Fe in magma - An overview

The strong influence of physical conditions during magma formation on Fe equilibria offers a large variety of
 possibilities to deduce these conditions from Fe-bearing phases and phase assemblages found in magmatic rocks.
 Conditions of magma genesis and their evolution are of major...

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Main Author: M. Wilke
Format: Article
Language:English
Published: Istituto Nazionale di Geofisica e Vulcanologia (INGV) 2005-06-01
Series:Annals of Geophysics
Subjects:
Online Access:http://www.annalsofgeophysics.eu/index.php/annals/article/view/3222
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author M. Wilke
author_facet M. Wilke
author_sort M. Wilke
collection DOAJ
description The strong influence of physical conditions during magma formation on Fe equilibria offers a large variety of
 possibilities to deduce these conditions from Fe-bearing phases and phase assemblages found in magmatic rocks.
 Conditions of magma genesis and their evolution are of major interest for the understanding of volcanic eruptions.
 A brief overview on the most common methods used is given together with potential problems and limitations.
 Fe equilibria are not only sensitive to changes in intensive parameters (especially T and fO2) and extensive
 parameters like composition also have major effects, so that direct application of experimentally calibrated
 equilibria to natural systems is not always possible. Best estimates for pre-eruptive conditions are certainly
 achieved by studies that relate field observations directly to experimental observations for the composition of
 interest using as many constraints as possible (phase stability relations, Fe-Ti oxides, Fe partitioning between
 phases, Fe oxidation state in glass etc.). Local structural environment of Fe in silicate melts is an important parameter
 that is needed to understand the relationship between melt transport properties and melt structure. Assignment
 of Fe co-ordination and its relationship to the oxidation state seems not to be straightforward. In addition,
 there is considerable evidence that the co-ordination of Fe in glass differs from that in the melt, which has
 to be taken into account when linking melt structure to physical properties of silicate melts at T and P.
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spelling doaj.art-ccf637727b8a48869ab9b55bcb4303e32022-12-22T02:07:41ZengIstituto Nazionale di Geofisica e Vulcanologia (INGV)Annals of Geophysics1593-52132037-416X2005-06-01484-510.4401/ag-3222Fe in magma - An overviewM. WilkeThe strong influence of physical conditions during magma formation on Fe equilibria offers a large variety of
 possibilities to deduce these conditions from Fe-bearing phases and phase assemblages found in magmatic rocks.
 Conditions of magma genesis and their evolution are of major interest for the understanding of volcanic eruptions.
 A brief overview on the most common methods used is given together with potential problems and limitations.
 Fe equilibria are not only sensitive to changes in intensive parameters (especially T and fO2) and extensive
 parameters like composition also have major effects, so that direct application of experimentally calibrated
 equilibria to natural systems is not always possible. Best estimates for pre-eruptive conditions are certainly
 achieved by studies that relate field observations directly to experimental observations for the composition of
 interest using as many constraints as possible (phase stability relations, Fe-Ti oxides, Fe partitioning between
 phases, Fe oxidation state in glass etc.). Local structural environment of Fe in silicate melts is an important parameter
 that is needed to understand the relationship between melt transport properties and melt structure. Assignment
 of Fe co-ordination and its relationship to the oxidation state seems not to be straightforward. In addition,
 there is considerable evidence that the co-ordination of Fe in glass differs from that in the melt, which has
 to be taken into account when linking melt structure to physical properties of silicate melts at T and P.http://www.annalsofgeophysics.eu/index.php/annals/article/view/3222ironsilicate meltredox conditions
spellingShingle M. Wilke
Fe in magma - An overview
Annals of Geophysics
iron
silicate melt
redox conditions
title Fe in magma - An overview
title_full Fe in magma - An overview
title_fullStr Fe in magma - An overview
title_full_unstemmed Fe in magma - An overview
title_short Fe in magma - An overview
title_sort fe in magma an overview
topic iron
silicate melt
redox conditions
url http://www.annalsofgeophysics.eu/index.php/annals/article/view/3222
work_keys_str_mv AT mwilke feinmagmaanoverview