Diaquabis(2,5-di-4-pyridyl-1,3,4-thiadiazole-κN2)bis(thiocyanato-κN)copper(II) dihydrate
In the title compound, [Cu(NCS)2(C12H8N4S)2(H2O)2]·2H2O, the Cu atom is located on an inversion center and displays an octahedral geometry. Two N atoms of two different 2,5-di-4-pyridyl-1,3,4-thiadiazole ligands and two N atoms from two separate thiocyanate molecules form the equatorial pla...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008-05-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808008854 |
| _version_ | 1818958640554442752 |
|---|---|
| author | Ming-Hua Yang Wei-Wu Ma |
| author_facet | Ming-Hua Yang Wei-Wu Ma |
| author_sort | Ming-Hua Yang |
| collection | DOAJ |
| description | In the title compound, [Cu(NCS)2(C12H8N4S)2(H2O)2]·2H2O, the Cu atom is located on an inversion center and displays an octahedral geometry. Two N atoms of two different 2,5-di-4-pyridyl-1,3,4-thiadiazole ligands and two N atoms from two separate thiocyanate molecules form the equatorial plane, while two coordinated water molecules are in axial positions. The crystal structure is consolidated by extensive hydrogen bonding, forming a two-dimensional network. |
| first_indexed | 2024-12-20T11:28:58Z |
| format | Article |
| id | doaj.art-cde86a50b5fa4961ab21cd41c5147bbe |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T11:28:58Z |
| publishDate | 2008-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-cde86a50b5fa4961ab21cd41c5147bbe2022-12-21T19:42:18ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-05-01645m630m63010.1107/S1600536808008854Diaquabis(2,5-di-4-pyridyl-1,3,4-thiadiazole-κN2)bis(thiocyanato-κN)copper(II) dihydrateMing-Hua YangWei-Wu MaIn the title compound, [Cu(NCS)2(C12H8N4S)2(H2O)2]·2H2O, the Cu atom is located on an inversion center and displays an octahedral geometry. Two N atoms of two different 2,5-di-4-pyridyl-1,3,4-thiadiazole ligands and two N atoms from two separate thiocyanate molecules form the equatorial plane, while two coordinated water molecules are in axial positions. The crystal structure is consolidated by extensive hydrogen bonding, forming a two-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S1600536808008854 |
| spellingShingle | Ming-Hua Yang Wei-Wu Ma Diaquabis(2,5-di-4-pyridyl-1,3,4-thiadiazole-κN2)bis(thiocyanato-κN)copper(II) dihydrate Acta Crystallographica Section E |
| title | Diaquabis(2,5-di-4-pyridyl-1,3,4-thiadiazole-κN2)bis(thiocyanato-κN)copper(II) dihydrate |
| title_full | Diaquabis(2,5-di-4-pyridyl-1,3,4-thiadiazole-κN2)bis(thiocyanato-κN)copper(II) dihydrate |
| title_fullStr | Diaquabis(2,5-di-4-pyridyl-1,3,4-thiadiazole-κN2)bis(thiocyanato-κN)copper(II) dihydrate |
| title_full_unstemmed | Diaquabis(2,5-di-4-pyridyl-1,3,4-thiadiazole-κN2)bis(thiocyanato-κN)copper(II) dihydrate |
| title_short | Diaquabis(2,5-di-4-pyridyl-1,3,4-thiadiazole-κN2)bis(thiocyanato-κN)copper(II) dihydrate |
| title_sort | diaquabis 2 5 di 4 pyridyl 1 3 4 thiadiazole 954 n2 bis thiocyanato 954 n copper ii dihydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808008854 |
| work_keys_str_mv | AT minghuayang diaquabis25di4pyridyl134thiadiazole954n2bisthiocyanato954ncopperiidihydrate AT weiwuma diaquabis25di4pyridyl134thiadiazole954n2bisthiocyanato954ncopperiidihydrate |