ZIF-8 and polyaniline modified coconut gel to fabricate composite aerogel for efficient removal of tetracycline
To overcome the limitations of large-scale applications for MOFs in the powder form, herein, we proposed a strategy of in-situ growth ZIF-8 onto polyaniline (PANI) modified coconut hydrogel (CCH). Firstly, PANI played the role of metal chelated layers, which were coated on CCH by in-situ polymerizat...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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EDP Sciences
2020-01-01
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| Series: | E3S Web of Conferences |
| Online Access: | https://www.e3s-conferences.org/articles/e3sconf/pdf/2020/45/e3sconf_iceeb2020_04055.pdf |
| _version_ | 1818722009115262976 |
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| author | Liu Qun Zeng Fanming Li Xiao Su Zhongmin |
| author_facet | Liu Qun Zeng Fanming Li Xiao Su Zhongmin |
| author_sort | Liu Qun |
| collection | DOAJ |
| description | To overcome the limitations of large-scale applications for MOFs in the powder form, herein, we proposed a strategy of in-situ growth ZIF-8 onto polyaniline (PANI) modified coconut hydrogel (CCH). Firstly, PANI played the role of metal chelated layers, which were coated on CCH by in-situ polymerization. Then, ZIF-8 nanocrystals were in-situ growth on the surface of the PANI coated CCH to synthesise the composite adsorbent ZIF-8/PANI/CCH. Finally, after vacuum freeze-dried, a white and well structured ZIF-8/PANI/CCA(ZIF-8/polyaniline/coconut aerogel) was obtained. The loading mass ratios of ZIF-8 on CCA and PANI/CCA were 11.3% and 37.5%, respectively, which indicates that PANI as interface layers can effectively promote the in-situ growth of ZIF-8. The obtained composite adsorbent (ZIF-8/PANI/CCA) was applied for the adsorption of tetracycline (TC)，and the removal efficiency reaches over 91.6%. This strategy may provide an effective and versatile pathway to increase MOF loading mass on natural polysaccharide aerogel and sequentially branch out their applications in pollutant treatment fields. |
| first_indexed | 2024-12-17T20:47:48Z |
| format | Article |
| id | doaj.art-cdf2fecc804e4f64ba117e5d3076eceb |
| institution | Directory Open Access Journal |
| issn | 2267-1242 |
| language | English |
| last_indexed | 2024-12-17T20:47:48Z |
| publishDate | 2020-01-01 |
| publisher | EDP Sciences |
| record_format | Article |
| series | E3S Web of Conferences |
| spelling | doaj.art-cdf2fecc804e4f64ba117e5d3076eceb2022-12-21T21:33:07ZengEDP SciencesE3S Web of Conferences2267-12422020-01-011850405510.1051/e3sconf/202018504055e3sconf_iceeb2020_04055ZIF-8 and polyaniline modified coconut gel to fabricate composite aerogel for efficient removal of tetracyclineLiu QunZeng FanmingLi XiaoSu ZhongminTo overcome the limitations of large-scale applications for MOFs in the powder form, herein, we proposed a strategy of in-situ growth ZIF-8 onto polyaniline (PANI) modified coconut hydrogel (CCH). Firstly, PANI played the role of metal chelated layers, which were coated on CCH by in-situ polymerization. Then, ZIF-8 nanocrystals were in-situ growth on the surface of the PANI coated CCH to synthesise the composite adsorbent ZIF-8/PANI/CCH. Finally, after vacuum freeze-dried, a white and well structured ZIF-8/PANI/CCA(ZIF-8/polyaniline/coconut aerogel) was obtained. The loading mass ratios of ZIF-8 on CCA and PANI/CCA were 11.3% and 37.5%, respectively, which indicates that PANI as interface layers can effectively promote the in-situ growth of ZIF-8. The obtained composite adsorbent (ZIF-8/PANI/CCA) was applied for the adsorption of tetracycline (TC)，and the removal efficiency reaches over 91.6%. This strategy may provide an effective and versatile pathway to increase MOF loading mass on natural polysaccharide aerogel and sequentially branch out their applications in pollutant treatment fields.https://www.e3s-conferences.org/articles/e3sconf/pdf/2020/45/e3sconf_iceeb2020_04055.pdf |
| spellingShingle | Liu Qun Zeng Fanming Li Xiao Su Zhongmin ZIF-8 and polyaniline modified coconut gel to fabricate composite aerogel for efficient removal of tetracycline E3S Web of Conferences |
| title | ZIF-8 and polyaniline modified coconut gel to fabricate composite aerogel for efficient removal of tetracycline |
| title_full | ZIF-8 and polyaniline modified coconut gel to fabricate composite aerogel for efficient removal of tetracycline |
| title_fullStr | ZIF-8 and polyaniline modified coconut gel to fabricate composite aerogel for efficient removal of tetracycline |
| title_full_unstemmed | ZIF-8 and polyaniline modified coconut gel to fabricate composite aerogel for efficient removal of tetracycline |
| title_short | ZIF-8 and polyaniline modified coconut gel to fabricate composite aerogel for efficient removal of tetracycline |
| title_sort | zif 8 and polyaniline modified coconut gel to fabricate composite aerogel for efficient removal of tetracycline |
| url | https://www.e3s-conferences.org/articles/e3sconf/pdf/2020/45/e3sconf_iceeb2020_04055.pdf |
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