(C5H12N)Cu2Br3: A Piperidinium Copper(I) Bromide with [Cu2Br3]− Ladders

(C5H12N)Cu2Br3: A Piperidinium Copper(I) Bromide with [Cu2Br3]− Ladders

Piperidinium copper(I) bromide, (C5H12N)Cu2Br3, was obtained from a solution of CuBr2, piperidine, and HBr in ethanol. At 60 °C ethanol slowly reduces copper(II) to copper(I). Colorless plates of (C5H12N)Cu2Br3 crystallize in the triclinic space group P-1 with lattice parameters of a = 6.2948(10) Å,...

Full description

Bibliographic Details
Main Authors:	Karl W. Krämer, Daniel Biner, Antonia Neels, Theresa Komm
Format:	Article
Language:	English
Published:	MDPI AG 2012-10-01
Series:	Crystals
Subjects:	halides copper bromine solid state structure X-ray diffraction
Online Access:	http://www.mdpi.com/2073-4352/2/4/1434

Similar Items

Tunable Dual‐Band White Light Emission from Gua3CuCl4 and Gua7Cu3X10·3DMF (X = Br, I)
by: Isaiah W. Gilley, et al.
Published: (2022-12-01)

Structural and Luminescence Properties of Cu(I)X-Quinoxaline under High Pressure (X = Br, I)
by: Javier Gonzalez-Platas, et al.
Published: (2023-01-01)

Copper-promoted C5-selective bromination of 8-aminoquinoline amides with alkyl bromides
by: Changdong Shao, et al.
Published: (2024-01-01)

1,4-Dibromo-2,5-bis(phenylalkoxy)benzene Derivatives: C–Br...π(arene) <em>Versus</em> C–H...Br and Br...Br Interactions in the Solid State
by: Giacomo Manfroni, et al.
Published: (2021-03-01)

Regioselective Monobromination of Phenols with KBr and ZnAl–BrO<sub>3</sub><sup>−</sup>–Layered Double Hydroxides
by: Ligeng Wang, et al.
Published: (2020-02-01)

Phase Equilibria in Ternary System CsBr-AgBr-InBr<sub>3</sub>
by: Rustam K. Kamilov, et al.
Published: (2023-01-01)

Polyvinylpyrrolidone-bromine complex: An efficient polymeric reagent for selective preparation of benzyl bromides in the presence of hexamethyldisilane
by: Moslem M. Lakouraj, et al.
Published: (2012-08-01)

Structure and surface properties of size-tuneable CsPbBr₃ nanocrystals
by: Hooper, Thomas J. N., et al.
Published: (2022)

In Search of a Double Perovskite in the Phase Triangle of Bromides CsBr-CuBr-InBr<sub>3</sub>
by: Rustam K. Kamilov, et al.
Published: (2023-05-01)

Growth of Eu doped LiBr/BaBr2 eutectic and its thermal neutron response
by: Yui Takizawa, et al.
Published: (2023-02-01)

Post treatment for precise size and shape control of monodisperse CsPbBr₃ nanocrystals under ambient condition using ZnBr₂
by: Foo, Di Kai, et al.
Published: (2023)

Simple and Regioselective Bromination of 5,6-Disubstituted-indan-1-ones with Br2 Under Acidic and Basic Conditions
by: Eunsook Ma, et al.
Published: (2007-01-01)

Grain size modulation and interfacial engineering of CH3NH3PbBr3 emitter films through incorporation of tetraethylammonium bromide
by: Nur Fadilah Jamaludin, et al.
Published: (2020)

Reactions of copper(II) bromide with 2,6-diacetylpyridine bis(phenyl-hydrazone) (L)-molecular and crystal structure of L and its mixed-valence complex [CuIIL2][CuI2Br4]
by: Rodić Marko V., et al.
Published: (2022-01-01)

Practice of electron microscopy on nanoparticles sensitive to radiation damage: CsPbBr3 nanocrystals as a case study
by: Tuan M. Duong, et al.
Published: (2022-12-01)

Bis(1,2,3-trimethylpyridinium) Octa(μ<sub>2</sub>-bromido)Tetrabromidopentacuprate(II): Linear, Quasi-Planar Pentacopper(II) Oligomers Stacked to Form Egg-Tray Layers
by: Subhash Akkina, et al.
Published: (2022-09-01)

Excitonic Enhancement and Excited Excitonic States in CsPbBr<sub>3</sub> Halide Perovskite Single Crystals
by: Anna Yu. Samsonova, et al.
Published: (2022-12-01)

Stable bromine isotopic composition of atmospheric CH3Br
by: Axel Horst, et al.
Published: (2013-09-01)

