Preparation and properties of magnetic oxidized graphene 17β-estradiol molecularly imprinted composite membrane

The magnetic functionalized graphene based 17β-estradiol molecularly imprinted composite membrane (GO@Fe<sub>3</sub>O<sub>4</sub>-MIP) was successfully prepared by reversible addition fragmentation chain transfer (RAFT) polymerization technique using GO@Fe<sub>3</sub...

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Main Authors: LI Ying, LEI Rui, XU Wen-kai, ZHU Xiao-xue, HUANG Yan-feng
Format: Article
Language:zho
Published: Journal of Materials Engineering 2021-06-01
Series:Cailiao gongcheng
Subjects:
Online Access:http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2019.001237
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author LI Ying
LEI Rui
XU Wen-kai
ZHU Xiao-xue
HUANG Yan-feng
author_facet LI Ying
LEI Rui
XU Wen-kai
ZHU Xiao-xue
HUANG Yan-feng
author_sort LI Ying
collection DOAJ
description The magnetic functionalized graphene based 17β-estradiol molecularly imprinted composite membrane (GO@Fe<sub>3</sub>O<sub>4</sub>-MIP) was successfully prepared by reversible addition fragmentation chain transfer (RAFT) polymerization technique using GO@Fe<sub>3</sub>O<sub>4</sub> as carrier and 17β-estradiol as template molecule. High resolution transmission electron microscopy (HRTEM) and atomic force microscope(AFM), vibrating sample magnetometer(VSM) were employed to characterize the as-prepared samples. The results show that the calculated magnetic property of GO@Fe<sub>3</sub>O<sub>4</sub>-MIP is 12.89 A·m<sup>2</sup>·kg<sup>-1</sup> and the thickness is about 6.45 nm. The adsorption equilibrium time of GO@Fe<sub>3</sub>O<sub>4</sub>-MIP on 17β-estradiol is 30 min, the maximum adsorption capacity is 28.62 mg/g. These findings confirm that GO@Fe<sub>3</sub>O<sub>4</sub>-MIP has high adsorption efficiency and good adsorption selectivity for 17β-estradiol.
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spelling doaj.art-ce0084c315774251bce2e5ff743395002023-01-02T13:24:40ZzhoJournal of Materials EngineeringCailiao gongcheng1001-43811001-43812021-06-0149617017710.11868/j.issn.1001-4381.2019.00123720210620Preparation and properties of magnetic oxidized graphene 17β-estradiol molecularly imprinted composite membraneLI Ying0LEI Rui1XU Wen-kai2ZHU Xiao-xue3HUANG Yan-feng4School of Environmental Science and Engineering, Tiangong University, Tianjin 300387, ChinaSchool of Environmental Science and Engineering, Tiangong University, Tianjin 300387, ChinaSchool of Environmental Science and Engineering, Tiangong University, Tianjin 300387, ChinaSchool of Environmental Science and Engineering, Tiangong University, Tianjin 300387, ChinaSchool of Environmental Science and Engineering, Tiangong University, Tianjin 300387, ChinaThe magnetic functionalized graphene based 17β-estradiol molecularly imprinted composite membrane (GO@Fe<sub>3</sub>O<sub>4</sub>-MIP) was successfully prepared by reversible addition fragmentation chain transfer (RAFT) polymerization technique using GO@Fe<sub>3</sub>O<sub>4</sub> as carrier and 17β-estradiol as template molecule. High resolution transmission electron microscopy (HRTEM) and atomic force microscope(AFM), vibrating sample magnetometer(VSM) were employed to characterize the as-prepared samples. The results show that the calculated magnetic property of GO@Fe<sub>3</sub>O<sub>4</sub>-MIP is 12.89 A·m<sup>2</sup>·kg<sup>-1</sup> and the thickness is about 6.45 nm. The adsorption equilibrium time of GO@Fe<sub>3</sub>O<sub>4</sub>-MIP on 17β-estradiol is 30 min, the maximum adsorption capacity is 28.62 mg/g. These findings confirm that GO@Fe<sub>3</sub>O<sub>4</sub>-MIP has high adsorption efficiency and good adsorption selectivity for 17β-estradiol.http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2019.001237molecular imprinted polymerraft polymerizationgraphene oxidizedfe<sub>3</sub>o<sub>4</sub>17β-estradiol
spellingShingle LI Ying
LEI Rui
XU Wen-kai
ZHU Xiao-xue
HUANG Yan-feng
Preparation and properties of magnetic oxidized graphene 17β-estradiol molecularly imprinted composite membrane
Cailiao gongcheng
molecular imprinted polymer
raft polymerization
graphene oxidized
fe<sub>3</sub>o<sub>4</sub>
17β-estradiol
title Preparation and properties of magnetic oxidized graphene 17β-estradiol molecularly imprinted composite membrane
title_full Preparation and properties of magnetic oxidized graphene 17β-estradiol molecularly imprinted composite membrane
title_fullStr Preparation and properties of magnetic oxidized graphene 17β-estradiol molecularly imprinted composite membrane
title_full_unstemmed Preparation and properties of magnetic oxidized graphene 17β-estradiol molecularly imprinted composite membrane
title_short Preparation and properties of magnetic oxidized graphene 17β-estradiol molecularly imprinted composite membrane
title_sort preparation and properties of magnetic oxidized graphene 17β estradiol molecularly imprinted composite membrane
topic molecular imprinted polymer
raft polymerization
graphene oxidized
fe<sub>3</sub>o<sub>4</sub>
17β-estradiol
url http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2019.001237
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AT xuwenkai preparationandpropertiesofmagneticoxidizedgraphene17bestradiolmolecularlyimprintedcompositemembrane
AT zhuxiaoxue preparationandpropertiesofmagneticoxidizedgraphene17bestradiolmolecularlyimprintedcompositemembrane
AT huangyanfeng preparationandpropertiesofmagneticoxidizedgraphene17bestradiolmolecularlyimprintedcompositemembrane