Synthesis of Carboxymethyl Cellulose-Acrylate-OvPOSS Graft Copolymer and its Application in Paper Protection
As an important part of cultural heritage, paper cultural relics have important historical, scientific and humanistic values. However, a large number of paper cultural relics are suffering from aging, mildew, yellowing, cracks, embrittlement and other threats, or are even completely damaged. To enha...
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| Format: | Article |
| Language: | English |
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Kaunas University of Technology
2023-02-01
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| Series: | Medžiagotyra |
| Subjects: | |
| Online Access: | https://matsc.ktu.lt/index.php/MatSc/article/view/29181 |
| _version_ | 1797900517436817408 |
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| author | Jinjie ZHANG Yingping QI Yongfeng SHEN Hua LI |
| author_facet | Jinjie ZHANG Yingping QI Yongfeng SHEN Hua LI |
| author_sort | Jinjie ZHANG |
| collection | DOAJ |
| description | As an important part of cultural heritage, paper cultural relics have important historical, scientific and humanistic values. However, a large number of paper cultural relics are suffering from aging, mildew, yellowing, cracks, embrittlement and other threats, or are even completely damaged. To enhance the strength of paper cultural relics and prolong the life of paper cultural relics, a novel CMC-acrylate-OVPOSS graft copolymer was synthesized with carboxymethyl cellulose (CMC), methyl methacrylate (MMA), butyl acrylate (BA), hydroxyethyl methacrylate (HEMA), glycidyl methacrylate (GMA), octavinyl polyhedral oligomeric silsesquioxane (OVPOSS). The synthesized materials were analyzed by infrared spectroscopy, X-ray diffractometer, thermal analyzer and X-ray photoelectron spectroscopy. In addition, the reinforcement solution was coated on the surface of the paper, and the protective effect of the reinforcement solution on the paper was evaluated by testing the mechanical and optical properties of the paper. When the reinforcement solution with a mass concentration of 10 % was coated on the paper, the mechanical properties of the paper were greatly improved, and the gloss and whiteness were basically unchanged. |
| first_indexed | 2024-04-10T08:46:14Z |
| format | Article |
| id | doaj.art-cd3f4e315301462184a6622b7bf49050 |
| institution | Directory Open Access Journal |
| issn | 1392-1320 2029-7289 |
| language | English |
| last_indexed | 2024-04-10T08:46:14Z |
| publishDate | 2023-02-01 |
| publisher | Kaunas University of Technology |
| record_format | Article |
| series | Medžiagotyra |
| spelling | doaj.art-cd3f4e315301462184a6622b7bf490502023-02-22T07:43:12ZengKaunas University of TechnologyMedžiagotyra1392-13202029-72892023-02-01291586410.5755/j02.ms.2918134435Synthesis of Carboxymethyl Cellulose-Acrylate-OvPOSS Graft Copolymer and its Application in Paper ProtectionJinjie ZHANG0https://orcid.org/0000-0002-3998-5607Yingping QI1Yongfeng SHEN2Hua LI3https://orcid.org/0000-0003-0744-9698Zhengzhou UniversityZhengzhou MuseumZhengzhou MuseumZhengzhou UniversityAs an important part of cultural heritage, paper cultural relics have important historical, scientific and humanistic values. However, a large number of paper cultural relics are suffering from aging, mildew, yellowing, cracks, embrittlement and other threats, or are even completely damaged. To enhance the strength of paper cultural relics and prolong the life of paper cultural relics, a novel CMC-acrylate-OVPOSS graft copolymer was synthesized with carboxymethyl cellulose (CMC), methyl methacrylate (MMA), butyl acrylate (BA), hydroxyethyl methacrylate (HEMA), glycidyl methacrylate (GMA), octavinyl polyhedral oligomeric silsesquioxane (OVPOSS). The synthesized materials were analyzed by infrared spectroscopy, X-ray diffractometer, thermal analyzer and X-ray photoelectron spectroscopy. In addition, the reinforcement solution was coated on the surface of the paper, and the protective effect of the reinforcement solution on the paper was evaluated by testing the mechanical and optical properties of the paper. When the reinforcement solution with a mass concentration of 10 % was coated on the paper, the mechanical properties of the paper were greatly improved, and the gloss and whiteness were basically unchanged.https://matsc.ktu.lt/index.php/MatSc/article/view/29181keywords: paper cultural relics, paper protection, carboxymethyl cellulose, acrylate |
| spellingShingle | Jinjie ZHANG Yingping QI Yongfeng SHEN Hua LI Synthesis of Carboxymethyl Cellulose-Acrylate-OvPOSS Graft Copolymer and its Application in Paper Protection Medžiagotyra keywords: paper cultural relics, paper protection, carboxymethyl cellulose, acrylate |
| title | Synthesis of Carboxymethyl Cellulose-Acrylate-OvPOSS Graft Copolymer and its Application in Paper Protection |
| title_full | Synthesis of Carboxymethyl Cellulose-Acrylate-OvPOSS Graft Copolymer and its Application in Paper Protection |
| title_fullStr | Synthesis of Carboxymethyl Cellulose-Acrylate-OvPOSS Graft Copolymer and its Application in Paper Protection |
| title_full_unstemmed | Synthesis of Carboxymethyl Cellulose-Acrylate-OvPOSS Graft Copolymer and its Application in Paper Protection |
| title_short | Synthesis of Carboxymethyl Cellulose-Acrylate-OvPOSS Graft Copolymer and its Application in Paper Protection |
| title_sort | synthesis of carboxymethyl cellulose acrylate ovposs graft copolymer and its application in paper protection |
| topic | keywords: paper cultural relics, paper protection, carboxymethyl cellulose, acrylate |
| url | https://matsc.ktu.lt/index.php/MatSc/article/view/29181 |
| work_keys_str_mv | AT jinjiezhang synthesisofcarboxymethylcelluloseacrylateovpossgraftcopolymeranditsapplicationinpaperprotection AT yingpingqi synthesisofcarboxymethylcelluloseacrylateovpossgraftcopolymeranditsapplicationinpaperprotection AT yongfengshen synthesisofcarboxymethylcelluloseacrylateovpossgraftcopolymeranditsapplicationinpaperprotection AT huali synthesisofcarboxymethylcelluloseacrylateovpossgraftcopolymeranditsapplicationinpaperprotection |