Extended Graphite Supported Flower-like MnO<sub>2</sub> as Bifunctional Materials for Supercapacitors and Glucose Sensing

A simple, efficient, and cost-effective extended graphite as a supporting platform further supported the MnO<sub>2</sub> growth for the construction of hierarchical flower-like MnO<sub>2</sub>/extended graphite. MnO<sub>2</sub>/extended graphite exhibited an incre...

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Main Authors: Han-Wei Chang, Chung-Li Dong, Yan-Hua Chen, Yuan-Zhang Xu, Tzu-Chi Huang, Song-Chi Chen, Feng-Jiin Liu, Yin-Hung Lai, Yu-Chen Tsai
Format: Article
Language:English
Published: MDPI AG 2021-10-01
Series:Nanomaterials
Subjects:
Online Access:https://www.mdpi.com/2079-4991/11/11/2881
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author Han-Wei Chang
Chung-Li Dong
Yan-Hua Chen
Yuan-Zhang Xu
Tzu-Chi Huang
Song-Chi Chen
Feng-Jiin Liu
Yin-Hung Lai
Yu-Chen Tsai
author_facet Han-Wei Chang
Chung-Li Dong
Yan-Hua Chen
Yuan-Zhang Xu
Tzu-Chi Huang
Song-Chi Chen
Feng-Jiin Liu
Yin-Hung Lai
Yu-Chen Tsai
author_sort Han-Wei Chang
collection DOAJ
description A simple, efficient, and cost-effective extended graphite as a supporting platform further supported the MnO<sub>2</sub> growth for the construction of hierarchical flower-like MnO<sub>2</sub>/extended graphite. MnO<sub>2</sub>/extended graphite exhibited an increase in sp<sup>2</sup> carbon bonds in comparison with that of extended graphite. It can be expected to display better electrical conductivity and further promote electron/ion transport kinetics for boosting the electrochemical performance in supercapacitors and glucose sensing. In supercapacitors, MnO<sub>2</sub>/extended graphite delivered an areal capacitance value of 20.4 mF cm<sup>−2</sup> at 0.25 mA cm<sup>−2</sup> current densities and great cycling stability (capacitance retention of 83% after 1000 cycles). In glucose sensing, MnO<sub>2</sub>/extended graphite exhibited a good linear relationship in glucose concentration up to about 5 mM, sensitivity of 43 μA mM<sup>−1</sup>cm<sup>−2</sup>, and the limit of detection of 0.081 mM. It is further concluded that MnO<sub>2</sub>/extended graphite could be a good candidate for the future design of synergistic multifunctional materials in electrochemical techniques.
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spelling doaj.art-ce7b79f159ba41fb868eacbc1a7347ff2023-11-23T00:39:50ZengMDPI AGNanomaterials2079-49912021-10-011111288110.3390/nano11112881Extended Graphite Supported Flower-like MnO<sub>2</sub> as Bifunctional Materials for Supercapacitors and Glucose SensingHan-Wei Chang0Chung-Li Dong1Yan-Hua Chen2Yuan-Zhang Xu3Tzu-Chi Huang4Song-Chi Chen5Feng-Jiin Liu6Yin-Hung Lai7Yu-Chen Tsai8Department of Chemical Engineering, National United University, Miaoli 360302, TaiwanDepartment of Physics, Tamkang University, Tamsui, New Taipei City 25137, TaiwanDepartment of Chemical Engineering, National United University, Miaoli 360302, TaiwanDepartment of Chemical Engineering, National United University, Miaoli 360302, TaiwanDepartment of Chemical Engineering, National United University, Miaoli 360302, TaiwanDepartment of Chemical Engineering, National United University, Miaoli 360302, TaiwanDepartment of Chemical Engineering, National United University, Miaoli 360302, TaiwanDepartment of Chemical Engineering, National United University, Miaoli 360302, TaiwanDepartment of Chemical Engineering, National Chung Hsing University, Taichung 40227, TaiwanA simple, efficient, and cost-effective extended graphite as a supporting platform further supported the MnO<sub>2</sub> growth for the construction of hierarchical flower-like MnO<sub>2</sub>/extended graphite. MnO<sub>2</sub>/extended graphite exhibited an increase in sp<sup>2</sup> carbon bonds in comparison with that of extended graphite. It can be expected to display better electrical conductivity and further promote electron/ion transport kinetics for boosting the electrochemical performance in supercapacitors and glucose sensing. In supercapacitors, MnO<sub>2</sub>/extended graphite delivered an areal capacitance value of 20.4 mF cm<sup>−2</sup> at 0.25 mA cm<sup>−2</sup> current densities and great cycling stability (capacitance retention of 83% after 1000 cycles). In glucose sensing, MnO<sub>2</sub>/extended graphite exhibited a good linear relationship in glucose concentration up to about 5 mM, sensitivity of 43 μA mM<sup>−1</sup>cm<sup>−2</sup>, and the limit of detection of 0.081 mM. It is further concluded that MnO<sub>2</sub>/extended graphite could be a good candidate for the future design of synergistic multifunctional materials in electrochemical techniques.https://www.mdpi.com/2079-4991/11/11/2881MnO<sub>2</sub>/extended graphitesupercapacitorsglucose sensing
spellingShingle Han-Wei Chang
Chung-Li Dong
Yan-Hua Chen
Yuan-Zhang Xu
Tzu-Chi Huang
Song-Chi Chen
Feng-Jiin Liu
Yin-Hung Lai
Yu-Chen Tsai
Extended Graphite Supported Flower-like MnO<sub>2</sub> as Bifunctional Materials for Supercapacitors and Glucose Sensing
Nanomaterials
MnO<sub>2</sub>/extended graphite
supercapacitors
glucose sensing
title Extended Graphite Supported Flower-like MnO<sub>2</sub> as Bifunctional Materials for Supercapacitors and Glucose Sensing
title_full Extended Graphite Supported Flower-like MnO<sub>2</sub> as Bifunctional Materials for Supercapacitors and Glucose Sensing
title_fullStr Extended Graphite Supported Flower-like MnO<sub>2</sub> as Bifunctional Materials for Supercapacitors and Glucose Sensing
title_full_unstemmed Extended Graphite Supported Flower-like MnO<sub>2</sub> as Bifunctional Materials for Supercapacitors and Glucose Sensing
title_short Extended Graphite Supported Flower-like MnO<sub>2</sub> as Bifunctional Materials for Supercapacitors and Glucose Sensing
title_sort extended graphite supported flower like mno sub 2 sub as bifunctional materials for supercapacitors and glucose sensing
topic MnO<sub>2</sub>/extended graphite
supercapacitors
glucose sensing
url https://www.mdpi.com/2079-4991/11/11/2881
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