Numerical study and optimization of GO/ZnO based perovskite solar cell using SCAPS

This paper focuses on the numerical study of hybrid organic-inorganic perovskite solar cells. It investigates the incorporation of a graphene oxide (GO) thin layer to enhance solar cell efficiency. The study demonstrates that the GO layer improves interaction with the absorber layer and enhances hol...

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Main Authors: Norsakinah Johrin, Fuei Pien Chee, Syafiqa Nasir, Pak Yan Moh
Format: Article
Language:English
Published: AIMS Press 2023-08-01
Series:AIMS Energy
Subjects:
Online Access:https://www.aimspress.com/article/doi/10.3934/energy.2023034?viewType=HTML
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author Norsakinah Johrin
Fuei Pien Chee
Syafiqa Nasir
Pak Yan Moh
author_facet Norsakinah Johrin
Fuei Pien Chee
Syafiqa Nasir
Pak Yan Moh
author_sort Norsakinah Johrin
collection DOAJ
description This paper focuses on the numerical study of hybrid organic-inorganic perovskite solar cells. It investigates the incorporation of a graphene oxide (GO) thin layer to enhance solar cell efficiency. The study demonstrates that the GO layer improves interaction with the absorber layer and enhances hole transportation, resulting in reduced recombination and diffusion losses at the absorber and hole transport layer (HTL) interface. The increased energy level of the Lower Unoccupied Molecular Orbital (LUMO) in GO acts as an excellent electron-blocking layer, thereby improving the V<sub>OC</sub>. The objective is to explore different structures of perovskite solar cells to enhance their performance. The simulated solar cell comprises a GO/FASnI<sub>3</sub>/TiO<sub>2</sub>/ZnO/ITO sandwich structure, with FASnI<sub>3</sub> and ZnO thicknesses adjusted to improve conversion efficiency. The impact of thickness on device performance, specifically the absorber and electron transport layers, is investigated. The fill factor (FF) changes as the absorber and electron transport layers (ETL) increase. The FF is an important parameter that determines PSC performance since it measures how effectively power is transferred from the cell to an external circuit. The optimized solar cell achieves a short-circuit current density (J<sub>SC</sub>) of 27.27 mA/cm<sup>2</sup>, an open-circuit voltage (V<sub>OC</sub>) of 2.76 V, a fill factor (FF) of 27.05% and the highest power conversion efficiency (PCE) of 20.39% with 400 nm of FASnI<sub>3</sub> and 300 nm of ZnO. These findings suggest promising directions for the development of more effective GO-based perovskite solar cells.
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spelling doaj.art-cedb5d8d760b4c65877760793752b8e82023-10-19T01:17:32ZengAIMS PressAIMS Energy2333-83342023-08-0111468369310.3934/energy.2023034Numerical study and optimization of GO/ZnO based perovskite solar cell using SCAPSNorsakinah Johrin0Fuei Pien Chee1Syafiqa Nasir2Pak Yan Moh31. Physics with Electronic Programme, Faculty of Science and Natural Resources, Universiti Malaysia Sabah1. Physics with Electronic Programme, Faculty of Science and Natural Resources, Universiti Malaysia Sabah1. Physics with Electronic Programme, Faculty of Science and Natural Resources, Universiti Malaysia Sabah2. Industrial Chemistry Programme, Faculty of Science and Natural Resources, Universiti Malaysia Sabah 3. Water Research Unit, Faculty of Science and Natural Resources, Universiti Malaysia SabahThis paper focuses on the numerical study of hybrid organic-inorganic perovskite solar cells. It investigates the incorporation of a graphene oxide (GO) thin layer to enhance solar cell efficiency. The study demonstrates that the GO layer improves interaction with the absorber layer and enhances hole transportation, resulting in reduced recombination and diffusion losses at the absorber and hole transport layer (HTL) interface. The increased energy level of the Lower Unoccupied Molecular Orbital (LUMO) in GO acts as an excellent electron-blocking layer, thereby improving the V<sub>OC</sub>. The objective is to explore different structures of perovskite solar cells to enhance their performance. The simulated solar cell comprises a GO/FASnI<sub>3</sub>/TiO<sub>2</sub>/ZnO/ITO sandwich structure, with FASnI<sub>3</sub> and ZnO thicknesses adjusted to improve conversion efficiency. The impact of thickness on device performance, specifically the absorber and electron transport layers, is investigated. The fill factor (FF) changes as the absorber and electron transport layers (ETL) increase. The FF is an important parameter that determines PSC performance since it measures how effectively power is transferred from the cell to an external circuit. The optimized solar cell achieves a short-circuit current density (J<sub>SC</sub>) of 27.27 mA/cm<sup>2</sup>, an open-circuit voltage (V<sub>OC</sub>) of 2.76 V, a fill factor (FF) of 27.05% and the highest power conversion efficiency (PCE) of 20.39% with 400 nm of FASnI<sub>3</sub> and 300 nm of ZnO. These findings suggest promising directions for the development of more effective GO-based perovskite solar cells.https://www.aimspress.com/article/doi/10.3934/energy.2023034?viewType=HTMLsolar cellgraphene oxideperovskitefill factorpower conversion efficiencyscaps
spellingShingle Norsakinah Johrin
Fuei Pien Chee
Syafiqa Nasir
Pak Yan Moh
Numerical study and optimization of GO/ZnO based perovskite solar cell using SCAPS
AIMS Energy
solar cell
graphene oxide
perovskite
fill factor
power conversion efficiency
scaps
title Numerical study and optimization of GO/ZnO based perovskite solar cell using SCAPS
title_full Numerical study and optimization of GO/ZnO based perovskite solar cell using SCAPS
title_fullStr Numerical study and optimization of GO/ZnO based perovskite solar cell using SCAPS
title_full_unstemmed Numerical study and optimization of GO/ZnO based perovskite solar cell using SCAPS
title_short Numerical study and optimization of GO/ZnO based perovskite solar cell using SCAPS
title_sort numerical study and optimization of go zno based perovskite solar cell using scaps
topic solar cell
graphene oxide
perovskite
fill factor
power conversion efficiency
scaps
url https://www.aimspress.com/article/doi/10.3934/energy.2023034?viewType=HTML
work_keys_str_mv AT norsakinahjohrin numericalstudyandoptimizationofgoznobasedperovskitesolarcellusingscaps
AT fueipienchee numericalstudyandoptimizationofgoznobasedperovskitesolarcellusingscaps
AT syafiqanasir numericalstudyandoptimizationofgoznobasedperovskitesolarcellusingscaps
AT pakyanmoh numericalstudyandoptimizationofgoznobasedperovskitesolarcellusingscaps