Detection of most commonly used pesticides in green leafy vegetables from sagar, india using direct injection hybrid micellar liquid chromatography
Imidacloprid, chlorpyrifos, profenofos and cypermethrin are most commonly applied pesticides on green leafy vegetables. After a survey conducted to know the pesticide management practices in Sagar, India, a procedure based on hybrid micellar liquid chromatography coupled to a photodiode array detect...
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| Format: | Article |
| Language: | English |
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Elsevier
2022-03-01
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| Series: | Advances in Sample Preparation |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S2772582022000122 |
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| author | Hemlata Bhamdare Priyanka Pahade Devasish Bose Abhilasha Durgbanshi Samuel Carda-Broch Juan Peris-Vicente |
| author_facet | Hemlata Bhamdare Priyanka Pahade Devasish Bose Abhilasha Durgbanshi Samuel Carda-Broch Juan Peris-Vicente |
| author_sort | Hemlata Bhamdare |
| collection | DOAJ |
| description | Imidacloprid, chlorpyrifos, profenofos and cypermethrin are most commonly applied pesticides on green leafy vegetables. After a survey conducted to know the pesticide management practices in Sagar, India, a procedure based on hybrid micellar liquid chromatography coupled to a photodiode array detector has been developed and validated to monitor imidacloprid, chlorpyrifos, profenofos and cypermethrin content in green leafy vegetables. The method was validated following the guideline of SANTE/11,312/2021 in terms of: selectivity, linearity (r2> 0.998), limit of quantification (0.09–0.25 mg/Kg, depending on the analyte under investigation), precision (<8.1%), and robustness (<5%). Chlorpyrifos was found to be the most commonly used pesticide among vegetable growers. It was found in seventy-six percent samples, profenofos in fifty-one percent, imidacloprid in eight percent and cypermethrin in four percent of the analyzed green leafy vegetable sample either individually or in combination. Sixteen percent of the collected samples were found to be negative for the selected pesticides. The developed procedure is rapid, easy to handle, green since it uses a low amount of toxic chemicals providing reliable results. The method was used to evaluate the eventual correlation between the analytical data and the information collected from the producers and users of these pesticides. |
| first_indexed | 2024-12-12T22:18:30Z |
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| institution | Directory Open Access Journal |
| issn | 2772-5820 |
| language | English |
| last_indexed | 2024-12-12T22:18:30Z |
| publishDate | 2022-03-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Advances in Sample Preparation |
| spelling | doaj.art-ce1004865873483d9349daf22fa944182022-12-22T00:10:01ZengElsevierAdvances in Sample Preparation2772-58202022-03-012100015Detection of most commonly used pesticides in green leafy vegetables from sagar, india using direct injection hybrid micellar liquid chromatographyHemlata Bhamdare0Priyanka Pahade1Devasish Bose2Abhilasha Durgbanshi3Samuel Carda-Broch4Juan Peris-Vicente5Department of Criminology and Forensic Science, Doctor Harisingh Gour Vishwavidyalaya (A Central University), Sagar, Madhya Pradesh 470003, IndiaDepartment of Criminology and Forensic Science, Doctor Harisingh Gour Vishwavidyalaya (A Central University), Sagar, Madhya Pradesh 470003, IndiaDepartment of Criminology and Forensic Science, Doctor Harisingh Gour Vishwavidyalaya (A Central University), Sagar, Madhya Pradesh 470003, India; Corresponding author.Department of Chemistry, Doctor Harisingh Gour Vishwavidyalaya (A Central University), Sagar, Madhya Pradesh 470003, IndiaBioanalytical Chemistry, Department of Physical and Analytical Chemistry, ESTCE, Universitat Jaume I, Castello, 12071 SpainDepartment of Analytical Chemistry, Faculty of Chemistry, Universitat de València, Burjassot-Valencia 46100, SpainImidacloprid, chlorpyrifos, profenofos and cypermethrin are most commonly applied pesticides on green leafy vegetables. After a survey conducted to know the pesticide management practices in Sagar, India, a procedure based on hybrid micellar liquid chromatography coupled to a photodiode array detector has been developed and validated to monitor imidacloprid, chlorpyrifos, profenofos and cypermethrin content in green leafy vegetables. The method was validated following the guideline of SANTE/11,312/2021 in terms of: selectivity, linearity (r2> 0.998), limit of quantification (0.09–0.25 mg/Kg, depending on the analyte under investigation), precision (<8.1%), and robustness (<5%). Chlorpyrifos was found to be the most commonly used pesticide among vegetable growers. It was found in seventy-six percent samples, profenofos in fifty-one percent, imidacloprid in eight percent and cypermethrin in four percent of the analyzed green leafy vegetable sample either individually or in combination. Sixteen percent of the collected samples were found to be negative for the selected pesticides. The developed procedure is rapid, easy to handle, green since it uses a low amount of toxic chemicals providing reliable results. The method was used to evaluate the eventual correlation between the analytical data and the information collected from the producers and users of these pesticides.http://www.sciencedirect.com/science/article/pii/S2772582022000122ChlorpyrifosCypermethrinGreen leafy vegetablesImidaclopridProfenofos |
| spellingShingle | Hemlata Bhamdare Priyanka Pahade Devasish Bose Abhilasha Durgbanshi Samuel Carda-Broch Juan Peris-Vicente Detection of most commonly used pesticides in green leafy vegetables from sagar, india using direct injection hybrid micellar liquid chromatography Advances in Sample Preparation Chlorpyrifos Cypermethrin Green leafy vegetables Imidacloprid Profenofos |
| title | Detection of most commonly used pesticides in green leafy vegetables from sagar, india using direct injection hybrid micellar liquid chromatography |
| title_full | Detection of most commonly used pesticides in green leafy vegetables from sagar, india using direct injection hybrid micellar liquid chromatography |
| title_fullStr | Detection of most commonly used pesticides in green leafy vegetables from sagar, india using direct injection hybrid micellar liquid chromatography |
| title_full_unstemmed | Detection of most commonly used pesticides in green leafy vegetables from sagar, india using direct injection hybrid micellar liquid chromatography |
| title_short | Detection of most commonly used pesticides in green leafy vegetables from sagar, india using direct injection hybrid micellar liquid chromatography |
| title_sort | detection of most commonly used pesticides in green leafy vegetables from sagar india using direct injection hybrid micellar liquid chromatography |
| topic | Chlorpyrifos Cypermethrin Green leafy vegetables Imidacloprid Profenofos |
| url | http://www.sciencedirect.com/science/article/pii/S2772582022000122 |
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