Preparation and properties of magnetic oxidized graphene 17β-estradiol molecularly imprinted composite membrane
The magnetic functionalized graphene based 17β-estradiol molecularly imprinted composite membrane (GO@Fe<sub>3</sub>O<sub>4</sub>-MIP) was successfully prepared by reversible addition fragmentation chain transfer (RAFT) polymerization technique using GO@Fe<sub>3</sub...
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Journal of Materials Engineering
2021-06-01
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Series: | Cailiao gongcheng |
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Online Access: | http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2019.001237 |
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author | LI Ying LEI Rui XU Wen-kai ZHU Xiao-xue HUANG Yan-feng |
author_facet | LI Ying LEI Rui XU Wen-kai ZHU Xiao-xue HUANG Yan-feng |
author_sort | LI Ying |
collection | DOAJ |
description | The magnetic functionalized graphene based 17β-estradiol molecularly imprinted composite membrane (GO@Fe<sub>3</sub>O<sub>4</sub>-MIP) was successfully prepared by reversible addition fragmentation chain transfer (RAFT) polymerization technique using GO@Fe<sub>3</sub>O<sub>4</sub> as carrier and 17β-estradiol as template molecule. High resolution transmission electron microscopy (HRTEM) and atomic force microscope(AFM), vibrating sample magnetometer(VSM) were employed to characterize the as-prepared samples. The results show that the calculated magnetic property of GO@Fe<sub>3</sub>O<sub>4</sub>-MIP is 12.89 A·m<sup>2</sup>·kg<sup>-1</sup> and the thickness is about 6.45 nm. The adsorption equilibrium time of GO@Fe<sub>3</sub>O<sub>4</sub>-MIP on 17β-estradiol is 30 min, the maximum adsorption capacity is 28.62 mg/g. These findings confirm that GO@Fe<sub>3</sub>O<sub>4</sub>-MIP has high adsorption efficiency and good adsorption selectivity for 17β-estradiol. |
first_indexed | 2024-04-11T03:05:30Z |
format | Article |
id | doaj.art-ce0084c315774251bce2e5ff74339500 |
institution | Directory Open Access Journal |
issn | 1001-4381 1001-4381 |
language | zho |
last_indexed | 2024-04-11T03:05:30Z |
publishDate | 2021-06-01 |
publisher | Journal of Materials Engineering |
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series | Cailiao gongcheng |
spelling | doaj.art-ce0084c315774251bce2e5ff743395002023-01-02T13:24:40ZzhoJournal of Materials EngineeringCailiao gongcheng1001-43811001-43812021-06-0149617017710.11868/j.issn.1001-4381.2019.00123720210620Preparation and properties of magnetic oxidized graphene 17β-estradiol molecularly imprinted composite membraneLI Ying0LEI Rui1XU Wen-kai2ZHU Xiao-xue3HUANG Yan-feng4School of Environmental Science and Engineering, Tiangong University, Tianjin 300387, ChinaSchool of Environmental Science and Engineering, Tiangong University, Tianjin 300387, ChinaSchool of Environmental Science and Engineering, Tiangong University, Tianjin 300387, ChinaSchool of Environmental Science and Engineering, Tiangong University, Tianjin 300387, ChinaSchool of Environmental Science and Engineering, Tiangong University, Tianjin 300387, ChinaThe magnetic functionalized graphene based 17β-estradiol molecularly imprinted composite membrane (GO@Fe<sub>3</sub>O<sub>4</sub>-MIP) was successfully prepared by reversible addition fragmentation chain transfer (RAFT) polymerization technique using GO@Fe<sub>3</sub>O<sub>4</sub> as carrier and 17β-estradiol as template molecule. High resolution transmission electron microscopy (HRTEM) and atomic force microscope(AFM), vibrating sample magnetometer(VSM) were employed to characterize the as-prepared samples. The results show that the calculated magnetic property of GO@Fe<sub>3</sub>O<sub>4</sub>-MIP is 12.89 A·m<sup>2</sup>·kg<sup>-1</sup> and the thickness is about 6.45 nm. The adsorption equilibrium time of GO@Fe<sub>3</sub>O<sub>4</sub>-MIP on 17β-estradiol is 30 min, the maximum adsorption capacity is 28.62 mg/g. These findings confirm that GO@Fe<sub>3</sub>O<sub>4</sub>-MIP has high adsorption efficiency and good adsorption selectivity for 17β-estradiol.http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2019.001237molecular imprinted polymerraft polymerizationgraphene oxidizedfe<sub>3</sub>o<sub>4</sub>17β-estradiol |
spellingShingle | LI Ying LEI Rui XU Wen-kai ZHU Xiao-xue HUANG Yan-feng Preparation and properties of magnetic oxidized graphene 17β-estradiol molecularly imprinted composite membrane Cailiao gongcheng molecular imprinted polymer raft polymerization graphene oxidized fe<sub>3</sub>o<sub>4</sub> 17β-estradiol |
title | Preparation and properties of magnetic oxidized graphene 17β-estradiol molecularly imprinted composite membrane |
title_full | Preparation and properties of magnetic oxidized graphene 17β-estradiol molecularly imprinted composite membrane |
title_fullStr | Preparation and properties of magnetic oxidized graphene 17β-estradiol molecularly imprinted composite membrane |
title_full_unstemmed | Preparation and properties of magnetic oxidized graphene 17β-estradiol molecularly imprinted composite membrane |
title_short | Preparation and properties of magnetic oxidized graphene 17β-estradiol molecularly imprinted composite membrane |
title_sort | preparation and properties of magnetic oxidized graphene 17β estradiol molecularly imprinted composite membrane |
topic | molecular imprinted polymer raft polymerization graphene oxidized fe<sub>3</sub>o<sub>4</sub> 17β-estradiol |
url | http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2019.001237 |
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