The Volcanic-Rich Layer of the “Camporotondo (Marche, Italy)” Section: Petrography and Sedimentation of an Unknown Distal Messinian Eruption

A Messinian and lithified horizon enriched in volcanic particles with thicknesses of 170–180 cm crops in the Camporotondo (CR) section (Marche, Italy). This volcanic-rich layer (VRL) was investigated by field plus mesoscopic observations, X-ray powder diffraction (XRPD), scanning electron microscopy...

Full description

Bibliographic Details
Main Authors: Davide Potere, Vittorio Scisciani, Monica Piochi, Pietro Paolo Pierantoni, Angela Mormone, Manuela Nazzari, Piergiorgio Scarlato, Gianluca Iezzi
Format: Article
Language:English
Published: MDPI AG 2022-07-01
Series:Minerals
Subjects:
Online Access:https://www.mdpi.com/2075-163X/12/7/893
_version_ 1797416825157320704
author Davide Potere
Vittorio Scisciani
Monica Piochi
Pietro Paolo Pierantoni
Angela Mormone
Manuela Nazzari
Piergiorgio Scarlato
Gianluca Iezzi
author_facet Davide Potere
Vittorio Scisciani
Monica Piochi
Pietro Paolo Pierantoni
Angela Mormone
Manuela Nazzari
Piergiorgio Scarlato
Gianluca Iezzi
author_sort Davide Potere
collection DOAJ
description A Messinian and lithified horizon enriched in volcanic particles with thicknesses of 170–180 cm crops in the Camporotondo (CR) section (Marche, Italy). This volcanic-rich layer (VRL) was investigated by field plus mesoscopic observations, X-ray powder diffraction (XRPD), scanning electron microscopy (SEM), bulk composition methods and electron-microprobe analysis (EMPA). The quantitative textural features of volcanic and sedimentary components were determined by 2D image analysis. The lowermost massive 70–80 cm portion is free of sedimentary structure or characterised only by plane-parallel ones, whereas the uppermost one is undulated and cross-laminated. The XRPD and SEM outcomes unveil that the VRL of CR is mainly composed of glassy shards (≥80 area%), a variable amount of sedimentary minerals (<20 area%) and a very low content of magmatic minerals (few area%). The bulk and micro-chemical attributes of volcanic and glassy materials are rhyolitic and almost identical to previous VRLs dated at 5.5 Ma (VRL-5.5). The signatures of immobile elements and the high amount of H<sub>2</sub>O present in the glass fraction suggest a provenance from a convergent geodynamic setting. The 2D image analysis on SEM observations show that the VRL-5.5 of CR is composed of very fine and sorted (averages of <i>M</i><sub>Z</sub> of 5,72 and <i>σ</i><sub><i>i</i></sub> of 0,70), scarcely vesicular, glass shards, with similar long and short size dimensions, shape and roundness. The VRL-5.5 of CR is free of large minerals and fossils. The coupling of mesoscopic and microscopic determinations indicates that the lowermost interval was deposited such as a primary tephra, i.e., fallout pyroclasts sinking in seawater. Instead, the uppermost interval derives from local, low-energy and sin-depositional remobilisation of the same VRL-5.5. The textural attributes of the volcanic fractions, the sedimentological features and the thickness of the VRL at CR correspond to the westward deposit of a still unknown eruption likely occurred at 5.5 Ma.
first_indexed 2024-03-09T06:09:46Z
format Article
id doaj.art-cedeea4439a34c789ecbe61619ec8090
institution Directory Open Access Journal
issn 2075-163X
language English
last_indexed 2024-03-09T06:09:46Z
publishDate 2022-07-01
publisher MDPI AG
record_format Article
series Minerals
spelling doaj.art-cedeea4439a34c789ecbe61619ec80902023-12-03T12:00:20ZengMDPI AGMinerals2075-163X2022-07-0112789310.3390/min12070893The Volcanic-Rich Layer of the “Camporotondo (Marche, Italy)” Section: Petrography and Sedimentation of an Unknown Distal Messinian EruptionDavide Potere0Vittorio Scisciani1Monica Piochi2Pietro Paolo Pierantoni3Angela Mormone4Manuela Nazzari5Piergiorgio Scarlato6Gianluca Iezzi7Dipartimento di Ingegneria & Geologia, Università G. d’Annunzio, Via dei Vestini 30, 66100 Chieti, ItalyDipartimento di Ingegneria & Geologia, Università G. d’Annunzio, Via dei Vestini 30, 66100 Chieti, ItalyOsservatorio Vesuviano, Istituto Nazionale di Geofisica e Vulcanologia, 80124 Naples, ItalyScuola di Scienze e Tecnologia, Università degli Studi di Camerino, 62032 Camerino, ItalyOsservatorio Vesuviano, Istituto Nazionale di Geofisica e Vulcanologia, 80124 Naples, ItalyIstituto Nazionale di Geofisica e Vulcanologia, Via di Vigna Murata 605, 00143 Roma, ItalyIstituto Nazionale di Geofisica e Vulcanologia, Via di Vigna Murata 605, 00143 Roma, ItalyDipartimento di Ingegneria & Geologia, Università G. d’Annunzio, Via dei Vestini 30, 66100 Chieti, ItalyA Messinian and lithified horizon enriched in volcanic particles with thicknesses of 170–180 cm crops in the Camporotondo (CR) section (Marche, Italy). This volcanic-rich layer (VRL) was investigated by field plus mesoscopic observations, X-ray powder diffraction (XRPD), scanning electron microscopy (SEM), bulk composition methods and electron-microprobe analysis (EMPA). The quantitative textural features of volcanic and sedimentary components were determined by 2D image analysis. The lowermost massive 70–80 cm portion is