SYNTHESIS AND STRUCTURAL CHARACTERISTICS OF BIS(CITRATE)GERMANATES(IV) (Hbipy)2[Ge(HCit)2]•2H2O AND [CuCl(bipy)2]2[Ge(HCit)2]•8H2O
The crystalline compounds (Hbipy)2[Ge(HCit)2]·2H2O (1) and CuCl(bipy)2]2[Ge(HCit)2]·8H2O (2) (where H4Cit is citric acid, bipy is 2,2ʹ-bipyridine) were obtained for the fi rst time and their structures were determined by the single-crystal X-ray diffraction method. Compounds were characterized by IR...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
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Academy of Sciences of Moldova, Institute of Chemistry
2016-12-01
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| Series: | Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry |
| Subjects: | |
| Online Access: | http://www.cjm.asm.md/sites/default/files/article_files/ChemJMold201611(2)_52-57_Martsinko.pdf |
| _version_ | 1818874919573782528 |
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| author | Inna Seifullina Elena Martsinko Elena Chebanenko Olha Pirozhok Viktoriya Dyakonenko Svitlana Shishkina |
| author_facet | Inna Seifullina Elena Martsinko Elena Chebanenko Olha Pirozhok Viktoriya Dyakonenko Svitlana Shishkina |
| author_sort | Inna Seifullina |
| collection | DOAJ |
| description | The crystalline compounds (Hbipy)2[Ge(HCit)2]·2H2O (1) and CuCl(bipy)2]2[Ge(HCit)2]·8H2O (2) (where H4Cit is citric acid, bipy is 2,2ʹ-bipyridine) were obtained for the fi rst time and their structures were determined by the single-crystal X-ray diffraction method. Compounds were characterized by IR spectroscopy, thermogravimetric (TGA) and elemental analyses. Both compounds are formed with complex bis(citrate)germanate anion and protonated
2,2’-bipyridine or [Cu(bipy)2Cl]+ as cations in compounds 1 and 2, respectively. |
| first_indexed | 2024-12-19T13:18:15Z |
| format | Article |
| id | doaj.art-cd4a9bb2f5424a12a7d0fc4ac330eb28 |
| institution | Directory Open Access Journal |
| issn | 1857-1727 2345-1688 |
| language | English |
| last_indexed | 2024-12-19T13:18:15Z |
| publishDate | 2016-12-01 |
| publisher | Academy of Sciences of Moldova, Institute of Chemistry |
| record_format | Article |
| series | Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry |
| spelling | doaj.art-cd4a9bb2f5424a12a7d0fc4ac330eb282022-12-21T20:19:46ZengAcademy of Sciences of Moldova, Institute of ChemistryChemistry Journal of Moldova: General, Industrial and Ecological Chemistry1857-17272345-16882016-12-011125257dx.doi.org/10.19261/cjm.2016.11(2).11 SYNTHESIS AND STRUCTURAL CHARACTERISTICS OF BIS(CITRATE)GERMANATES(IV) (Hbipy)2[Ge(HCit)2]•2H2O AND [CuCl(bipy)2]2[Ge(HCit)2]•8H2OInna Seifullina0Elena Martsinko1Elena Chebanenko2Olha Pirozhok3Viktoriya Dyakonenko4Svitlana Shishkina5I.I. Mechnikov Odessa National University, Odessa 65082, UkraineI.I. Mechnikov Odessa National University, Odessa 65082, UkraineI.I. Mechnikov Odessa National University, Odessa 65082, UkraineI.I. Mechnikov Odessa National University, Odessa 65082, UkraineSSI “Institute for Single Crystals”, National Academy of Sciences of Ukraine, 60, Nauki Ave., Kharkiv 61001, UkraineSSI “Institute for Single Crystals”, National Academy of Sciences of Ukraine, 60, Nauki Ave., Kharkiv 61001, Ukraine; V.N. Karazin Kharkiv National University, 4 Svobody sq., Kharkiv 61077, UkraineThe crystalline compounds (Hbipy)2[Ge(HCit)2]·2H2O (1) and CuCl(bipy)2]2[Ge(HCit)2]·8H2O (2) (where H4Cit is citric acid, bipy is 2,2ʹ-bipyridine) were obtained for the fi rst time and their structures were determined by the single-crystal X-ray diffraction method. Compounds were characterized by IR spectroscopy, thermogravimetric (TGA) and elemental analyses. Both compounds are formed with complex bis(citrate)germanate anion and protonated 2,2’-bipyridine or [Cu(bipy)2Cl]+ as cations in compounds 1 and 2, respectively.http://www.cjm.asm.md/sites/default/files/article_files/ChemJMold201611(2)_52-57_Martsinko.pdfgermanium(IV) compoundcitric acid22’-bipyridinecopper(II) complexstructure |
| spellingShingle | Inna Seifullina Elena Martsinko Elena Chebanenko Olha Pirozhok Viktoriya Dyakonenko Svitlana Shishkina SYNTHESIS AND STRUCTURAL CHARACTERISTICS OF BIS(CITRATE)GERMANATES(IV) (Hbipy)2[Ge(HCit)2]•2H2O AND [CuCl(bipy)2]2[Ge(HCit)2]•8H2O Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry germanium(IV) compound citric acid 2 2’-bipyridine copper(II) complex structure |
| title | SYNTHESIS AND STRUCTURAL CHARACTERISTICS OF BIS(CITRATE)GERMANATES(IV) (Hbipy)2[Ge(HCit)2]•2H2O AND [CuCl(bipy)2]2[Ge(HCit)2]•8H2O |
| title_full | SYNTHESIS AND STRUCTURAL CHARACTERISTICS OF BIS(CITRATE)GERMANATES(IV) (Hbipy)2[Ge(HCit)2]•2H2O AND [CuCl(bipy)2]2[Ge(HCit)2]•8H2O |
| title_fullStr | SYNTHESIS AND STRUCTURAL CHARACTERISTICS OF BIS(CITRATE)GERMANATES(IV) (Hbipy)2[Ge(HCit)2]•2H2O AND [CuCl(bipy)2]2[Ge(HCit)2]•8H2O |
| title_full_unstemmed | SYNTHESIS AND STRUCTURAL CHARACTERISTICS OF BIS(CITRATE)GERMANATES(IV) (Hbipy)2[Ge(HCit)2]•2H2O AND [CuCl(bipy)2]2[Ge(HCit)2]•8H2O |
| title_short | SYNTHESIS AND STRUCTURAL CHARACTERISTICS OF BIS(CITRATE)GERMANATES(IV) (Hbipy)2[Ge(HCit)2]•2H2O AND [CuCl(bipy)2]2[Ge(HCit)2]•8H2O |
| title_sort | synthesis and structural characteristics of bis citrate germanates iv hbipy 2 ge hcit 2 •2h2o and cucl bipy 2 2 ge hcit 2 •8h2o |
| topic | germanium(IV) compound citric acid 2 2’-bipyridine copper(II) complex structure |
| url | http://www.cjm.asm.md/sites/default/files/article_files/ChemJMold201611(2)_52-57_Martsinko.pdf |
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