Limiting Factors Affecting the Ionic Conductivities of LATP/Polymer Hybrid Electrolytes
All-Solid-State Lithium Batteries (ASSLB) are promising candidates for next generation lithium battery systems due to their increased safety, stability, and energy density. Ceramic and solid composite electrolytes (SCE), which consist of dispersed ceramic particles within a polymeric host, are among...
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| Format: | Article |
| Language: | English |
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MDPI AG
2023-01-01
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| Series: | Batteries |
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| Online Access: | https://www.mdpi.com/2313-0105/9/2/87 |
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| author | Adrien Méry Steeve Rousselot David Lepage David Aymé-Perrot Mickael Dollé |
| author_facet | Adrien Méry Steeve Rousselot David Lepage David Aymé-Perrot Mickael Dollé |
| author_sort | Adrien Méry |
| collection | DOAJ |
| description | All-Solid-State Lithium Batteries (ASSLB) are promising candidates for next generation lithium battery systems due to their increased safety, stability, and energy density. Ceramic and solid composite electrolytes (SCE), which consist of dispersed ceramic particles within a polymeric host, are among the preferred technologies for use as electrolytes in ASSLB systems. Synergetic effects between ceramic and polymer electrolyte components are usually reported in SCE. Herein, we report a case study on the lithium conductivity of ceramic and SCE comprised of Li<sub>1.4</sub>Al<sub>0.4</sub>Ti<sub>1.6</sub>(PO<sub>4</sub>)<sub>3</sub> (LATP), a NASICON-type ceramic. An evaluation of the impact of the processing and sintering of the ceramic on the conductive properties of the electrolyte is addressed. The study is then extended to Poly(Ethylene) Oxide (PEO)-LATP SCE. The presence of the ceramic particles conferred limited benefits to the SCE. These findings somewhat contradict commonly held assumptions on the role of ceramic additives in SCE. |
| first_indexed | 2024-03-11T09:09:24Z |
| format | Article |
| id | doaj.art-ceb1bfe5257940acb8f5a30b4da4e6b1 |
| institution | Directory Open Access Journal |
| issn | 2313-0105 |
| language | English |
| last_indexed | 2024-03-11T09:09:24Z |
| publishDate | 2023-01-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Batteries |
| spelling | doaj.art-ceb1bfe5257940acb8f5a30b4da4e6b12023-11-16T19:07:22ZengMDPI AGBatteries2313-01052023-01-01928710.3390/batteries9020087Limiting Factors Affecting the Ionic Conductivities of LATP/Polymer Hybrid ElectrolytesAdrien Méry0Steeve Rousselot1David Lepage2David Aymé-Perrot3Mickael Dollé4Chemistry Department, Université de Montréal, 1375 Avenue Thérèse-Lavoie-Roux, Montreal, QC H2V 0B3, CanadaChemistry Department, Université de Montréal, 1375 Avenue Thérèse-Lavoie-Roux, Montreal, QC H2V 0B3, CanadaChemistry Department, Université de Montréal, 1375 Avenue Thérèse-Lavoie-Roux, Montreal, QC H2V 0B3, CanadaTotalEnergies SE, 2 Pl. Jean Millier, La Défense 6, 92078 Paris, FranceChemistry Department, Université de Montréal, 1375 Avenue Thérèse-Lavoie-Roux, Montreal, QC H2V 0B3, CanadaAll-Solid-State Lithium Batteries (ASSLB) are promising candidates for next generation lithium battery systems due to their increased safety, stability, and energy density. Ceramic and solid composite electrolytes (SCE), which consist of dispersed ceramic particles within a polymeric host, are among the preferred technologies for use as electrolytes in ASSLB systems. Synergetic effects between ceramic and polymer electrolyte components are usually reported in SCE. Herein, we report a case study on the lithium conductivity of ceramic and SCE comprised of Li<sub>1.4</sub>Al<sub>0.4</sub>Ti<sub>1.6</sub>(PO<sub>4</sub>)<sub>3</sub> (LATP), a NASICON-type ceramic. An evaluation of the impact of the processing and sintering of the ceramic on the conductive properties of the electrolyte is addressed. The study is then extended to Poly(Ethylene) Oxide (PEO)-LATP SCE. The presence of the ceramic particles conferred limited benefits to the SCE. These findings somewhat contradict commonly held assumptions on the role of ceramic additives in SCE.https://www.mdpi.com/2313-0105/9/2/87All-Solid-State Lithium Batterysolid composite electrolyteceramic electrolytesinteringpressure |
| spellingShingle | Adrien Méry Steeve Rousselot David Lepage David Aymé-Perrot Mickael Dollé Limiting Factors Affecting the Ionic Conductivities of LATP/Polymer Hybrid Electrolytes Batteries All-Solid-State Lithium Battery solid composite electrolyte ceramic electrolyte sintering pressure |
| title | Limiting Factors Affecting the Ionic Conductivities of LATP/Polymer Hybrid Electrolytes |
| title_full | Limiting Factors Affecting the Ionic Conductivities of LATP/Polymer Hybrid Electrolytes |
| title_fullStr | Limiting Factors Affecting the Ionic Conductivities of LATP/Polymer Hybrid Electrolytes |
| title_full_unstemmed | Limiting Factors Affecting the Ionic Conductivities of LATP/Polymer Hybrid Electrolytes |
| title_short | Limiting Factors Affecting the Ionic Conductivities of LATP/Polymer Hybrid Electrolytes |
| title_sort | limiting factors affecting the ionic conductivities of latp polymer hybrid electrolytes |
| topic | All-Solid-State Lithium Battery solid composite electrolyte ceramic electrolyte sintering pressure |
| url | https://www.mdpi.com/2313-0105/9/2/87 |
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