free of sedimentary structure or characterised only by plane-parallel ones, whereas the uppermost one is undulated and cross-laminated. The XRPD and SEM outcomes unveil that the VRL of CR is mainly composed of glassy shards (≥80 area%), a variable amount of sedimentary minerals (<20 area%) and a very low content of magmatic minerals (few area%). The bulk and micro-chemical attributes of volcanic and glassy materials are rhyolitic and almost identical to previous VRLs dated at 5.5 Ma (VRL-5.5). The signatures of immobile elements and the high amount of H<sub>2</sub>O present in the glass fraction suggest a provenance from a convergent geodynamic setting. The 2D image analysis on SEM observations show that the VRL-5.5 of CR is composed of very fine and sorted (averages of <i>M</i><sub>Z</sub> of 5,72 and <i>σ</i><sub><i>i</i></sub> of 0,70), scarcely vesicular, glass shards, with similar long and short size dimensions, shape and roundness. The VRL-5.5 of CR is free of large minerals and fossils. The coupling of mesoscopic and microscopic determinations indicates that the lowermost interval was deposited such as a primary tephra, i.e., fallout pyroclasts sinking in seawater. Instead, the uppermost interval derives from local, low-energy and sin-depositional remobilisation of the same VRL-5.5. The textural attributes of the volcanic fractions, the sedimentological features and the thickness of the VRL at CR correspond to the westward deposit of a still unknown eruption likely occurred at 5.5 Ma.https://www.mdpi.com/2075-163X/12/7/893volcanic glassXRPDimage analysispetrographysedimentationeruption
spellingShingle Davide Potere
Vittorio Scisciani
Monica Piochi
Pietro Paolo Pierantoni
Angela Mormone
Manuela Nazzari
Piergiorgio Scarlato
Gianluca Iezzi
The Volcanic-Rich Layer of the “Camporotondo (Marche, Italy)” Section: Petrography and Sedimentation of an Unknown Distal Messinian Eruption
Minerals
volcanic glass
XRPD
image analysis
petrography
sedimentation
eruption
title The Volcanic-Rich Layer of the “Camporotondo (Marche, Italy)” Section: Petrography and Sedimentation of an Unknown Distal Messinian Eruption
title_full The Volcanic-Rich Layer of the “Camporotondo (Marche, Italy)” Section: Petrography and Sedimentation of an Unknown Distal Messinian Eruption
title_fullStr The Volcanic-Rich Layer of the “Camporotondo (Marche, Italy)” Section: Petrography and Sedimentation of an Unknown Distal Messinian Eruption
title_full_unstemmed The Volcanic-Rich Layer of the “Camporotondo (Marche, Italy)” Section: Petrography and Sedimentation of an Unknown Distal Messinian Eruption
title_short The Volcanic-Rich Layer of the “Camporotondo (Marche, Italy)” Section: Petrography and Sedimentation of an Unknown Distal Messinian Eruption
title_sort volcanic rich layer of the camporotondo marche italy section petrography and sedimentation of an unknown distal messinian eruption
topic volcanic glass
XRPD
image analysis
petrography
sedimentation
eruption
url https://www.mdpi.com/2075-163X/12/7/893
work_keys_str_mv AT davidepotere thevolcanicrichlayerofthecamporotondomarcheitalysectionpetrographyandsedimentationofanunknowndistalmessinianeruption
AT vittorioscisciani thevolcanicrichlayerofthecamporotondomarcheitalysectionpetrographyandsedimentationofanunknowndistalmessinianeruption
AT monicapiochi thevolcanicrichlayerofthecamporotondomarcheitalysectionpetrographyandsedimentationofanunknowndistalmessinianeruption
AT pietropaolopierantoni thevolcanicrichlayerofthecamporotondomarcheitalysectionpetrographyandsedimentationofanunknowndistalmessinianeruption
AT angelamormone thevolcanicrichlayerofthecamporotondomarcheitalysectionpetrographyandsedimentationofanunknowndistalmessinianeruption
AT manuelanazzari thevolcanicrichlayerofthecamporotondomarcheitalysectionpetrographyandsedimentationofanunknowndistalmessinianeruption
AT piergiorgioscarlato thevolcanicrichlayerofthecamporotondomarcheitalysectionpetrographyandsedimentationofanunknowndistalmessinianeruption
AT gianlucaiezzi thevolcanicrichlayerofthecamporotondomarcheitalysectionpetrographyandsedimentationofanunknowndistalmessinianeruption
AT davidepotere volcanicrichlayerofthecamporotondomarcheitalysectionpetrographyandsedimentationofanunknowndistalmessinianeruption
AT vittorioscisciani volcanicrichlayerofthecamporotondomarcheitalysectionpetrographyandsedimentationofanunknowndistalmessinianeruption
AT monicapiochi volcanicrichlayerofthecamporotondomarcheitalysectionpetrographyandsedimentationofanunknowndistalmessinianeruption
AT pietropaolopierantoni volcanicrichlayerofthecamporotondomarcheitalysectionpetrographyandsedimentationofanunknowndistalmessinianeruption
AT angelamormone volcanicrichlayerofthecamporotondomarcheitalysectionpetrographyandsedimentationofanunknowndistalmessinianeruption
AT manuelanazzari volcanicrichlayerofthecamporotondomarcheitalysectionpetrographyandsedimentationofanunknowndistalmessinianeruption
AT piergiorgioscarlato volcanicrichlayerofthecamporotondomarcheitalysectionpetrographyandsedimentationofanunknowndistalmessinianeruption
AT gianlucaiezzi volcanicrichlayerofthecamporotondomarcheitalysectionpetrographyandsedimentationofanunknowndistalmessinianeruption