Chlorido(4′-chloro-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)(trifluoromethanesulfonato-κO)zinc(II) acetonitrile monosolvate
In the title complex, [Zn(CF3O3S)Cl(C15H10ClN3)]·CH3CN, the zinc(II) core is fivefold coordinated by one chloride, one trifluoromethanesulfonate O atom and three terpyridine N atoms in a slightly distorted square-pyramidal geometry. The structure provides a distinct example amongst other zinc(II) 4-...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2020-09-01
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| Series: | IUCrData |
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314620012924 |
| _version_ | 1818847390333927424 |
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| author | Rafael A. Adrian Hadi D. Arman |
| author_facet | Rafael A. Adrian Hadi D. Arman |
| author_sort | Rafael A. Adrian |
| collection | DOAJ |
| description | In the title complex, [Zn(CF3O3S)Cl(C15H10ClN3)]·CH3CN, the zinc(II) core is fivefold coordinated by one chloride, one trifluoromethanesulfonate O atom and three terpyridine N atoms in a slightly distorted square-pyramidal geometry. The structure provides a distinct example amongst other zinc(II) 4-chloroterpyridine complexes because of the unusual planarity of the coordinated chloride, the short length of the Zn—N bond opposite to the chloride ligand [1.9572 (15) Å], and the presence of an elongated Zn—O bond [2.3911 (14) Å] in the coordinated trifluoromethanesulfonate ion. A molecule of acetonitrile is also found in the asymmetric unit of the title complex. |
| first_indexed | 2024-12-19T06:00:41Z |
| format | Article |
| id | doaj.art-cd6d99848df546c5b6df037bf6022cac |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-12-19T06:00:41Z |
| publishDate | 2020-09-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-cd6d99848df546c5b6df037bf6022cac2022-12-21T20:33:19ZengInternational Union of CrystallographyIUCrData2414-31462020-09-015910.1107/S2414314620012924vm4046Chlorido(4′-chloro-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)(trifluoromethanesulfonato-κO)zinc(II) acetonitrile monosolvateRafael A. Adrian0Hadi D. Arman1Department of Chemistry and Biochemistry, University of the Incarnate Word, San Antonio TX 78209, USADepartment of Chemistry, The University of Texas at San Antonio, San Antonio TX 78249, USAIn the title complex, [Zn(CF3O3S)Cl(C15H10ClN3)]·CH3CN, the zinc(II) core is fivefold coordinated by one chloride, one trifluoromethanesulfonate O atom and three terpyridine N atoms in a slightly distorted square-pyramidal geometry. The structure provides a distinct example amongst other zinc(II) 4-chloroterpyridine complexes because of the unusual planarity of the coordinated chloride, the short length of the Zn—N bond opposite to the chloride ligand [1.9572 (15) Å], and the presence of an elongated Zn—O bond [2.3911 (14) Å] in the coordinated trifluoromethanesulfonate ion. A molecule of acetonitrile is also found in the asymmetric unit of the title complex.http://scripts.iucr.org/cgi-bin/paper?S2414314620012924crystal structurezinc atomchloroterpyridine ligandfivefold coordinatedtrifluoromethanesulfonate salt |
| spellingShingle | Rafael A. Adrian Hadi D. Arman Chlorido(4′-chloro-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)(trifluoromethanesulfonato-κO)zinc(II) acetonitrile monosolvate IUCrData crystal structure zinc atom chloroterpyridine ligand fivefold coordinated trifluoromethanesulfonate salt |
| title | Chlorido(4′-chloro-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)(trifluoromethanesulfonato-κO)zinc(II) acetonitrile monosolvate |
| title_full | Chlorido(4′-chloro-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)(trifluoromethanesulfonato-κO)zinc(II) acetonitrile monosolvate |
| title_fullStr | Chlorido(4′-chloro-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)(trifluoromethanesulfonato-κO)zinc(II) acetonitrile monosolvate |
| title_full_unstemmed | Chlorido(4′-chloro-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)(trifluoromethanesulfonato-κO)zinc(II) acetonitrile monosolvate |
| title_short | Chlorido(4′-chloro-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)(trifluoromethanesulfonato-κO)zinc(II) acetonitrile monosolvate |
| title_sort | chlorido 4 chloro 2 2 6 2 terpyridine κ3n n n trifluoromethanesulfonato κo zinc ii acetonitrile monosolvate |
| topic | crystal structure zinc atom chloroterpyridine ligand fivefold coordinated trifluoromethanesulfonate salt |
| url | http://scripts.iucr.org/cgi-bin/paper?S2414314620012924 |
| work_keys_str_mv | AT rafaelaadrian chlorido4chloro2262terpyridinek3nnntrifluoromethanesulfonatokozinciiacetonitrilemonosolvate AT hadidarman chlorido4chloro2262terpyridinek3nnntrifluoromethanesulfonatokozinciiacetonitrilemonosolvate |