Adsorptive Capacity, Inhibitory Activity and Processing Techniques for a Copper-MOF Based on the 3,4-Dihydroxybenzoate Ligand
Due to the fast, emerging development of antibiotic-resistant bacteria, the need for novel, efficient routes to battle these pathogens is crucial; in this scenario, metal-organic frameworks (MOFs) are promising materials for combating them effectively. Herein, a novel Cu-MOF—namely <b>1</b&...
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MDPI AG
2022-11-01
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author | Estitxu Echenique-Errandonea Sara Rojas Víctor Karim Abdelkader-Fernández Manuel Pérez-Mendoza Ricardo F. Mendes Paula Barbosa Filipe Figueiredo Flávio Figueira Filipe A. Almeida Paz José Manuel Delgado-López Antonio Rodríguez-Diéguez José Manuel Seco |
author_facet | Estitxu Echenique-Errandonea Sara Rojas Víctor Karim Abdelkader-Fernández Manuel Pérez-Mendoza Ricardo F. Mendes Paula Barbosa Filipe Figueiredo Flávio Figueira Filipe A. Almeida Paz José Manuel Delgado-López Antonio Rodríguez-Diéguez José Manuel Seco |
author_sort | Estitxu Echenique-Errandonea |
collection | DOAJ |
description | Due to the fast, emerging development of antibiotic-resistant bacteria, the need for novel, efficient routes to battle these pathogens is crucial; in this scenario, metal-organic frameworks (MOFs) are promising materials for combating them effectively. Herein, a novel Cu-MOF—namely <b>1</b>—that displays the formula [Cu<sub>3</sub>L<sub>2</sub>(DMF)<sub>2</sub>]<sub>n</sub> (DMF = <i>N</i>,<i>N</i>-dimethylformamide) is described, synthesized by the combination of copper(II) and 3,4-dihydroxybenzoic acid (H<sub>3</sub>L)—both having well-known antibacterial properties. The resulting three-dimensional structure motivated us to study the antibacterial activity, adsorptive capacity and processability of the MOF in the form of pellets and membranes as a proof-of-concept to evaluate its future application in devices. |
first_indexed | 2024-03-09T18:07:22Z |
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institution | Directory Open Access Journal |
issn | 1420-3049 |
language | English |
last_indexed | 2024-03-09T18:07:22Z |
publishDate | 2022-11-01 |
publisher | MDPI AG |
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series | Molecules |
spelling | doaj.art-ce6c47d8dd6848fea6de41ee6af246362023-11-24T09:26:02ZengMDPI AGMolecules1420-30492022-11-012722807310.3390/molecules27228073Adsorptive Capacity, Inhibitory Activity and Processing Techniques for a Copper-MOF Based on the 3,4-Dihydroxybenzoate LigandEstitxu Echenique-Errandonea0Sara Rojas1Víctor Karim Abdelkader-Fernández2Manuel Pérez-Mendoza3Ricardo F. Mendes4Paula Barbosa5Filipe Figueiredo6Flávio Figueira7Filipe A. Almeida Paz8José Manuel Delgado-López9Antonio Rodríguez-Diéguez10José Manuel Seco11Departamento de Química Aplicada, Facultad de Química, Universidad del País Vasco UPV/EHU, Paseo Manuel Lardizabal, N° 3, 20018 Donostia-San Sebastián, SpainDepartamento de Química Inorgánica, Facultad de Ciencias, Universidad de Granada, Av. Fuentenueva S/N, 18071 Granada, SpainDepartamento de Química Inorgánica, Facultad de Ciencias, Universidad de Granada, Av. Fuentenueva S/N, 18071 Granada, SpainDepartamento de Química Inorgánica, Facultad de Ciencias, Universidad de Granada, Av. Fuentenueva S/N, 18071 Granada, SpainDepartment of Chemistry, CICECO—Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, PortugalDepartment of Materials & Ceramic Engineering, CICECO—Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, PortugalDepartment of Materials & Ceramic Engineering, CICECO—Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, PortugalDepartment of Chemistry, CICECO—Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, PortugalDepartment of Chemistry, CICECO—Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, PortugalDepartamento de Química Inorgánica, Facultad de Ciencias, Universidad de Granada, Av. Fuentenueva S/N, 18071 Granada, SpainDepartamento de Química Inorgánica, Facultad de Ciencias, Universidad de Granada, Av. Fuentenueva S/N, 18071 Granada, SpainDepartamento de Química Aplicada, Facultad de Química, Universidad del País Vasco UPV/EHU, Paseo Manuel Lardizabal, N° 3, 20018 Donostia-San Sebastián, SpainDue to the fast, emerging development of antibiotic-resistant bacteria, the need for novel, efficient routes to battle these pathogens is crucial; in this scenario, metal-organic frameworks (MOFs) are promising materials for combating them effectively. Herein, a novel Cu-MOF—namely <b>1</b>—that displays the formula [Cu<sub>3</sub>L<sub>2</sub>(DMF)<sub>2</sub>]<sub>n</sub> (DMF = <i>N</i>,<i>N</i>-dimethylformamide) is described, synthesized by the combination of copper(II) and 3,4-dihydroxybenzoic acid (H<sub>3</sub>L)—both having well-known antibacterial properties. The resulting three-dimensional structure motivated us to study the antibacterial activity, adsorptive capacity and processability of the MOF in the form of pellets and membranes as a proof-of-concept to evaluate its future application in devices.https://www.mdpi.com/1420-3049/27/22/8073metal-organic frameworksmaterial processingadsorption capacityantibacterial activity |
spellingShingle | Estitxu Echenique-Errandonea Sara Rojas Víctor Karim Abdelkader-Fernández Manuel Pérez-Mendoza Ricardo F. Mendes Paula Barbosa Filipe Figueiredo Flávio Figueira Filipe A. Almeida Paz José Manuel Delgado-López Antonio Rodríguez-Diéguez José Manuel Seco Adsorptive Capacity, Inhibitory Activity and Processing Techniques for a Copper-MOF Based on the 3,4-Dihydroxybenzoate Ligand Molecules metal-organic frameworks material processing adsorption capacity antibacterial activity |
title | Adsorptive Capacity, Inhibitory Activity and Processing Techniques for a Copper-MOF Based on the 3,4-Dihydroxybenzoate Ligand |
title_full | Adsorptive Capacity, Inhibitory Activity and Processing Techniques for a Copper-MOF Based on the 3,4-Dihydroxybenzoate Ligand |
title_fullStr | Adsorptive Capacity, Inhibitory Activity and Processing Techniques for a Copper-MOF Based on the 3,4-Dihydroxybenzoate Ligand |
title_full_unstemmed | Adsorptive Capacity, Inhibitory Activity and Processing Techniques for a Copper-MOF Based on the 3,4-Dihydroxybenzoate Ligand |
title_short | Adsorptive Capacity, Inhibitory Activity and Processing Techniques for a Copper-MOF Based on the 3,4-Dihydroxybenzoate Ligand |
title_sort | adsorptive capacity inhibitory activity and processing techniques for a copper mof based on the 3 4 dihydroxybenzoate ligand |
topic | metal-organic frameworks material processing adsorption capacity antibacterial activity |
url | https://www.mdpi.com/1420-3049/27/22/8073 |
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