Synthesis, characterization, and crystal structure of 2-(2-azidophenyl)-3-oxo-3H-indole 1-oxide
An attempt to explore the reactivity of the nitro group in the presence of gold catalysis in comparison to the azide group yielded intriguing results. Surprisingly, only the nitro group exhibited reactivity, ultimately giving rise to the formation of the title isatogen, C14H8N4O2. In the crystal str...
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2024-03-01
|
| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989024001440 |
| _version_ | 1827325328832331776 |
|---|---|
| author | Pawan Dhote Srinu Tothadi Chepuri V. Ramana |
| author_facet | Pawan Dhote Srinu Tothadi Chepuri V. Ramana |
| author_sort | Pawan Dhote |
| collection | DOAJ |
| description | An attempt to explore the reactivity of the nitro group in the presence of gold catalysis in comparison to the azide group yielded intriguing results. Surprisingly, only the nitro group exhibited reactivity, ultimately giving rise to the formation of the title isatogen, C14H8N4O2. In the crystal structure, weak C—H...O hydrogen bonds and π–π stacking interactions link the molecules. The structure exhibits disorder of the molecule. |
| first_indexed | 2024-03-07T14:25:34Z |
| format | Article |
| id | doaj.art-cd694f5a14c649f8a9c28d9b0c3e2c36 |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-03-07T14:25:34Z |
| publishDate | 2024-03-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-cd694f5a14c649f8a9c28d9b0c3e2c362024-03-06T08:47:40ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902024-03-0180331031310.1107/S2056989024001440dx2056Synthesis, characterization, and crystal structure of 2-(2-azidophenyl)-3-oxo-3H-indole 1-oxidePawan Dhote0Srinu Tothadi1Chepuri V. Ramana2Organic Chemistry Division, CSIR-National Chemical Laboratory, Pune, 411008, IndiaAnalytical and Environmental Sciences Division and Centralized Instrumentation Facility, CSIR-Central Salt and Marine Chemicals Research Institute, Gijubhai Badheka Marg, Bhavnagar, 364002 , IndiaOrganic Chemistry Division, CSIR-National Chemical Laboratory, Pune, 411008, IndiaAn attempt to explore the reactivity of the nitro group in the presence of gold catalysis in comparison to the azide group yielded intriguing results. Surprisingly, only the nitro group exhibited reactivity, ultimately giving rise to the formation of the title isatogen, C14H8N4O2. In the crystal structure, weak C—H...O hydrogen bonds and π–π stacking interactions link the molecules. The structure exhibits disorder of the molecule.http://scripts.iucr.org/cgi-bin/paper?S2056989024001440crystal structureisatogenreactivityhydrogen bonding |
| spellingShingle | Pawan Dhote Srinu Tothadi Chepuri V. Ramana Synthesis, characterization, and crystal structure of 2-(2-azidophenyl)-3-oxo-3H-indole 1-oxide Acta Crystallographica Section E: Crystallographic Communications crystal structure isatogen reactivity hydrogen bonding |
| title | Synthesis, characterization, and crystal structure of 2-(2-azidophenyl)-3-oxo-3H-indole 1-oxide |
| title_full | Synthesis, characterization, and crystal structure of 2-(2-azidophenyl)-3-oxo-3H-indole 1-oxide |
| title_fullStr | Synthesis, characterization, and crystal structure of 2-(2-azidophenyl)-3-oxo-3H-indole 1-oxide |
| title_full_unstemmed | Synthesis, characterization, and crystal structure of 2-(2-azidophenyl)-3-oxo-3H-indole 1-oxide |
| title_short | Synthesis, characterization, and crystal structure of 2-(2-azidophenyl)-3-oxo-3H-indole 1-oxide |
| title_sort | synthesis characterization and crystal structure of 2 2 azidophenyl 3 oxo 3h indole 1 oxide |
| topic | crystal structure isatogen reactivity hydrogen bonding |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989024001440 |
| work_keys_str_mv | AT pawandhote synthesischaracterizationandcrystalstructureof22azidophenyl3oxo3hindole1oxide AT srinutothadi synthesischaracterizationandcrystalstructureof22azidophenyl3oxo3hindole1oxide AT chepurivramana synthesischaracterizationandcrystalstructureof22azidophenyl3oxo3hindole1oxide |