Chromium deposition and poisoning of La2NiO4 cathode of solid oxide fuel cell
Chromium deposition and poisoning of La2NiO4 cathode of solid oxide fuel cell were studied. La2NiO4 cathode showed stable performance in the presence of metallic interconnects. Comparing with the polarization resistance (Rp) of La2NiO4 cathode in the absence of metallic interconnects, Rp did not cha...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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The Royal Society
2018-01-01
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| Series: | Royal Society Open Science |
| Subjects: | |
| Online Access: | https://royalsocietypublishing.org/doi/pdf/10.1098/rsos.180634 |
| _version_ | 1818116388534878208 |
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| author | Bingxue Hou Cheng Cheng Wang Xumei Cui Yungui Chen |
| author_facet | Bingxue Hou Cheng Cheng Wang Xumei Cui Yungui Chen |
| author_sort | Bingxue Hou |
| collection | DOAJ |
| description | Chromium deposition and poisoning of La2NiO4 cathode of solid oxide fuel cell were studied. La2NiO4 cathode showed stable performance in the presence of metallic interconnects. Comparing with the polarization resistance (Rp) of La2NiO4 cathode in the absence of metallic interconnects, Rp did not change in the presence of metallic interconnect. After electrical conductivity relaxation method, La2NiO4 with high surface oxygen diffusion coefficients working under Cr atmosphere improved the oxygen reduction kinetics and increased cathode O2 reduction reaction rates. No chromium deposition was observed on the La2NiO4 cathode surface after polarization for 20 h at 800°C. The chemical compatibility of La2NiO4/Cr2O3 and La2NiO4/Gd0.1Ce0.9O1.95 (GDC) study indicates that La2NiO4 did not react with Cr2O3 and GDC under the operating temperature. The results indicate that La2NiO4 cathode is a potential chromium-tolerant material of solid oxide fuel cell. |
| first_indexed | 2024-12-11T04:21:43Z |
| format | Article |
| id | doaj.art-cee54f85557046869606f8a30ddd4108 |
| institution | Directory Open Access Journal |
| issn | 2054-5703 |
| language | English |
| last_indexed | 2024-12-11T04:21:43Z |
| publishDate | 2018-01-01 |
| publisher | The Royal Society |
| record_format | Article |
| series | Royal Society Open Science |
| spelling | doaj.art-cee54f85557046869606f8a30ddd41082022-12-22T01:21:06ZengThe Royal SocietyRoyal Society Open Science2054-57032018-01-0151010.1098/rsos.180634180634Chromium deposition and poisoning of La2NiO4 cathode of solid oxide fuel cellBingxue HouCheng Cheng WangXumei CuiYungui ChenChromium deposition and poisoning of La2NiO4 cathode of solid oxide fuel cell were studied. La2NiO4 cathode showed stable performance in the presence of metallic interconnects. Comparing with the polarization resistance (Rp) of La2NiO4 cathode in the absence of metallic interconnects, Rp did not change in the presence of metallic interconnect. After electrical conductivity relaxation method, La2NiO4 with high surface oxygen diffusion coefficients working under Cr atmosphere improved the oxygen reduction kinetics and increased cathode O2 reduction reaction rates. No chromium deposition was observed on the La2NiO4 cathode surface after polarization for 20 h at 800°C. The chemical compatibility of La2NiO4/Cr2O3 and La2NiO4/Gd0.1Ce0.9O1.95 (GDC) study indicates that La2NiO4 did not react with Cr2O3 and GDC under the operating temperature. The results indicate that La2NiO4 cathode is a potential chromium-tolerant material of solid oxide fuel cell.https://royalsocietypublishing.org/doi/pdf/10.1098/rsos.180634chromium poisoningla2nio4impedance spectroscopyoxygen reductionsolid oxide fuel cell |
| spellingShingle | Bingxue Hou Cheng Cheng Wang Xumei Cui Yungui Chen Chromium deposition and poisoning of La2NiO4 cathode of solid oxide fuel cell Royal Society Open Science chromium poisoning la2nio4 impedance spectroscopy oxygen reduction solid oxide fuel cell |
| title | Chromium deposition and poisoning of La2NiO4 cathode of solid oxide fuel cell |
| title_full | Chromium deposition and poisoning of La2NiO4 cathode of solid oxide fuel cell |
| title_fullStr | Chromium deposition and poisoning of La2NiO4 cathode of solid oxide fuel cell |
| title_full_unstemmed | Chromium deposition and poisoning of La2NiO4 cathode of solid oxide fuel cell |
| title_short | Chromium deposition and poisoning of La2NiO4 cathode of solid oxide fuel cell |
| title_sort | chromium deposition and poisoning of la2nio4 cathode of solid oxide fuel cell |
| topic | chromium poisoning la2nio4 impedance spectroscopy oxygen reduction solid oxide fuel cell |
| url | https://royalsocietypublishing.org/doi/pdf/10.1098/rsos.180634 |
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