QUANTITATIVE SPECIATION OF THE LIQUID PHASE BY FTIR SPECTROSCOPY IN THE SYSTEM AMP-PZ-CO2-H2O
This work reports a multivariate calibration partial least square regression (PLS) model to quantify the liquid-phase concentrations of 2-amino-2-methyl-1-propanol (AMP), piperazine (PZ), bicarbonate, PZ monocarbamate, and PZ dicarbamate during the absorption/desorption process by Fourier Transform...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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Sociedade Brasileira de Química
2022-08-01
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| Series: | Química Nova |
| Subjects: | |
| Online Access: | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422022000600674&tlng=en |
| _version_ | 1798036194179678208 |
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| author | Armando Zanone Denise T. Tavares José L. de Paiva |
| author_facet | Armando Zanone Denise T. Tavares José L. de Paiva |
| author_sort | Armando Zanone |
| collection | DOAJ |
| description | This work reports a multivariate calibration partial least square regression (PLS) model to quantify the liquid-phase concentrations of 2-amino-2-methyl-1-propanol (AMP), piperazine (PZ), bicarbonate, PZ monocarbamate, and PZ dicarbamate during the absorption/desorption process by Fourier Transform Mid-Infrared spectroscopy (mid-FTIR). The model could predict 33 different concentrations ranging from 0 to 40 wt.% AMP, 0 to 15 wt.% PZ, and 0 to 12 wt.% total CO2 with relative errors lower than 10%, and 87% of the variance of all samples have been represented (R2), except for PZ dicarbamate. A comparison of a single PLS2 model was made with multiple PLS1 models, one for each chemical species present in the liquid phase. The latter had better predictions and made it possible to differentiate CO2 from its chemical forms, allowing a better understanding of the CO2 capture processes. |
| first_indexed | 2024-04-11T21:09:07Z |
| format | Article |
| id | doaj.art-ce7051513a444851bbaf74d2e1dbd729 |
| institution | Directory Open Access Journal |
| issn | 1678-7064 |
| language | English |
| last_indexed | 2024-04-11T21:09:07Z |
| publishDate | 2022-08-01 |
| publisher | Sociedade Brasileira de Química |
| record_format | Article |
| series | Química Nova |
| spelling | doaj.art-ce7051513a444851bbaf74d2e1dbd7292022-12-22T04:03:05ZengSociedade Brasileira de QuímicaQuímica Nova1678-70642022-08-0145667467910.21577/0100-4042.20170883QUANTITATIVE SPECIATION OF THE LIQUID PHASE BY FTIR SPECTROSCOPY IN THE SYSTEM AMP-PZ-CO2-H2OArmando Zanonehttps://orcid.org/0000-0003-3082-5233Denise T. TavaresJosé L. de PaivaThis work reports a multivariate calibration partial least square regression (PLS) model to quantify the liquid-phase concentrations of 2-amino-2-methyl-1-propanol (AMP), piperazine (PZ), bicarbonate, PZ monocarbamate, and PZ dicarbamate during the absorption/desorption process by Fourier Transform Mid-Infrared spectroscopy (mid-FTIR). The model could predict 33 different concentrations ranging from 0 to 40 wt.% AMP, 0 to 15 wt.% PZ, and 0 to 12 wt.% total CO2 with relative errors lower than 10%, and 87% of the variance of all samples have been represented (R2), except for PZ dicarbamate. A comparison of a single PLS2 model was made with multiple PLS1 models, one for each chemical species present in the liquid phase. The latter had better predictions and made it possible to differentiate CO2 from its chemical forms, allowing a better understanding of the CO2 capture processes.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422022000600674&tlng=enamine blendcarbamatecarbon captureinfrared spectroscopy. |
| spellingShingle | Armando Zanone Denise T. Tavares José L. de Paiva QUANTITATIVE SPECIATION OF THE LIQUID PHASE BY FTIR SPECTROSCOPY IN THE SYSTEM AMP-PZ-CO2-H2O Química Nova amine blend carbamate carbon capture infrared spectroscopy. |
| title | QUANTITATIVE SPECIATION OF THE LIQUID PHASE BY FTIR SPECTROSCOPY IN THE SYSTEM AMP-PZ-CO2-H2O |
| title_full | QUANTITATIVE SPECIATION OF THE LIQUID PHASE BY FTIR SPECTROSCOPY IN THE SYSTEM AMP-PZ-CO2-H2O |
| title_fullStr | QUANTITATIVE SPECIATION OF THE LIQUID PHASE BY FTIR SPECTROSCOPY IN THE SYSTEM AMP-PZ-CO2-H2O |
| title_full_unstemmed | QUANTITATIVE SPECIATION OF THE LIQUID PHASE BY FTIR SPECTROSCOPY IN THE SYSTEM AMP-PZ-CO2-H2O |
| title_short | QUANTITATIVE SPECIATION OF THE LIQUID PHASE BY FTIR SPECTROSCOPY IN THE SYSTEM AMP-PZ-CO2-H2O |
| title_sort | quantitative speciation of the liquid phase by ftir spectroscopy in the system amp pz co2 h2o |
| topic | amine blend carbamate carbon capture infrared spectroscopy. |
| url | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422022000600674&tlng=en |
| work_keys_str_mv | AT armandozanone quantitativespeciationoftheliquidphasebyftirspectroscopyinthesystemamppzco2h2o AT denisettavares quantitativespeciationoftheliquidphasebyftirspectroscopyinthesystemamppzco2h2o AT joseldepaiva quantitativespeciationoftheliquidphasebyftirspectroscopyinthesystemamppzco2h2o |