Heterobimetallic palladium-based carboxylates as a new way to mixed- metal nanomaterials
New synthetic approach to the preparation of palladium(II)-based heterobimetallic complexes was proposed. The complexes were prepared in high yields (85-95%) in single-crystalline form and structurally characterized by physicochemical methods, including X-ray structural analysis. All the complexes a...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | Russian |
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MIREA - Russian Technological University
2007-06-01
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| Series: | Тонкие химические технологии |
| Online Access: | https://www.finechem-mirea.ru/jour/article/view/1312 |
| Summary: | New synthetic approach to the preparation of palladium(II)-based heterobimetallic complexes was proposed. The complexes were prepared in high yields (85-95%) in single-crystalline form and structurally characterized by physicochemical methods, including X-ray structural analysis. All the complexes are built based on the structural motif [Pd(-OOCR)4M] (R = Me, tBu; M = Cu(II), Zn(II), Ni(II), Co(II), Mn(II), Ce(IV), Nd(III), Sm(III), Eu(III), Tm(III), Yb(III)). Reduction of the heterobimetallic complexes can produce new mixed-metal nanomaterials |
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| ISSN: | 2410-6593 2686-7575 |