High methane combustion activity of PdO/CeO2–ZrO2–NiO/γ-Al2O3 catalysts

PdO/CeO2–ZrO2–NiO/γ-Al2O3 catalysts were prepared for the combustion of methane at moderate temperatures. The introduction of a small amount of NiO within the cubic fluorite CeO2–ZrO2 structure as a promoter effectively enhanced the oxygen release and storage abilities of the catalysts, thereby achi...

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Main Authors: Minchan Jeong, Naoyoshi Nunotani, Naoki Moriyama, Nobuhito Imanaka
Format: Article
Language:English
Published: Taylor & Francis Group 2016-09-01
Series:Journal of Asian Ceramic Societies
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2187076416300136
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author Minchan Jeong
Naoyoshi Nunotani
Naoki Moriyama
Nobuhito Imanaka
author_facet Minchan Jeong
Naoyoshi Nunotani
Naoki Moriyama
Nobuhito Imanaka
author_sort Minchan Jeong
collection DOAJ
description PdO/CeO2–ZrO2–NiO/γ-Al2O3 catalysts were prepared for the combustion of methane at moderate temperatures. The introduction of a small amount of NiO within the cubic fluorite CeO2–ZrO2 structure as a promoter effectively enhanced the oxygen release and storage abilities of the catalysts, thereby achieving the complete oxidation of methane. The catalyst with the highest activity for methane combustion was 11.3 mass% PdO/20 mass% Ce0.64Zr0.16Ni0.2O1.9/γ-Al2O3, and efficient combustion was realized at a temperature as low as 300 °C.
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spelling doaj.art-cebcda722b5d4e5681d71698eca2e1d32022-12-21T20:31:40ZengTaylor & Francis GroupJournal of Asian Ceramic Societies2187-07642016-09-014325926210.1016/j.jascer.2016.05.004High methane combustion activity of PdO/CeO2–ZrO2–NiO/γ-Al2O3 catalystsMinchan JeongNaoyoshi NunotaniNaoki MoriyamaNobuhito ImanakaPdO/CeO2–ZrO2–NiO/γ-Al2O3 catalysts were prepared for the combustion of methane at moderate temperatures. The introduction of a small amount of NiO within the cubic fluorite CeO2–ZrO2 structure as a promoter effectively enhanced the oxygen release and storage abilities of the catalysts, thereby achieving the complete oxidation of methane. The catalyst with the highest activity for methane combustion was 11.3 mass% PdO/20 mass% Ce0.64Zr0.16Ni0.2O1.9/γ-Al2O3, and efficient combustion was realized at a temperature as low as 300 °C.http://www.sciencedirect.com/science/article/pii/S2187076416300136CeriaCatalystMethaneRare earth oxide
spellingShingle Minchan Jeong
Naoyoshi Nunotani
Naoki Moriyama
Nobuhito Imanaka
High methane combustion activity of PdO/CeO2–ZrO2–NiO/γ-Al2O3 catalysts
Journal of Asian Ceramic Societies
Ceria
Catalyst
Methane
Rare earth oxide
title High methane combustion activity of PdO/CeO2–ZrO2–NiO/γ-Al2O3 catalysts
title_full High methane combustion activity of PdO/CeO2–ZrO2–NiO/γ-Al2O3 catalysts
title_fullStr High methane combustion activity of PdO/CeO2–ZrO2–NiO/γ-Al2O3 catalysts
title_full_unstemmed High methane combustion activity of PdO/CeO2–ZrO2–NiO/γ-Al2O3 catalysts
title_short High methane combustion activity of PdO/CeO2–ZrO2–NiO/γ-Al2O3 catalysts
title_sort high methane combustion activity of pdo ceo2 zro2 nio γ al2o3 catalysts
topic Ceria
Catalyst
Methane
Rare earth oxide
url http://www.sciencedirect.com/science/article/pii/S2187076416300136
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AT naokimoriyama highmethanecombustionactivityofpdoceo2zro2niogal2o3catalysts
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