Calculation of CO2 P-ρ-T properties in the temperature range from T = 400 K to T = 1700 K

Сalculation of the carbon dioxide state equation isotherms in the temperature range from T = 400 K to T = 1700 K is presented. Implemented calculation method is a refinement of the previously proposed approach based on the fractal state equation and specially developed software Fract EOS. The calcul...

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Main Authors: R.A. Magomedov, E.N. Akhmedov
Format: Article
Language:Russian
Published: Tver State University 2023-12-01
Series:Физико-химические аспекты изучения кластеров, наноструктур и наноматериалов
Subjects:
Online Access:https://physchemaspects.ru/2023/doi-10-26456-pcascnn-2023-15-274/?lang=en
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author R.A. Magomedov
E.N. Akhmedov
author_facet R.A. Magomedov
E.N. Akhmedov
author_sort R.A. Magomedov
collection DOAJ
description Сalculation of the carbon dioxide state equation isotherms in the temperature range from T = 400 K to T = 1700 K is presented. Implemented calculation method is a refinement of the previously proposed approach based on the fractal state equation and specially developed software Fract EOS. The calculation results are in good agreement with the experimental data. It is shown, that the fitting parameter α of the fractal state equation for carbon dioxide does not depend on temperature. The density dependence can be accurately approximated using the polynomial. This fact simplifies the calculation of isotherms in a wide temperature range, and allowed to make the calculation for temperatures, that are not presented in the tabular reference data. The obtained results show that the proposed equation of state is suitable for studying not only simple substances like noble gases, but also for more complex substances, such as carbon dioxide.
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spelling doaj.art-cdc1a94df3ff412bb837e22225c377d52023-12-03T09:33:08ZrusTver State UniversityФизико-химические аспекты изучения кластеров, наноструктур и наноматериалов2226-44422658-43602023-12-011527428110.26456/pcascnn/2023.15.274Calculation of CO2 P-ρ-T properties in the temperature range from T = 400 K to T = 1700 KR.A. Magomedov0E.N. Akhmedov1Institute for Geothermal Researches and Renewable Energy, The Joint Institute for High Temperatures of the Russian Academy of Sciences, Makhachkala, RussiaInstitute for Geothermal Researches and Renewable Energy, The Joint Institute for High Temperatures of the Russian Academy of Sciences, Makhachkala, RussiaСalculation of the carbon dioxide state equation isotherms in the temperature range from T = 400 K to T = 1700 K is presented. Implemented calculation method is a refinement of the previously proposed approach based on the fractal state equation and specially developed software Fract EOS. The calculation results are in good agreement with the experimental data. It is shown, that the fitting parameter α of the fractal state equation for carbon dioxide does not depend on temperature. The density dependence can be accurately approximated using the polynomial. This fact simplifies the calculation of isotherms in a wide temperature range, and allowed to make the calculation for temperatures, that are not presented in the tabular reference data. The obtained results show that the proposed equation of state is suitable for studying not only simple substances like noble gases, but also for more complex substances, such as carbon dioxide.https://physchemaspects.ru/2023/doi-10-26456-pcascnn-2023-15-274/?lang=enequation of stateintegral-differentiation of fractional ordermaxwell relationshelmholtz potentialpartition functioncarbon dioxideisothermthermophysical properties
spellingShingle R.A. Magomedov
E.N. Akhmedov
Calculation of CO2 P-ρ-T properties in the temperature range from T = 400 K to T = 1700 K
Физико-химические аспекты изучения кластеров, наноструктур и наноматериалов
equation of state
integral-differentiation of fractional order
maxwell relations
helmholtz potential
partition function
carbon dioxide
isotherm
thermophysical properties
title Calculation of CO2 P-ρ-T properties in the temperature range from T = 400 K to T = 1700 K
title_full Calculation of CO2 P-ρ-T properties in the temperature range from T = 400 K to T = 1700 K
title_fullStr Calculation of CO2 P-ρ-T properties in the temperature range from T = 400 K to T = 1700 K
title_full_unstemmed Calculation of CO2 P-ρ-T properties in the temperature range from T = 400 K to T = 1700 K
title_short Calculation of CO2 P-ρ-T properties in the temperature range from T = 400 K to T = 1700 K
title_sort calculation of co2 p ρ t properties in the temperature range from t 400 k to t 1700 k
topic equation of state
integral-differentiation of fractional order
maxwell relations
helmholtz potential
partition function
carbon dioxide
isotherm
thermophysical properties
url https://physchemaspects.ru/2023/doi-10-26456-pcascnn-2023-15-274/?lang=en
work_keys_str_mv AT ramagomedov calculationofco2prtpropertiesinthetemperaturerangefromt400ktot1700k
AT enakhmedov calculationofco2prtpropertiesinthetemperaturerangefromt400ktot1700k