Coordination and Crystallization Molecules: Their Interactions Affecting the Dimensionality of Metalloporphyrinic SCFs
Synthetic metalloporphyrin complexes are often used as analogues of natural systems, and they can be used for the preparation of new Solid Coordination Frameworks (SCFs). In this work, a series of six metalloporphyrinic compounds constructed from different meso substituted metalloporphyrins (phenyl,...
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| Format: | Article |
| Language: | English |
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MDPI AG
2015-04-01
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| Series: | Molecules |
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| Online Access: | http://www.mdpi.com/1420-3049/20/4/6683 |
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| author | Arkaitz Fidalgo-Marijuan Eder Amayuelas Gotzone Barandika Begoña Bazán Miren Karmele Urtiaga María Isabel Arriortua |
| author_facet | Arkaitz Fidalgo-Marijuan Eder Amayuelas Gotzone Barandika Begoña Bazán Miren Karmele Urtiaga María Isabel Arriortua |
| author_sort | Arkaitz Fidalgo-Marijuan |
| collection | DOAJ |
| description | Synthetic metalloporphyrin complexes are often used as analogues of natural systems, and they can be used for the preparation of new Solid Coordination Frameworks (SCFs). In this work, a series of six metalloporphyrinic compounds constructed from different meso substituted metalloporphyrins (phenyl, carboxyphenyl and sulfonatophenyl) have been structurally characterized by means of single crystal X-ray diffraction, IR spectroscopy and elemental analysis. The compounds were classified considering the dimensionality of the crystal array, referred just to coordination bonds, into 0D, 1D and 2D compounds. This way, the structural features and relationships of those crystal structures were analyzed, in order to extract conclusions not only about the dimensionality of the networks but also about possible applications of the as-obtained compounds, focusing the interest on the interactions of coordination and crystallization molecules. These interactions provide the coordination bonds and the cohesion forces which produce SCFs with different dimensionalities. |
| first_indexed | 2024-04-13T07:09:26Z |
| format | Article |
| id | doaj.art-cecbd4ac43de41cea36741963af24bce |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-04-13T07:09:26Z |
| publishDate | 2015-04-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-cecbd4ac43de41cea36741963af24bce2022-12-22T02:56:54ZengMDPI AGMolecules1420-30492015-04-012046683669910.3390/molecules20046683molecules20046683Coordination and Crystallization Molecules: Their Interactions Affecting the Dimensionality of Metalloporphyrinic SCFsArkaitz Fidalgo-Marijuan0Eder Amayuelas1Gotzone Barandika2Begoña Bazán3Miren Karmele Urtiaga4María Isabel Arriortua5Departamento de Mineralogía y Petrología, Facultad de Ciencia y Tecnología, Universidad del País Vasco (UPV/EHU), Apdo. 644, 48080 Bilbao, SpainDepartamento de Mineralogía y Petrología, Facultad de Ciencia y Tecnología, Universidad del País Vasco (UPV/EHU), Apdo. 644, 48080 Bilbao, SpainDepartamento de Química Inorgánica, Facultad de Ciencia y Tecnología, Universidad del País Vasco (UPV/EHU), Apdo. 644, 48080 Bilbao, SpainDepartamento de Mineralogía y Petrología, Facultad de Ciencia y Tecnología, Universidad del País Vasco (UPV/EHU), Apdo. 644, 48080 Bilbao, SpainDepartamento de Mineralogía y Petrología, Facultad de Ciencia y Tecnología, Universidad del País Vasco (UPV/EHU), Apdo. 644, 48080 Bilbao, SpainDepartamento de Mineralogía y Petrología, Facultad de Ciencia y Tecnología, Universidad del País Vasco (UPV/EHU), Apdo. 644, 48080 Bilbao, SpainSynthetic metalloporphyrin complexes are often used as analogues of natural systems, and they can be used for the preparation of new Solid Coordination Frameworks (SCFs). In this work, a series of six metalloporphyrinic compounds constructed from different meso substituted metalloporphyrins (phenyl, carboxyphenyl and sulfonatophenyl) have been structurally characterized by means of single crystal X-ray diffraction, IR spectroscopy and elemental analysis. The compounds were classified considering the dimensionality of the crystal array, referred just to coordination bonds, into 0D, 1D and 2D compounds. This way, the structural features and relationships of those crystal structures were analyzed, in order to extract conclusions not only about the dimensionality of the networks but also about possible applications of the as-obtained compounds, focusing the interest on the interactions of coordination and crystallization molecules. These interactions provide the coordination bonds and the cohesion forces which produce SCFs with different dimensionalities.http://www.mdpi.com/1420-3049/20/4/6683metalloporphyrinSolid Coordination Frameworks (SCFs)crystal structuredimensionality |
| spellingShingle | Arkaitz Fidalgo-Marijuan Eder Amayuelas Gotzone Barandika Begoña Bazán Miren Karmele Urtiaga María Isabel Arriortua Coordination and Crystallization Molecules: Their Interactions Affecting the Dimensionality of Metalloporphyrinic SCFs Molecules metalloporphyrin Solid Coordination Frameworks (SCFs) crystal structure dimensionality |
| title | Coordination and Crystallization Molecules: Their Interactions Affecting the Dimensionality of Metalloporphyrinic SCFs |
| title_full | Coordination and Crystallization Molecules: Their Interactions Affecting the Dimensionality of Metalloporphyrinic SCFs |
| title_fullStr | Coordination and Crystallization Molecules: Their Interactions Affecting the Dimensionality of Metalloporphyrinic SCFs |
| title_full_unstemmed | Coordination and Crystallization Molecules: Their Interactions Affecting the Dimensionality of Metalloporphyrinic SCFs |
| title_short | Coordination and Crystallization Molecules: Their Interactions Affecting the Dimensionality of Metalloporphyrinic SCFs |
| title_sort | coordination and crystallization molecules their interactions affecting the dimensionality of metalloporphyrinic scfs |
| topic | metalloporphyrin Solid Coordination Frameworks (SCFs) crystal structure dimensionality |
| url | http://www.mdpi.com/1420-3049/20/4/6683 |
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