Templated Synthesis of Diamond Nanopillar Arrays Using Porous Anodic Aluminium Oxide (AAO) Membranes

Diamond nanostructures are mostly produced from bulk diamond (single- or polycrystalline) by using time-consuming and/or costly subtractive manufacturing methods. In this study, we report the bottom-up synthesis of ordered diamond nanopillar arrays by using porous anodic aluminium oxide (AAO). Comme...

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Main Authors: Chenghao Zhang, Zhichao Liu, Chun Li, Jian Cao, Josephus G. Buijnsters
Format: Article
Language:English
Published: MDPI AG 2023-02-01
Series:Nanomaterials
Subjects:
Online Access:https://www.mdpi.com/2079-4991/13/5/888
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author Chenghao Zhang
Zhichao Liu
Chun Li
Jian Cao
Josephus G. Buijnsters
author_facet Chenghao Zhang
Zhichao Liu
Chun Li
Jian Cao
Josephus G. Buijnsters
author_sort Chenghao Zhang
collection DOAJ
description Diamond nanostructures are mostly produced from bulk diamond (single- or polycrystalline) by using time-consuming and/or costly subtractive manufacturing methods. In this study, we report the bottom-up synthesis of ordered diamond nanopillar arrays by using porous anodic aluminium oxide (AAO). Commercial ultrathin AAO membranes were adopted as the growth template in a straightforward, three-step fabrication process involving chemical vapor deposition (CVD) and the transfer and removal of the alumina foils. Two types of AAO membranes with distinct nominal pore size were employed and transferred onto the nucleation side of CVD diamond sheets. Subsequently, diamond nanopillars were grown directly on these sheets. After removal of the AAO template by chemical etching, ordered arrays of submicron and nanoscale diamond pillars with ~325 nm and ~85 nm diameters were successfully released.
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spelling doaj.art-ce6b9ab1fadb4354973af014e400f8d42023-11-17T08:17:54ZengMDPI AGNanomaterials2079-49912023-02-0113588810.3390/nano13050888Templated Synthesis of Diamond Nanopillar Arrays Using Porous Anodic Aluminium Oxide (AAO) MembranesChenghao Zhang0Zhichao Liu1Chun Li2Jian Cao3Josephus G. Buijnsters4State Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin 150001, ChinaDepartment of Precision and Microsystems Engineering, Faculty of Mechanical, Maritime and Materials Engineering, Delft University of Technology, Mekelweg 2, 2628 CD Delft, The NetherlandsState Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin 150001, ChinaState Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin 150001, ChinaDepartment of Precision and Microsystems Engineering, Faculty of Mechanical, Maritime and Materials Engineering, Delft University of Technology, Mekelweg 2, 2628 CD Delft, The NetherlandsDiamond nanostructures are mostly produced from bulk diamond (single- or polycrystalline) by using time-consuming and/or costly subtractive manufacturing methods. In this study, we report the bottom-up synthesis of ordered diamond nanopillar arrays by using porous anodic aluminium oxide (AAO). Commercial ultrathin AAO membranes were adopted as the growth template in a straightforward, three-step fabrication process involving chemical vapor deposition (CVD) and the transfer and removal of the alumina foils. Two types of AAO membranes with distinct nominal pore size were employed and transferred onto the nucleation side of CVD diamond sheets. Subsequently, diamond nanopillars were grown directly on these sheets. After removal of the AAO template by chemical etching, ordered arrays of submicron and nanoscale diamond pillars with ~325 nm and ~85 nm diameters were successfully released.https://www.mdpi.com/2079-4991/13/5/888template-assisted growthdiamond nanopillarsanodic aluminium oxide (AAO)chemical vapor deposition (CVD)stress modeling
spellingShingle Chenghao Zhang
Zhichao Liu
Chun Li
Jian Cao
Josephus G. Buijnsters
Templated Synthesis of Diamond Nanopillar Arrays Using Porous Anodic Aluminium Oxide (AAO) Membranes
Nanomaterials
template-assisted growth
diamond nanopillars
anodic aluminium oxide (AAO)
chemical vapor deposition (CVD)
stress modeling
title Templated Synthesis of Diamond Nanopillar Arrays Using Porous Anodic Aluminium Oxide (AAO) Membranes
title_full Templated Synthesis of Diamond Nanopillar Arrays Using Porous Anodic Aluminium Oxide (AAO) Membranes
title_fullStr Templated Synthesis of Diamond Nanopillar Arrays Using Porous Anodic Aluminium Oxide (AAO) Membranes
title_full_unstemmed Templated Synthesis of Diamond Nanopillar Arrays Using Porous Anodic Aluminium Oxide (AAO) Membranes
title_short Templated Synthesis of Diamond Nanopillar Arrays Using Porous Anodic Aluminium Oxide (AAO) Membranes
title_sort templated synthesis of diamond nanopillar arrays using porous anodic aluminium oxide aao membranes
topic template-assisted growth
diamond nanopillars
anodic aluminium oxide (AAO)
chemical vapor deposition (CVD)
stress modeling
url https://www.mdpi.com/2079-4991/13/5/888
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