Atomic reconstruction induced by uniaxial stress in MnP

Abstract In condensed matter physics, pressure is frequently used to modify the stability of both electronic states and atomic arrangements. Under isotropic pressure, the intermetallic compound MnP has recently attracted attention for the interplay between pressure-induced superconductivity and comp...

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Main Authors: Tatsuya Kozawa, Masayoshi Fujihala, Takeru Uchihara, Setsuo Mitsuda, Shin-ichiro Yano, Hiromu Tamatsukuri, Koji Munakata, Akiko Nakao
Format: Article
Language:English
Published: Nature Portfolio 2023-08-01
Series:Scientific Reports
Online Access:https://doi.org/10.1038/s41598-023-40806-1
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author Tatsuya Kozawa
Masayoshi Fujihala
Takeru Uchihara
Setsuo Mitsuda
Shin-ichiro Yano
Hiromu Tamatsukuri
Koji Munakata
Akiko Nakao
author_facet Tatsuya Kozawa
Masayoshi Fujihala
Takeru Uchihara
Setsuo Mitsuda
Shin-ichiro Yano
Hiromu Tamatsukuri
Koji Munakata
Akiko Nakao
author_sort Tatsuya Kozawa
collection DOAJ
description Abstract In condensed matter physics, pressure is frequently used to modify the stability of both electronic states and atomic arrangements. Under isotropic pressure, the intermetallic compound MnP has recently attracted attention for the interplay between pressure-induced superconductivity and complicated magnetic order in the vicinity . By contrast, we use uniaxial stress, a directional type of pressure, to investigate the effect on the magnetism and crystal structure of this compound. An irreversible magnetisation response induced by uniaxial stress is discovered in MnP at uniaxial stress as low as $$0.04\ \text {GPa}$$ 0.04 GPa . Neutron diffraction experiments reveal that uniaxial stress forms crystal domains that satisfy pseudo-rotational symmetry unique to the MnP-type structure. The structure of the coexisting domains accounts for the stress-induced magnetism. We term this first discovered phenomenon atomic reconstruction (AR) induced by uniaxial stress. Furthermore, our calculation results provide guidelines on the search for AR candidates. AR allows crystal domain engineering to control anisotropic properties of materials, including dielectricity, elasticity, electrical conduction, magnetism and superconductivity. A wide-ranging exploration of potential AR candidates would ensure that crystal domain engineering yields unconventional methods to design functional multi-domain materials for a wide variety of purposes.
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spelling doaj.art-ccc61c0bdf434b1e8c5bad076a3541ba2023-11-20T09:10:41ZengNature PortfolioScientific Reports2045-23222023-08-011311810.1038/s41598-023-40806-1Atomic reconstruction induced by uniaxial stress in MnPTatsuya Kozawa0Masayoshi Fujihala1Takeru Uchihara2Setsuo Mitsuda3Shin-ichiro Yano4Hiromu Tamatsukuri5Koji Munakata6Akiko Nakao7Department of Physics, Faculty of Science, Tokyo University of ScienceDepartment of Physics, Faculty of Science, Tokyo University of ScienceDepartment of Physics, Faculty of Science, Tokyo University of ScienceDepartment of Physics, Faculty of Science, Tokyo University of ScienceNational Synchrotron Radiation Research CenterDepartment of Physics, Faculty of Science, Tokyo University of ScienceNeutron Science and Technology Center, Comprehensive Research Organization for Science and SocietyNeutron Science and Technology Center, Comprehensive Research Organization for Science and SocietyAbstract In condensed matter physics, pressure is frequently used to modify the stability of both electronic states and atomic arrangements. Under isotropic pressure, the intermetallic compound MnP has recently attracted attention for the interplay between pressure-induced superconductivity and complicated magnetic order in the vicinity . By contrast, we use uniaxial stress, a directional type of pressure, to investigate the effect on the magnetism and crystal structure of this compound. An irreversible magnetisation response induced by uniaxial stress is discovered in MnP at uniaxial stress as low as $$0.04\ \text {GPa}$$ 0.04 GPa . Neutron diffraction experiments reveal that uniaxial stress forms crystal domains that satisfy pseudo-rotational symmetry unique to the MnP-type structure. The structure of the coexisting domains accounts for the stress-induced magnetism. We term this first discovered phenomenon atomic reconstruction (AR) induced by uniaxial stress. Furthermore, our calculation results provide guidelines on the search for AR candidates. AR allows crystal domain engineering to control anisotropic properties of materials, including dielectricity, elasticity, electrical conduction, magnetism and superconductivity. A wide-ranging exploration of potential AR candidates would ensure that crystal domain engineering yields unconventional methods to design functional multi-domain materials for a wide variety of purposes.https://doi.org/10.1038/s41598-023-40806-1
spellingShingle Tatsuya Kozawa
Masayoshi Fujihala
Takeru Uchihara
Setsuo Mitsuda
Shin-ichiro Yano
Hiromu Tamatsukuri
Koji Munakata
Akiko Nakao
Atomic reconstruction induced by uniaxial stress in MnP
Scientific Reports
title Atomic reconstruction induced by uniaxial stress in MnP
title_full Atomic reconstruction induced by uniaxial stress in MnP
title_fullStr Atomic reconstruction induced by uniaxial stress in MnP
title_full_unstemmed Atomic reconstruction induced by uniaxial stress in MnP
title_short Atomic reconstruction induced by uniaxial stress in MnP
title_sort atomic reconstruction induced by uniaxial stress in mnp
url https://doi.org/10.1038/s41598-023-40806-1
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