Fluorescein dihexanoate as a profluorescent marker for monitoring of hydrolytic descruction of polylactide-based materials

Polylactide (PLA) is one of the most promising biodegradable and biocompatible polymer materials. Estimation of hydrolytic destruction of PLA is of high importance for their applications both at planning and at real-time exploitation. This paper reports on synthesis and applicability of fluorescein-...

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Main Authors: Dmitry A. Belov, Yaroslav V. Faletrov, Polina S. Yakovets, Vladimir M. Shkumatov
Format: Article
Language:Belarusian
Published: Belarusian State University 2022-04-01
Series:Журнал Белорусского государственного университета: Химия
Subjects:
Online Access:https://journals.bsu.by/index.php/chemistry/article/view/4310
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author Dmitry A. Belov
Yaroslav V. Faletrov
Polina S. Yakovets
Vladimir M. Shkumatov
author_facet Dmitry A. Belov
Yaroslav V. Faletrov
Polina S. Yakovets
Vladimir M. Shkumatov
author_sort Dmitry A. Belov
collection DOAJ
description Polylactide (PLA) is one of the most promising biodegradable and biocompatible polymer materials. Estimation of hydrolytic destruction of PLA is of high importance for their applications both at planning and at real-time exploitation. This paper reports on synthesis and applicability of fluorescein-O-dihexanoate as a pro-fluorescent marker of hydrolytic destruction of two types of PLA-based materials. Fluorescence enhancement correlated with adequately more fast destruction of poly-D,L-lactide as well as less stability to alkaline hydrolysis. Thus, applicability of fluorescein-O-dihexanoate for fluorescence-based estimation of hydrolytic destruction of PLA-based materials is shown in quite real time mode.
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language Belarusian
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series Журнал Белорусского государственного университета: Химия
spelling doaj.art-cec1ce0a4ace4746bc76c9d30ef4ff9d2022-12-22T00:32:30ZbelBelarusian State UniversityЖурнал Белорусского государственного университета: Химия2520-257X2617-39802022-04-011536010.33581/2520-257X-2022-1-53-604310Fluorescein dihexanoate as a profluorescent marker for monitoring of hydrolytic descruction of polylactide-based materialsDmitry A. Belov0https://orcid.org/0000-0002-0304-256XYaroslav V. Faletrov1Polina S. Yakovets2Vladimir M. Shkumatov3Belarusian State University, 4 Niezaliežnasci Avenue, Minsk 220030, BelarusBelarusian State University, 4 Niezaliežnasci Avenue, Minsk 220030, Belarus; Research Institute for Physical Chemical Problems, Belarusian State University, 14 Lieninhradskaja Street, Minsk 220006, BelarusBelarusian State University, 4 Niezaliežnasci Avenue, Minsk 220030, BelarusBelarusian State University, 4 Niezaliežnasci Avenue, Minsk 220030, Belarus; Research Institute for Physical Chemical Problems, Belarusian State University, 14 Lieninhradskaja Street, Minsk 220006, BelarusPolylactide (PLA) is one of the most promising biodegradable and biocompatible polymer materials. Estimation of hydrolytic destruction of PLA is of high importance for their applications both at planning and at real-time exploitation. This paper reports on synthesis and applicability of fluorescein-O-dihexanoate as a pro-fluorescent marker of hydrolytic destruction of two types of PLA-based materials. Fluorescence enhancement correlated with adequately more fast destruction of poly-D,L-lactide as well as less stability to alkaline hydrolysis. Thus, applicability of fluorescein-O-dihexanoate for fluorescence-based estimation of hydrolytic destruction of PLA-based materials is shown in quite real time mode.https://journals.bsu.by/index.php/chemistry/article/view/4310poly-l-lactidepoly-d,l-lactidefluorescein-o-dihexanoatefluorescencehydrolysis
spellingShingle Dmitry A. Belov
Yaroslav V. Faletrov
Polina S. Yakovets
Vladimir M. Shkumatov
Fluorescein dihexanoate as a profluorescent marker for monitoring of hydrolytic descruction of polylactide-based materials
Журнал Белорусского государственного университета: Химия
poly-l-lactide
poly-d,l-lactide
fluorescein-o-dihexanoate
fluorescence
hydrolysis
title Fluorescein dihexanoate as a profluorescent marker for monitoring of hydrolytic descruction of polylactide-based materials
title_full Fluorescein dihexanoate as a profluorescent marker for monitoring of hydrolytic descruction of polylactide-based materials
title_fullStr Fluorescein dihexanoate as a profluorescent marker for monitoring of hydrolytic descruction of polylactide-based materials
title_full_unstemmed Fluorescein dihexanoate as a profluorescent marker for monitoring of hydrolytic descruction of polylactide-based materials
title_short Fluorescein dihexanoate as a profluorescent marker for monitoring of hydrolytic descruction of polylactide-based materials
title_sort fluorescein dihexanoate as a profluorescent marker for monitoring of hydrolytic descruction of polylactide based materials
topic poly-l-lactide
poly-d,l-lactide
fluorescein-o-dihexanoate
fluorescence
hydrolysis
url https://journals.bsu.by/index.php/chemistry/article/view/4310
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AT polinasyakovets fluoresceindihexanoateasaprofluorescentmarkerformonitoringofhydrolyticdescructionofpolylactidebasedmaterials
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