In Situ Recrystallization of Co-Evaporated Cu(In,Ga)Se<sub>2</sub> Thin Films by Copper Chloride Vapor Treatment towards Solar Cell Applications
by: Deewakar Poudel, et al.
Published: (2021-07-01)

Leaching Br from high bromine containing circuit board smelting flue dust by sodium hydroxide solution: thermodynamics and kinetics study
by: Qiang Deng, et al.
Published: (2020-07-01)

Crystal structures of three N-aryl-2,2,2-tribromoacetamides
by: S. Sreenivasa, et al.
Published: (2015-09-01)

Biotransformation of Flavonoids with -NO<sub>2</sub>, -CH<sub>3</sub> Groups and -Br, -Cl Atoms by Entomopathogenic Filamentous Fungi
by: Martyna Perz, et al.
Published: (2023-05-01)

Fabricating Surface-Functionalized CsPbBr3/Cs4PbBr6 Nanosheets for Visible-Light Photocatalytic Oxidation of Styrene
by: Ping Qiu, et al.
Published: (2020-03-01)

Ge–Cu-Complexes Ph(pyO)Ge(μ<sup>2</sup>-pyO)<sub>2</sub>CuCl and PhGe(μ<sup>2</sup>-pyO)<sub>4</sub>CuCl—Representatives of Cu(I)→Ge(IV) and Cu(II)→Ge(IV) Dative Bond Systems
by: Jörg Wagler, et al.
Published: (2023-07-01)

A MAPbBr3/PdSe2 Schottky junction-based optoelectronic sensor with self-powered and switchable photocurrents
by: Jingni Zhang, et al.
Published: (2023-10-01)

On the Role of Cs<sub>4</sub>PbBr<sub>6</sub> Phase in the Luminescence Performance of Bright CsPbBr<sub>3</sub> Nanocrystals
by: Kateřina Děcká, et al.
Published: (2021-07-01)

In Situ Measurement of Localized Current Distribution in H<sub>2</sub>-Br<sub>2</sub> Redox Flow Batteries
by: Brenda Berenice Martinez Cantu, et al.
Published: (2021-08-01)

Bromine Isotope Variations in Magmatic and Hydrothermal Sodalite and Tugtupite and the Estimation of Br Isotope Fractionation between Melt and Sodalite
by: Hans G. M. Eggenkamp, et al.
Published: (2021-03-01)

Chemical conversion of electrodeposited PbO2 to the all-inorganic cesium lead halide perovskites CsPbBr3 and CsPbCl3
by: Tao Liu, et al.
Published: (2022-10-01)

Using Imidazolium in the Construction of Hybrid 2D and 3D Lead Bromide Pseudoperovskites
by: Gonzalo García-Espejo, et al.
Published: (2023-05-01)

Efficient Photocatalytic CO<sub>2</sub> Reduction with MIL-100(Fe)-CsPbBr<sub>3</sub> Composites
by: Ruolin Cheng, et al.
Published: (2020-11-01)

Efficient Carbon-Based CsPbBr3 Inorganic Perovskite Solar Cells by Using Cu-Phthalocyanine as Hole Transport Material
by: Zhiyong Liu, et al.
Published: (2018-01-01)

Dopant Control of Solution‐Processed CuI:S for Highly Conductive p‐Type Transparent Electrode
by: Minki Son, et al.
Published: (2024-04-01)

Unprecedented formation of reactive BrO– ions and their role as mediators for organic compounds degradation: The fate of bromide ions released during the anodic oxidation of Bromophenol blue dye
by: Camila Carvalho de Almeida, et al.
Published: (2023-12-01)

An Ultra‐Low Self‐Discharge Aqueous|Organic Membraneless Battery with Minimized Br2 Cross‐Over
by: Han Yang, et al.
Published: (2024-02-01)

Improving the Stability of CsPbBr3 Perovskite Nanocrystals by Peroxides Post-treatment
by: Min Liu, et al.
Published: (2019-11-01)

Comparative Analysis of Hg<sub>2</sub>Br<sub>2</sub> and Hg<sub>2</sub>Br<sub>x</sub>Cl<sub>2-x</sub> Crystals Grown via PVT
by: Ojun Kwon, et al.
Published: (2020-11-01)

Enlightening the temperature coefficient of triple mesoscopic CH3NH3PbI3−x Cl x /NiO and double mesoscopic CsFAMAPbI3−x Br x /CuSCN carbon perovskite solar cells
by: Shubhranshu Bhandari, et al.
Published: (2023-01-01)

Fabrication of aqueous stable CH3NH3PbBr3 perovskite: Addressing optoelectronics and fluorescent sensing applications
by: Saba Pervaiz, et al.
Published: (2024-03-01)

2-(1-Bromo-1-methyl-ethyl)-2-methyl-[1,3]dioxolane
by: Adolfo Sánchez, et al.
Published: (2004-03-01)