Dry Glass Reference Perturbation Theory Predictions of the Temperature and Pressure Dependent Separations of Complex Liquid Mixtures Using SBAD-1 Glassy Polymer Membranes
In this work we apply dry glass reference perturbation theory (DGRPT) within the context of fully mutualized diffusion theory to predict the temperature and pressure dependent separations of complex liquid mixtures using SBAD-1 glassy polymer membranes. We demonstrate that the approach allows for th...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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MDPI AG
2022-07-01
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| Series: | Membranes |
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| Online Access: | https://www.mdpi.com/2077-0375/12/7/705 |
| _version_ | 1797417107247333376 |
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| author | Bennett D. Marshall Wenjun Li Ryan P. Lively |
| author_facet | Bennett D. Marshall Wenjun Li Ryan P. Lively |
| author_sort | Bennett D. Marshall |
| collection | DOAJ |
| description | In this work we apply dry glass reference perturbation theory (DGRPT) within the context of fully mutualized diffusion theory to predict the temperature and pressure dependent separations of complex liquid mixtures using SBAD-1 glassy polymer membranes. We demonstrate that the approach allows for the prediction of the membrane-based separation of complex liquid mixtures over a wide range of temperature and pressure, using only single-component vapor sorption isotherms measured at 25 °C to parameterize the model. The model was then applied to predict the membrane separation of a light shale crude using a structure oriented lumping (SOL) based compositional model of petroleum. It was shown that when DGRPT is applied based on SOL compositions, the combined model allows for the accurate prediction of separation performance based on the trend of both molecular weight and molecular class. |
| first_indexed | 2024-03-09T06:14:02Z |
| format | Article |
| id | doaj.art-ceb9197b56f344378c481ef2e61cffe8 |
| institution | Directory Open Access Journal |
| issn | 2077-0375 |
| language | English |
| last_indexed | 2024-03-09T06:14:02Z |
| publishDate | 2022-07-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Membranes |
| spelling | doaj.art-ceb9197b56f344378c481ef2e61cffe82023-12-03T11:55:34ZengMDPI AGMembranes2077-03752022-07-0112770510.3390/membranes12070705Dry Glass Reference Perturbation Theory Predictions of the Temperature and Pressure Dependent Separations of Complex Liquid Mixtures Using SBAD-1 Glassy Polymer MembranesBennett D. Marshall0Wenjun Li1Ryan P. Lively2ExxonMobil Technology and Engineering Company, Annandale, NJ 08801, USAExxonMobil Technology and Engineering Company, Annandale, NJ 08801, USASchool of Chemical and Biomolecular Engineering, Georgia Institute of Technology, Atlanta, GA 30332, USAIn this work we apply dry glass reference perturbation theory (DGRPT) within the context of fully mutualized diffusion theory to predict the temperature and pressure dependent separations of complex liquid mixtures using SBAD-1 glassy polymer membranes. We demonstrate that the approach allows for the prediction of the membrane-based separation of complex liquid mixtures over a wide range of temperature and pressure, using only single-component vapor sorption isotherms measured at 25 °C to parameterize the model. The model was then applied to predict the membrane separation of a light shale crude using a structure oriented lumping (SOL) based compositional model of petroleum. It was shown that when DGRPT is applied based on SOL compositions, the combined model allows for the accurate prediction of separation performance based on the trend of both molecular weight and molecular class.https://www.mdpi.com/2077-0375/12/7/705glassy polymermembranestheorypetrochemical |
| spellingShingle | Bennett D. Marshall Wenjun Li Ryan P. Lively Dry Glass Reference Perturbation Theory Predictions of the Temperature and Pressure Dependent Separations of Complex Liquid Mixtures Using SBAD-1 Glassy Polymer Membranes Membranes glassy polymer membranes theory petrochemical |
| title | Dry Glass Reference Perturbation Theory Predictions of the Temperature and Pressure Dependent Separations of Complex Liquid Mixtures Using SBAD-1 Glassy Polymer Membranes |
| title_full | Dry Glass Reference Perturbation Theory Predictions of the Temperature and Pressure Dependent Separations of Complex Liquid Mixtures Using SBAD-1 Glassy Polymer Membranes |
| title_fullStr | Dry Glass Reference Perturbation Theory Predictions of the Temperature and Pressure Dependent Separations of Complex Liquid Mixtures Using SBAD-1 Glassy Polymer Membranes |
| title_full_unstemmed | Dry Glass Reference Perturbation Theory Predictions of the Temperature and Pressure Dependent Separations of Complex Liquid Mixtures Using SBAD-1 Glassy Polymer Membranes |
| title_short | Dry Glass Reference Perturbation Theory Predictions of the Temperature and Pressure Dependent Separations of Complex Liquid Mixtures Using SBAD-1 Glassy Polymer Membranes |
| title_sort | dry glass reference perturbation theory predictions of the temperature and pressure dependent separations of complex liquid mixtures using sbad 1 glassy polymer membranes |
| topic | glassy polymer membranes theory petrochemical |
| url | https://www.mdpi.com/2077-0375/12/7/705 |
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