Innovative Method for Coating of Natural Corrosion Inhibitor Based on <i>Artemisia vulgaris</i>

In this work, the production of a novel methodology for the application of natural corrosion inhibitors on steel, using an autoclave is presented. Tests were carried out using <i>Artemisia vulgaris</i>. The inhibitor was produced with a simple soxhlet extraction process using 15 g of <...

Full description

Bibliographic Details
Main Authors: Daniel Alejandro Pineda Hernández, Elisabeth Restrepo Parra, Pedro José Arango Arango, Belarmino Segura Giraldo, Carlos Daniel Acosta Medina
Format: Article
Language:English
Published: MDPI AG 2021-04-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/14/9/2234
_version_ 1797536207259828224
author Daniel Alejandro Pineda Hernández
Elisabeth Restrepo Parra
Pedro José Arango Arango
Belarmino Segura Giraldo
Carlos Daniel Acosta Medina
author_facet Daniel Alejandro Pineda Hernández
Elisabeth Restrepo Parra
Pedro José Arango Arango
Belarmino Segura Giraldo
Carlos Daniel Acosta Medina
author_sort Daniel Alejandro Pineda Hernández
collection DOAJ
description In this work, the production of a novel methodology for the application of natural corrosion inhibitors on steel, using an autoclave is presented. Tests were carried out using <i>Artemisia vulgaris</i>. The inhibitor was produced with a simple soxhlet extraction process using 15 g of <i>Artemisia vulgaris</i> and 260 mL of Ether. Once the inhibitor was produced, the steel was immersed in it, to form a coating that protects the material against corrosion. Thermogravimetry analyzes (TGA) were performed on the inhibitor, to determine the degradation temperature; it was observed that, at 321 °C, the loss of organic mass begins. After applying the inhibitor to the steel, the Fourier Transform Infrared Spectroscopy (FTIR) technique was used to determine the vibrational bands and the difference between the spectra for the steels before and after the coating was applied. For the evaluation of the method efficiency, Electrochemical Impedance Spectroscopy (EIS) and polarization resistance tests were performed, where Nyquist diagrams and Tafel curves were obtained, for steels with and without treatment. In this case, an increase of 93% in the corrosion resistance, and an 88% decrease in the corrosion rate were observed, proving that this methodology can be used to protect steel against corrosion and extend the steel’s useful life.
first_indexed 2024-03-10T11:56:22Z
format Article
id doaj.art-ccf81cd620754f2984e2369ebb32a438
institution Directory Open Access Journal
issn 1996-1944
language English
last_indexed 2024-03-10T11:56:22Z
publishDate 2021-04-01
publisher MDPI AG
record_format Article
series Materials
spelling doaj.art-ccf81cd620754f2984e2369ebb32a4382023-11-21T17:16:52ZengMDPI AGMaterials1996-19442021-04-01149223410.3390/ma14092234Innovative Method for Coating of Natural Corrosion Inhibitor Based on <i>Artemisia vulgaris</i>Daniel Alejandro Pineda Hernández0Elisabeth Restrepo Parra1Pedro José Arango Arango2Belarmino Segura Giraldo3Carlos Daniel Acosta Medina4Laboratorio de Física del Plasma, Unicversidad Nacional de Colombia sede Manizales, Manizales-Caldas 170003, ColombiaLaboratorio de Física del Plasma, Unicversidad Nacional de Colombia sede Manizales, Manizales-Caldas 170003, ColombiaLaboratorio de Física del Plasma, Unicversidad Nacional de Colombia sede Manizales, Manizales-Caldas 170003, ColombiaLaboratorio de Física del Plasma, Unicversidad Nacional de Colombia sede Manizales, Manizales-Caldas 170003, ColombiaCalculo Científico y Modelamiento Matemático, Universidad Nacional de Colombia sede Manizales, Manizales-Caldas 170003, ColombiaIn this work, the production of a novel methodology for the application of natural corrosion inhibitors on steel, using an autoclave is presented. Tests were carried out using <i>Artemisia vulgaris</i>. The inhibitor was produced with a simple soxhlet extraction process using 15 g of <i>Artemisia vulgaris</i> and 260 mL of Ether. Once the inhibitor was produced, the steel was immersed in it, to form a coating that protects the material against corrosion. Thermogravimetry analyzes (TGA) were performed on the inhibitor, to determine the degradation temperature; it was observed that, at 321 °C, the loss of organic mass begins. After applying the inhibitor to the steel, the Fourier Transform Infrared Spectroscopy (FTIR) technique was used to determine the vibrational bands and the difference between the spectra for the steels before and after the coating was applied. For the evaluation of the method efficiency, Electrochemical Impedance Spectroscopy (EIS) and polarization resistance tests were performed, where Nyquist diagrams and Tafel curves were obtained, for steels with and without treatment. In this case, an increase of 93% in the corrosion resistance, and an 88% decrease in the corrosion rate were observed, proving that this methodology can be used to protect steel against corrosion and extend the steel’s useful life.https://www.mdpi.com/1996-1944/14/9/2234EISorganic coatingtafelmild steelcorrosion
spellingShingle Daniel Alejandro Pineda Hernández
Elisabeth Restrepo Parra
Pedro José Arango Arango
Belarmino Segura Giraldo
Carlos Daniel Acosta Medina
Innovative Method for Coating of Natural Corrosion Inhibitor Based on <i>Artemisia vulgaris</i>
Materials
EIS
organic coating
tafel
mild steel
corrosion
title Innovative Method for Coating of Natural Corrosion Inhibitor Based on <i>Artemisia vulgaris</i>
title_full Innovative Method for Coating of Natural Corrosion Inhibitor Based on <i>Artemisia vulgaris</i>
title_fullStr Innovative Method for Coating of Natural Corrosion Inhibitor Based on <i>Artemisia vulgaris</i>
title_full_unstemmed Innovative Method for Coating of Natural Corrosion Inhibitor Based on <i>Artemisia vulgaris</i>
title_short Innovative Method for Coating of Natural Corrosion Inhibitor Based on <i>Artemisia vulgaris</i>
title_sort innovative method for coating of natural corrosion inhibitor based on i artemisia vulgaris i
topic EIS
organic coating
tafel
mild steel
corrosion
url https://www.mdpi.com/1996-1944/14/9/2234
work_keys_str_mv AT danielalejandropinedahernandez innovativemethodforcoatingofnaturalcorrosioninhibitorbasedoniartemisiavulgarisi
AT elisabethrestrepoparra innovativemethodforcoatingofnaturalcorrosioninhibitorbasedoniartemisiavulgarisi
AT pedrojosearangoarango innovativemethodforcoatingofnaturalcorrosioninhibitorbasedoniartemisiavulgarisi
AT belarminoseguragiraldo innovativemethodforcoatingofnaturalcorrosioninhibitorbasedoniartemisiavulgarisi
AT carlosdanielacostamedina innovativemethodforcoatingofnaturalcorrosioninhibitorbasedoniartemisiavulgarisi