Electrochemical corrosion behavior of atmospheric-plasma-sprayed copper as a coating material for deep geological disposal canisters

Cu, which exhibits excellent corrosion resistance in underground environments, has been investigated as a canister material for use in the deep geological disposal of spent nuclear fuels. In this study, the technical viability of atmospheric plasma spraying for producing Cu-coated canisters was inve...

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Main Authors: Sung-Wook Kim, Gha-Young Kim, Young-Ho Lee, Jun-Hyuk Jang, Chung-Won Lee, Jeong-Hyun Woo, Seok Yoon
Format: Article
Language:English
Published: Elsevier 2023-11-01
Series:Nuclear Engineering and Technology
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S1738573323003339
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author Sung-Wook Kim
Gha-Young Kim
Young-Ho Lee
Jun-Hyuk Jang
Chung-Won Lee
Jeong-Hyun Woo
Seok Yoon
author_facet Sung-Wook Kim
Gha-Young Kim
Young-Ho Lee
Jun-Hyuk Jang
Chung-Won Lee
Jeong-Hyun Woo
Seok Yoon
author_sort Sung-Wook Kim
collection DOAJ
description Cu, which exhibits excellent corrosion resistance in underground environments, has been investigated as a canister material for use in the deep geological disposal of spent nuclear fuels. In this study, the technical viability of atmospheric plasma spraying for producing Cu-coated canisters was investigated. A high-purity Cu film (millimeter scale) was deposited onto a stainless-steel substrate using a plasma gun with a shroud structure. Potentiodynamic polarization studies revealed that the Cu film exhibited a sufficiently low corrosion rate in the groundwater electrolyte. In addition, no pitting corrosion was observed on the Cu film surface after accelerated corrosion studies. A prototype cylindrical Cu film was fabricated on a 1/20 scale on a stainless-steel tube to demonstrate the scalability of atmospheric plasma spraying in producing Cu-coated canisters.
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spelling doaj.art-ce2248d4d661423699bf592525a393bd2023-10-22T04:48:28ZengElsevierNuclear Engineering and Technology1738-57332023-11-01551140324038Electrochemical corrosion behavior of atmospheric-plasma-sprayed copper as a coating material for deep geological disposal canistersSung-Wook Kim0Gha-Young Kim1Young-Ho Lee2Jun-Hyuk Jang3Chung-Won Lee4Jeong-Hyun Woo5Seok Yoon6Corresponding author.; Korea Atomic Energy Research Institute, 989-111 Daedeok-daero, Yuseong-gu, Daejeon, 34057, Republic of KoreaKorea Atomic Energy Research Institute, 989-111 Daedeok-daero, Yuseong-gu, Daejeon, 34057, Republic of KoreaKorea Atomic Energy Research Institute, 989-111 Daedeok-daero, Yuseong-gu, Daejeon, 34057, Republic of KoreaKorea Atomic Energy Research Institute, 989-111 Daedeok-daero, Yuseong-gu, Daejeon, 34057, Republic of KoreaKorea Atomic Energy Research Institute, 989-111 Daedeok-daero, Yuseong-gu, Daejeon, 34057, Republic of KoreaKorea Atomic Energy Research Institute, 989-111 Daedeok-daero, Yuseong-gu, Daejeon, 34057, Republic of KoreaKorea Atomic Energy Research Institute, 989-111 Daedeok-daero, Yuseong-gu, Daejeon, 34057, Republic of KoreaCu, which exhibits excellent corrosion resistance in underground environments, has been investigated as a canister material for use in the deep geological disposal of spent nuclear fuels. In this study, the technical viability of atmospheric plasma spraying for producing Cu-coated canisters was investigated. A high-purity Cu film (millimeter scale) was deposited onto a stainless-steel substrate using a plasma gun with a shroud structure. Potentiodynamic polarization studies revealed that the Cu film exhibited a sufficiently low corrosion rate in the groundwater electrolyte. In addition, no pitting corrosion was observed on the Cu film surface after accelerated corrosion studies. A prototype cylindrical Cu film was fabricated on a 1/20 scale on a stainless-steel tube to demonstrate the scalability of atmospheric plasma spraying in producing Cu-coated canisters.http://www.sciencedirect.com/science/article/pii/S1738573323003339Deep geological disposalCanisterCopperAdditive manufacturingAtmospheric plasma sprayingElectrochemistry
spellingShingle Sung-Wook Kim
Gha-Young Kim
Young-Ho Lee
Jun-Hyuk Jang
Chung-Won Lee
Jeong-Hyun Woo
Seok Yoon
Electrochemical corrosion behavior of atmospheric-plasma-sprayed copper as a coating material for deep geological disposal canisters
Nuclear Engineering and Technology
Deep geological disposal
Canister
Copper
Additive manufacturing
Atmospheric plasma spraying
Electrochemistry
title Electrochemical corrosion behavior of atmospheric-plasma-sprayed copper as a coating material for deep geological disposal canisters
title_full Electrochemical corrosion behavior of atmospheric-plasma-sprayed copper as a coating material for deep geological disposal canisters
title_fullStr Electrochemical corrosion behavior of atmospheric-plasma-sprayed copper as a coating material for deep geological disposal canisters
title_full_unstemmed Electrochemical corrosion behavior of atmospheric-plasma-sprayed copper as a coating material for deep geological disposal canisters
title_short Electrochemical corrosion behavior of atmospheric-plasma-sprayed copper as a coating material for deep geological disposal canisters
title_sort electrochemical corrosion behavior of atmospheric plasma sprayed copper as a coating material for deep geological disposal canisters
topic Deep geological disposal
Canister
Copper
Additive manufacturing
Atmospheric plasma spraying
Electrochemistry
url http://www.sciencedirect.com/science/article/pii/S1738573323003339
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