Crystal structures of binuclear complexes of gadolinium(III) and dysprosium(III) with oxalate bridges and chelating N,N′-bis(2-oxidobenzyl)-N,N′-bis(pyridin-2-ylmethyl)ethylenediamine (bbpen2−)

Crystal structures of binuclear complexes of gadolinium(III) and dysprosium(III) with oxalate bridges and chelating N,N′-bis(2-oxidobenzyl)-N,N′-bis(pyridin-2-ylmethyl)ethylenediamine (bbpen2−)

The reaction between mononuclear [Ln(bbpen)Cl] [Ln = Gd or Dy; H2bbpen = N,N′-bis(2-hydroxybenzyl)-N,N′-bis(pyridin-2-ylmethyl)ethylenediamine, C28H30N4O2] and potassium oxalate monohydrate in water/methanol produced the solvated centrosymmetric isostructural binuclear (μ-oxalato)bis{[N,N′-bis(2-oxi...

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Bibliographic Details
Main Authors: Guilherme Augusto Barbosa, Francielli Sousa Santana, Giovana Gioppo Nunes, Jaísa Fernandes Soares
Format: Article
Language:English
Published: International Union of Crystallography 2019-04-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
binuclear
lanthanide
oxalate bridge
N,N′-bis(2-hydroxybenzyl)-N,N′-bis(pyridin-2-ylmethyl)ethylenediamine
H2bbpen
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989019002998

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