Bis(O-n-butyl dithiocarbonato-κ2S,S′)bis(pyridine-κN)manganese(II)
The structure of the title manganese complex, [Mn(C5H9OS2)2(C5H5N)2] or [Mn(S2CO-n-Bu)2(C5H5N)2], consists of discrete monomeric entities with Mn2+ ions located on centres of inversion. The metal atom is coordinated by a six-coordinate trans-N2S4 donor set with the pyridyl N atoms located in the api...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811026523 |
| _version_ | 1818320870972588032 |
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| author | Naveed Alam Muhammad Ali Ehsan Matthias Zeller Muhammad Mazhar Zainudin Arifin |
| author_facet | Naveed Alam Muhammad Ali Ehsan Matthias Zeller Muhammad Mazhar Zainudin Arifin |
| author_sort | Naveed Alam |
| collection | DOAJ |
| description | The structure of the title manganese complex, [Mn(C5H9OS2)2(C5H5N)2] or [Mn(S2CO-n-Bu)2(C5H5N)2], consists of discrete monomeric entities with Mn2+ ions located on centres of inversion. The metal atom is coordinated by a six-coordinate trans-N2S4 donor set with the pyridyl N atoms located in the apical positions. The observed slight deviations from octahedral geometry are caused by the bite angle of the bidentate κ2-S2CO-n-Bu ligands [69.48 (1)°]. The O(CH2)3(CH3) chains of the O-n-butyl dithiocarbonate units are disordered over two sets of sites with an occupancy ratio of 0.589 (2):0.411 (2). |
| first_indexed | 2024-12-13T10:31:53Z |
| format | Article |
| id | doaj.art-cee7a2595cb044c0aa80ac36e74605f5 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T10:31:53Z |
| publishDate | 2011-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-cee7a2595cb044c0aa80ac36e74605f52022-12-21T23:50:50ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-08-01678m1064m106410.1107/S1600536811026523Bis(O-n-butyl dithiocarbonato-κ2S,S′)bis(pyridine-κN)manganese(II)Naveed AlamMuhammad Ali EhsanMatthias ZellerMuhammad MazharZainudin ArifinThe structure of the title manganese complex, [Mn(C5H9OS2)2(C5H5N)2] or [Mn(S2CO-n-Bu)2(C5H5N)2], consists of discrete monomeric entities with Mn2+ ions located on centres of inversion. The metal atom is coordinated by a six-coordinate trans-N2S4 donor set with the pyridyl N atoms located in the apical positions. The observed slight deviations from octahedral geometry are caused by the bite angle of the bidentate κ2-S2CO-n-Bu ligands [69.48 (1)°]. The O(CH2)3(CH3) chains of the O-n-butyl dithiocarbonate units are disordered over two sets of sites with an occupancy ratio of 0.589 (2):0.411 (2).http://scripts.iucr.org/cgi-bin/paper?S1600536811026523 |
| spellingShingle | Naveed Alam Muhammad Ali Ehsan Matthias Zeller Muhammad Mazhar Zainudin Arifin Bis(O-n-butyl dithiocarbonato-κ2S,S′)bis(pyridine-κN)manganese(II) Acta Crystallographica Section E |
| title | Bis(O-n-butyl dithiocarbonato-κ2S,S′)bis(pyridine-κN)manganese(II) |
| title_full | Bis(O-n-butyl dithiocarbonato-κ2S,S′)bis(pyridine-κN)manganese(II) |
| title_fullStr | Bis(O-n-butyl dithiocarbonato-κ2S,S′)bis(pyridine-κN)manganese(II) |
| title_full_unstemmed | Bis(O-n-butyl dithiocarbonato-κ2S,S′)bis(pyridine-κN)manganese(II) |
| title_short | Bis(O-n-butyl dithiocarbonato-κ2S,S′)bis(pyridine-κN)manganese(II) |
| title_sort | bis o n butyl dithiocarbonato amp 954 2s s amp 8242 bis pyridine amp 954 n manganese ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811026523 |
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