Corrosion behavior of a Co−Cr−Mo−Si alloy in pure Al and Al−Si melt
Metallic phase change materials (MPCMs) are attracting considerable attention for their application in thermal energy storage. Al–Si alloys are considered potential MPCMs; however, to develop storage systems/modules, it is crucial to fabricate corrosion-resistant materials for MPCMs. In this study,...
Main Authors: | , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
De Gruyter
2023-06-01
|
Series: | High Temperature Materials and Processes |
Subjects: | |
Online Access: | https://doi.org/10.1515/htmp-2022-0278 |
_version_ | 1797800867830693888 |
---|---|
author | Yamanaka Kenta Mori Manami Yoshida Kazuo Tunthawiroon Phacharaphon Chiba Akihiko |
author_facet | Yamanaka Kenta Mori Manami Yoshida Kazuo Tunthawiroon Phacharaphon Chiba Akihiko |
author_sort | Yamanaka Kenta |
collection | DOAJ |
description | Metallic phase change materials (MPCMs) are attracting considerable attention for their application in thermal energy storage. Al–Si alloys are considered potential MPCMs; however, to develop storage systems/modules, it is crucial to fabricate corrosion-resistant materials for MPCMs. In this study, the corrosion behavior of Co−28Cr−6Mo−1.5Si (wt%) alloy was examined via immersion tests in commercial Al−Si alloy (ADC12) melt at 700°C for 10 h. The results were compared to those obtained for pure Al. Substrate thickness loss measurements revealed that the liquid metal corrosion was more severe in the Al−Si melt than that in pure Al, suggesting an increased reactivity due to Si addition. Interfacial analysis elucidated a direct reaction between the alloy substrate and molten Al in both cases. Furthermore, the formation of oxides such as Al2O3 and SiO2 did not contribute to corrosion resistance. |
first_indexed | 2024-03-13T04:41:47Z |
format | Article |
id | doaj.art-cd6e295d62604edd83ecc50932a5d993 |
institution | Directory Open Access Journal |
issn | 2191-0324 |
language | English |
last_indexed | 2024-03-13T04:41:47Z |
publishDate | 2023-06-01 |
publisher | De Gruyter |
record_format | Article |
series | High Temperature Materials and Processes |
spelling | doaj.art-cd6e295d62604edd83ecc50932a5d9932023-06-19T05:52:57ZengDe GruyterHigh Temperature Materials and Processes2191-03242023-06-01421pp. 35037710.1515/htmp-2022-0278Corrosion behavior of a Co−Cr−Mo−Si alloy in pure Al and Al−Si meltYamanaka Kenta0Mori Manami1Yoshida Kazuo2Tunthawiroon Phacharaphon3Chiba Akihiko4Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577, JapanInstitute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577, JapanInstitute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577, JapanDepartment of Industrial Engineering, School of Engineering, King Mongkut’s Institute of Technology Ladkrabang, Bangkok, 10520, ThailandInstitute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577, JapanMetallic phase change materials (MPCMs) are attracting considerable attention for their application in thermal energy storage. Al–Si alloys are considered potential MPCMs; however, to develop storage systems/modules, it is crucial to fabricate corrosion-resistant materials for MPCMs. In this study, the corrosion behavior of Co−28Cr−6Mo−1.5Si (wt%) alloy was examined via immersion tests in commercial Al−Si alloy (ADC12) melt at 700°C for 10 h. The results were compared to those obtained for pure Al. Substrate thickness loss measurements revealed that the liquid metal corrosion was more severe in the Al−Si melt than that in pure Al, suggesting an increased reactivity due to Si addition. Interfacial analysis elucidated a direct reaction between the alloy substrate and molten Al in both cases. Furthermore, the formation of oxides such as Al2O3 and SiO2 did not contribute to corrosion resistance.https://doi.org/10.1515/htmp-2022-0278phase change materialaluminumcorrosionco−cr−mo alloys |
spellingShingle | Yamanaka Kenta Mori Manami Yoshida Kazuo Tunthawiroon Phacharaphon Chiba Akihiko Corrosion behavior of a Co−Cr−Mo−Si alloy in pure Al and Al−Si melt High Temperature Materials and Processes phase change material aluminum corrosion co−cr−mo alloys |
title | Corrosion behavior of a Co−Cr−Mo−Si alloy in pure Al and Al−Si melt |
title_full | Corrosion behavior of a Co−Cr−Mo−Si alloy in pure Al and Al−Si melt |
title_fullStr | Corrosion behavior of a Co−Cr−Mo−Si alloy in pure Al and Al−Si melt |
title_full_unstemmed | Corrosion behavior of a Co−Cr−Mo−Si alloy in pure Al and Al−Si melt |
title_short | Corrosion behavior of a Co−Cr−Mo−Si alloy in pure Al and Al−Si melt |
title_sort | corrosion behavior of a co cr mo si alloy in pure al and al si melt |
topic | phase change material aluminum corrosion co−cr−mo alloys |
url | https://doi.org/10.1515/htmp-2022-0278 |
work_keys_str_mv | AT yamanakakenta corrosionbehaviorofacocrmosialloyinpurealandalsimelt AT morimanami corrosionbehaviorofacocrmosialloyinpurealandalsimelt AT yoshidakazuo corrosionbehaviorofacocrmosialloyinpurealandalsimelt AT tunthawiroonphacharaphon corrosionbehaviorofacocrmosialloyinpurealandalsimelt AT chibaakihiko corrosionbehaviorofacocrmosialloyinpurealandalsimelt |