to or greater than that of the reference compound used.https://www.mdpi.com/1996-1944/16/14/5154polycaprolactonepolyphenolsplant extractsaccelerated aging
spellingShingle Krzysztof Moraczewski
Magdalena Stepczyńska
Rafał Malinowski
Tomasz Karasiewicz
Bartłomiej Jagodziński
Piotr Rytlewski
Modification of Polycaprolactone with Plant Extracts to Improve the Aging Resistance
Materials
polycaprolactone
polyphenols
plant extracts
accelerated aging
title Modification of Polycaprolactone with Plant Extracts to Improve the Aging Resistance
title_full Modification of Polycaprolactone with Plant Extracts to Improve the Aging Resistance
title_fullStr Modification of Polycaprolactone with Plant Extracts to Improve the Aging Resistance
title_full_unstemmed Modification of Polycaprolactone with Plant Extracts to Improve the Aging Resistance
title_short Modification of Polycaprolactone with Plant Extracts to Improve the Aging Resistance
title_sort modification of polycaprolactone with plant extracts to improve the aging resistance
topic polycaprolactone
polyphenols
plant extracts
accelerated aging
url https://www.mdpi.com/1996-1944/16/14/5154
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AT rafałmalinowski modificationofpolycaprolactonewithplantextractstoimprovetheagingresistance
AT tomaszkarasiewicz modificationofpolycaprolactonewithplantextractstoimprovetheagingresistance
AT bartłomiejjagodzinski modificationofpolycaprolactonewithplantextractstoimprovetheagingresistance
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