Corrosion behavior of a Co−Cr−Mo−Si alloy in pure Al and Al−Si melt

Metallic phase change materials (MPCMs) are attracting considerable attention for their application in thermal energy storage. Al–Si alloys are considered potential MPCMs; however, to develop storage systems/modules, it is crucial to fabricate corrosion-resistant materials for MPCMs. In this study,...

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Main Authors: Yamanaka Kenta, Mori Manami, Yoshida Kazuo, Tunthawiroon Phacharaphon, Chiba Akihiko
Format: Article
Language:English
Published: De Gruyter 2023-06-01
Series:High Temperature Materials and Processes
Subjects:
Online Access:https://doi.org/10.1515/htmp-2022-0278
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author Yamanaka Kenta
Mori Manami
Yoshida Kazuo
Tunthawiroon Phacharaphon
Chiba Akihiko
author_facet Yamanaka Kenta
Mori Manami
Yoshida Kazuo
Tunthawiroon Phacharaphon
Chiba Akihiko
author_sort Yamanaka Kenta
collection DOAJ
description Metallic phase change materials (MPCMs) are attracting considerable attention for their application in thermal energy storage. Al–Si alloys are considered potential MPCMs; however, to develop storage systems/modules, it is crucial to fabricate corrosion-resistant materials for MPCMs. In this study, the corrosion behavior of Co−28Cr−6Mo−1.5Si (wt%) alloy was examined via immersion tests in commercial Al−Si alloy (ADC12) melt at 700°C for 10 h. The results were compared to those obtained for pure Al. Substrate thickness loss measurements revealed that the liquid metal corrosion was more severe in the Al−Si melt than that in pure Al, suggesting an increased reactivity due to Si addition. Interfacial analysis elucidated a direct reaction between the alloy substrate and molten Al in both cases. Furthermore, the formation of oxides such as Al2O3 and SiO2 did not contribute to corrosion resistance.
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spelling doaj.art-cd6e295d62604edd83ecc50932a5d9932023-06-19T05:52:57ZengDe GruyterHigh Temperature Materials and Processes2191-03242023-06-01421pp. 35037710.1515/htmp-2022-0278Corrosion behavior of a Co−Cr−Mo−Si alloy in pure Al and Al−Si meltYamanaka Kenta0Mori Manami1Yoshida Kazuo2Tunthawiroon Phacharaphon3Chiba Akihiko4Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577, JapanInstitute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577, JapanInstitute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577, JapanDepartment of Industrial Engineering, School of Engineering, King Mongkut’s Institute of Technology Ladkrabang, Bangkok, 10520, ThailandInstitute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577, JapanMetallic phase change materials (MPCMs) are attracting considerable attention for their application in thermal energy storage. Al–Si alloys are considered potential MPCMs; however, to develop storage systems/modules, it is crucial to fabricate corrosion-resistant materials for MPCMs. In this study, the corrosion behavior of Co−28Cr−6Mo−1.5Si (wt%) alloy was examined via immersion tests in commercial Al−Si alloy (ADC12) melt at 700°C for 10 h. The results were compared to those obtained for pure Al. Substrate thickness loss measurements revealed that the liquid metal corrosion was more severe in the Al−Si melt than that in pure Al, suggesting an increased reactivity due to Si addition. Interfacial analysis elucidated a direct reaction between the alloy substrate and molten Al in both cases. Furthermore, the formation of oxides such as Al2O3 and SiO2 did not contribute to corrosion resistance.https://doi.org/10.1515/htmp-2022-0278phase change materialaluminumcorrosionco−cr−mo alloys
spellingShingle Yamanaka Kenta
Mori Manami
Yoshida Kazuo
Tunthawiroon Phacharaphon
Chiba Akihiko
Corrosion behavior of a Co−Cr−Mo−Si alloy in pure Al and Al−Si melt
High Temperature Materials and Processes
phase change material
aluminum
corrosion
co−cr−mo alloys
title Corrosion behavior of a Co−Cr−Mo−Si alloy in pure Al and Al−Si melt
title_full Corrosion behavior of a Co−Cr−Mo−Si alloy in pure Al and Al−Si melt
title_fullStr Corrosion behavior of a Co−Cr−Mo−Si alloy in pure Al and Al−Si melt
title_full_unstemmed Corrosion behavior of a Co−Cr−Mo−Si alloy in pure Al and Al−Si melt
title_short Corrosion behavior of a Co−Cr−Mo−Si alloy in pure Al and Al−Si melt
title_sort corrosion behavior of a co cr mo si alloy in pure al and al si melt
topic phase change material
aluminum
corrosion
co−cr−mo alloys
url https://doi.org/10.1515/htmp-2022-0278
work_keys_str_mv AT yamanakakenta corrosionbehaviorofacocrmosialloyinpurealandalsimelt
AT morimanami corrosionbehaviorofacocrmosialloyinpurealandalsimelt
AT yoshidakazuo corrosionbehaviorofacocrmosialloyinpurealandalsimelt
AT tunthawiroonphacharaphon corrosionbehaviorofacocrmosialloyinpurealandalsimelt
AT chibaakihiko corrosionbehaviorofacocrmosialloyinpurealandalsimelt